Quantum dot solar concentrator: Device optimisation using spectroscopic techniques

The quantum dot solar concentrator (QDSC) is a novel non-tracking solar concentrator comprising quantum dots (QDs) seeded in materials such as plastics and glasses, that concentrates both direct and diffuse solar energy on attached photovoltaic cells. Spectroscopic measurements have been undertaken for a range of different quantum dot (QD) types and transparent host materials. High transparency in the matrix material and QDs with high quantum efficiency are essential for an efficient QDSC. An optimum matrix material for a QDSC has been determined based on absorption characteristics and an optimum commercially available QD type has been chosen using steady-state absorption, photoluminescence and photoluminescence excitation spectroscopy of QDs in solution and solid matrices.     

Quantum dot solar concentrators: Electrical conversion efficiencies and comparative concentrating factors of fabricated devices

A novel, non-tracking concentrator is described, which uses nano-scale quantum dot technology to render the concept of a fluorescent dye solar concentrator (FSC) a practical proposition. The quantum dot solar concentrator (QDSC) comprises quantum dots (QDs) seeded in materials such as plastics and glasses that are suitable for incorporation into building façades. Photovoltaic (PV) cells attached to the edges convert direct and diffuse solar energy collected into electricity for use in the building. Small scale QDSC devices were fabricated. Devices have been characterised to determine current, voltage and power readings. Electrical conversion efficiencies, fill factors and comparative concentrating factors are reported.     

Low emittance coatings and the thermal performance of vacuum glazing

The thermal performances of vacuum glazings employing coatings with emittance between 0.02 and 0.16 were simulated using a three-dimensional finite volume model. Physical samples of vacuum glazings with hard and soft coatings with emittance of 0.04, 0.12 and 0.16 were fabricated and their thermal performance characterised experimentally using a guarded hot box calorimeter. Good agreement was found between experimental and theoretical thermal performances for both a vacuum glazing with a soft coating (emittance 0.04) and those with hard coatings (emittance 0.12 and 0.16). Simulations showed that for a low value of emittance (e.g. 0.02), the use of two low-emittance coatings gives limited improvement in thermal performance of the glazing system. The use of a single high performance low-emittance coating in a vacuum glazing has been shown to provide excellent performance.     

Fabrication of evacuated glazing at low temperature

An indium-based seal augmented with an adhesive, developed to maintain a vacuum between two sheets of glass, avoids the high temperatures required to produce a seal in evacuated glazings to date. An experimentally-validated three-dimensional transient model has been used to predict heat transfer for an indium/adhesive sealed 1 m² area evacuated window with a highly insulating frame. An overall heat loss coefficient of 0.9 W m⁻² K⁻¹, with a midplane value of 0.36 W m⁻² K⁻¹, can be achieved with 0.72 visible transmittance for two 6 mm panes separated by 0.2 mm diameter pillars 40 mm apart. The conduction through a 3 mm edge-seal was 1.14 W m⁻² K⁻¹. Detailed three-dimensional isothermal contour plots through the system are presented.     

Computationally efficient algorithms for state estimation with ellipsoidal approximations

Computationally efficient algorithms for computing minimal‐volume ellipsoidal bounds on the state of a linear, discrete‐time dynamical system are presented. Ellipsoidally bounded noise is considered, rather than the scalar‐noise case usually treated; the latter is covered as a degenerate special case of the former. The algorithms have differing accuracy and computational requirements, resulting from differing specifications of the bounds. The paper compares these alternative approaches to computing ellipsoidal bounds on state, giving simulation results to illustrate the performance of the algorithms. Copyright © 2002 John Wiley & Sons, Ltd.     

Eddy current inversion for layered conductors

By making multifrequency eddy current measurements on a layered conductor, it is possible to acquire information on the depth dependence of the conductivity. We consider an inversion problem in which coil impedance data are used to determine either the layer thicknesses or layer conductivities. The algorithm is based on a well known forward model which gives the impedance of an air cored coil above a stratified conductor from a closed form expression. In the forward calculation, estimates of the unknown material parameters are used to get tentative predictions of the measurements. Differences between these predictions and measured impedances are expressed in terms of a global error that is minimized iteratively with the aid of a descent algorithm by varying the parameters of the structure. Examples of minimization searches for layer parameters are given.This article is dedicated to Professor Bertram A. Auld on the occasion of his 70th birthday and his retirement from Stanford University.     

Hemostatic and fibrinolytic indices in neonatal foals with presumed septicemia

Gerbils learned to approach a spatial-olfactory stimulus that signaled access to their pairmate. Experiments 1 and 3 used a discrimination procedure in which 1 conditioned stimulus (the CS+) was presented immediately before access to the pairmate and another (the CS-) was presented alone. Both male and female gerbils came to approach the CS+ sooner than the CS- and spent more time near the CS+ than the CS-. Discrimination learning was facilitated by making the CS+ and CS- spatially distinct (Experiment 3). Learning also was demonstrated in male gerbils, using a between-subjects design with a single CS. Pairing the CS with the opportunity for social interaction resulted in greater approach to the CS within 10 trials than presenting the CS and social opportunity in an unpaired fashion (Experiment 2). These findings demonstrate social-affiliative learning in the Mongolian gerbil. Similarities and differences between these findings and sexual conditioning effects in other species are discussed.     

Radioprotection of mice by dietary squalene

Male C3H mice were fed a diet containing 2% squalene for 14 d prior to and 30 d subsequent to exposure to 6, 7 or 8 Gy of whole body γ-irradiation (Cesium-137). After 14 d on squalene-supplemented diet, plasma and jejunal tissue squalene levels were 2X and 15X that of controls. Seven days after irradiation, total white cell counts and total lymphocyte counts were substantially depressed in a radiation dose-dependent manner. Although counts in the squalene group were consistently (18–119%) higher than those in the corresponding dietary control group, the differences between dietary groups at any single dose were not significant. Nuclear area of villus cells in the jejunum of both dietary groups was significantly reduced (20%) by day 11 post-irradiation but the nuclear area in squalene-fed mice was significantly greater (15%) than in controls, before and after irradiation. There were no differences in body weight as a function of either diet or radiation dose prior to the first observations of animal lethality. Animal survival was decreased from 100 to 0% at 30 d post-irradiation by radiation doses of 6–8 Gy, with the greatest difference between dietary groups being observed at 7 Gy (median survival times of 12 and 16 d for control and squalene groups, respectively). Overall, survival of squalene-fed mice was significantly prolonged compared with control-fed mice (P=0.0054 by censored multiple regression analysis). It is concluded that squalene conferred some cellular and systemic radioprotection to mice receiving these lethal whole-body radiation doses.     

Effects of intrapleural pressure changes on canine left ventricular function

Left ventricular diameter, pressure, and dP/dt, as well as aortic and intrapleural pressures, were recorded simultaneously from 10 acute anethetized mongrel dogs. Normal inspiration produced a significant decrease in end-diastolic diameter (46.9 +/- 1.2 to 43.1 +/- 1.0 mm) and end-systolic diameter (35.5 +/- 1.4 to 34.2 +/- 1.7 mm), reducing stroke diameter 2.5 mm. Airway occlusion (greater than or equal to 60%) produced a reduction in the decrease of end-diastolic diameter seen with normal inspiration and, to a lesser degree, in end-systolic diameter. Because only acute airway occlusion greater than or equal to 80% produced a significant increase in left ventricular afterload, the authors conclude that normal spontaneous inspiration results in a decrease in left ventricular preload due to pooling of blood in the pulmonary vasculature. The data suggest that this decrease in left ventricular preload is the predominant mechanism responsible for the inspiratory decrease in left ventricular stroke volume.     

Eimeria maxima: a comparison of two laboratory strains with a fresh isolate

Oocysts of the Weybridge and Houghton strains of Eimeria maxima and a fresh field isolate were similar and measured on average 30-9 X 22-4 mum. The Weybridge strain and the field isolate produced similar pathogenic effects in 6-week-old chickens, high doses causing 50-80% mortality and severe weight loss. The Houghton strain was slightly less pathogenic and few birds died but more oocysts were produced. With each strain, a single dose gave complete immunity to a light challenge with the homologous strain. Two or 3 immunizing doses gave complete immunity to a heavy homologous challenge but were not sufficient to protect against heterologous challenge.