Changes in electrochemical impedance with microstructural development in TBCs

Thermal barrier coatings (TBCs) are improving the performance and efficiency of advanced gas turbine engines by allowing higher inlet temperature and insulation of critical hot-section components. Monitoring the integrity of TBCs prior to failure is critical to the overall performance of gas turbine en gines and requires a robust nondestructive evaluation (NDE) technique. In this paper, changes in electrochemical impedance with microstructural degradation of critical constituents in TBCs are summarized for the development of electrochemical impedance spectroscopy as an NDE technique for TBCs.     

Overall Rate Analysis of the Gaseous Reduction of Stable Oxides Incorporating Chemical Kinetics, Mass Transfer, and Chemical Equilibrium

A unified mathematical relationship for the overall rate of gaseous reduction of a stable oxide that produces a volatile suboxide has been derived including the effects of a product gas in the bulk stream, chemical kinetics, mass transfer, and chemical equilibrium. The important effect of the small equilibrium constant is quantified. How the reaction conditions affect the overall rate at different asymptotic conditions is also elucidated. By using the obtained results, the conflicting previous claims on the rate-controlling mechanism for the hydrogen reduction of silica has been critically examined and reconciled. The small equilibrium constant of this reaction causes it to be rate controlled by mass transfer under typical conditions and its rate to be slow. How the presence of even a small amount of water vapor in the bulk gas greatly enhances the effects of the small equilibrium constant is elucidated from the mathematical derivation. In addition, the small equilibrium constant also causes the apparent activation energy of silica reduction by wet hydrogen to approach the Δ H ° of reaction and that by dry hydrogen to approach     Δ H °. Because of the large positive Δ H ° value associated with reactions with a large positive Δ G ° value, such a reaction has been mistaken to be rate controlled by chemical kinetics.     

Characterization and preparation of new multiwall carbon nanotube/conducting polymer composites by in situ polymerization

Composites based on poly(diphenyl amine) (PDPA) and multiwall carbon nanotubes (MWNTs) were prepared by chemical oxidative polymerization through two different approaches: in situ polymerization and intimate mixing. In in situ polymerization, DPA was polymerized in the presence of dispersed MWNTs in sulfuric acid medium for different molar composition ratios of MWNT and DPA. Intimate mixing of synthesized PDPA with MWNT was also used for the preparation of PDPA/MWNT composites. Transmission electron microscopy revealed that the diameter of the tubular structure for the composite was 10–20 nm higher than the diameter of pure MWNT. Scanning electron microscopy provided evidence for the differences in the morphology between the MWNTs and the composites. Raman and Fourier transform IR (FTIR) spectroscopy, thermogravimetric analysis, X‐ray diffraction, and UV–visible spectroscopy were used to characterize the composites and reveal the differences in the molecular level interactions between the components in the composites. The Raman and FTIR spectral results revealed doping‐type molecular interactions and coordinate covalent‐type interactions between MWNT and PDPA in the composite prepared by in situ polymerization and intimate mixing, respectively. The backbone structure of PDPA in the composite decomposed at a higher temperature (>340°C) than the pristine PDPA (～300°C). This behavior also favored the molecular level interactions between MWNT and PDPA in the composite. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3721–3729, 2006     

Synthesis and characterizations of a polyimide containing a triphenylamine derivative as an interlayer in polymer light-emitting diode

Polyimide containing triphenylamine derivative (TPD-PI) was synthesized to prepare a polymer interlayer having insolubility in common nonpolar solvent for light-emitting polymers. N,N′-diphenyl-N,N′-bis(4-aminophenyl)-1,1-biphenyl-4,4′-diamine, as a new triphenylamine-containing diamine monomer, was synthesized by the palladium-catalyzed amination reaction between 4-nitrodiphenylamine and 4,4′-dibromobiphenyl and subsequent reduction of the nitro-intermediate. The TPD-PI was prepared from the synthesized diamine monomer and 4,4′-(hexafluoropropylidene)-diphthalic anhydride by the standard two-step polymerization method, which involved ring-opening polymerization and subsequent cyclodehydration. The structures and properties of the monomer and the resulting polyimide were characterized with ¹H and ¹³C NMR, elemental analysis, gel permeation chromatography, UV-visible spectroscopy, etc. The TPD-PI is readily soluble in aprotic polar solvents such as N-methyl-2-pyrrolidinone and N,N-dimethylformamide and insoluble in nonpolar solvents such as toluene and xylene. The highest occupied molecular orbital (HOMO) level of the TPD-PI was measured to be 5.5 eV by a photoelectron spectrometer in air, and the band gap was calculated as 3.1 eV from the onset of UV-vis spectrum. The polymer light-emitting diode with the thin TPD-PI layer between a hole injection layer and an emitting polymer layer was fabricated to examine the performance of the polyimide as an polymer interlayer. Although the luminous efficiency of the device is lowered by the introduction of the TPD-PI interlayer, the lifetime of the device is improved.     

Synthesis and luminescence properties of new blue‐light‐emitting polyconjugated poly{1,1′‐biphenyl‐4,4′‐diyl‐[1‐(4‐t‐butylphenyl)]vinylene} polymers and copolymers

Three new soluble polyconjugated polymers, all of which emitted blue light in photoluminescence and electroluminescence, were synthesized, and their luminescence properties were studied. The polymers were poly{1,1′‐biphenyl‐4,4′‐diyl‐[1‐(4‐t‐butylphenyl)]vinylene}, poly((9,9‐dioctylfluorene‐2,7‐diyl)‐alt‐{1,4‐phenylene‐[1‐(4‐t‐butylphenyl)vinylene‐1,4‐phenylene]}) [P(DOF‐PVP)], and poly([N‐(2‐ethyl) hexylcarbazole‐3,6‐diyl]‐alt‐{1,4‐phenylene‐[1‐(4‐t‐butylphenyl)]vinylene‐1,4‐phenylene}). The last two polymers had alternating sequences of the two structural units. Among the three polymers, P(DOF‐PVP) performed best in the light‐emitting diode devices of indium–tin oxide/poly(ethylenedioxythiophene) doped with poly(styrene sulfonate) (30 nm)/polymer (150 nm)/Li:Al (100 nm). This might have been correlated with the balance in and magnitude of the mobility of the charge carriers, that is, positive holes and electrons, and also the electronic structure, that is, highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) levels, of the polymers. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 307–317, 2006     

Hybrid neural network bushing model for vehicle dynamics simulation

Although the linear model was widely used for the bushing model in vehicle suspension systems, it could not express the nonlinear characteristics of bushing in terms of the amplitude and the frequency. An artificial neural network model was suggested to consider the hysteretic responses of bushings. This model, however, often diverges due to the uncertainties of the neural network under the unexpected excitation inputs. In this paper, a hybrid neural network bushing model combining linear and neural network is suggested. A linear model was employed to represent linear stiffness and damping effects, and the artificial neural network algorithm was adopted to take into account the hysteretic responses. A rubber test was performed to capture bushing characteristics, where sine excitation with different frequencies and amplitudes is applied. Random test results were used to update the weighting factors of the neural network model. It is proven that the proposed model has more robust characteristics than a simple neural network model under step excitation input. A full car simulation was carried out to verify the proposed bushing models. It was shown that the hybrid model results are almost identical to the linear model under several maneuvers. This paper was recommended for publication in revised form by Associate Editor Hong Hee Yoo Dr. Wan-Suk Yoo was born in 1954, and received B.S. degree from Seoul National University (1976), and got M.S. degree from KAIST (1978) and Ph.D. from the University of Iowa (1985). He is currently a full professor at the Pusan National University in Korea, where he joined since 1978. His major area is vehicle dynamics and flexible multibody dynamics. He became an ASME Fellow (2004), and currently serving as an associate editor for the ASME, J. of computational and nonlinear dynamics. He is also serving a contributing editor for the multibody system dynamics journal. He is serving as ISC chair for the ACMD2008, and a member at IFToMM TC for multibody dynamics. He is currently a vicepresident of the KSME (Korean Society of Mechanical Engineers).     

Study on side collision reconstruction using database based on deformed shape information

A side collision reconstruction algorithm using a database based on the deformed shape information from experiments is suggested. A deformation index related to the deformed shape is developed to set the database for the side collision reconstruction algorithm. Two small-sized model cars are developed to carry out the side collision test. Several side collision tests according to velocities and collision angles are performed for establishing side collision database. A high speed camera with 1000fps is used to capture the motion of the car. Side collision reconstruction algorithm is developed and applied to find the collision conditions before the accident occurred. Several collision cases are tested to validate the database and the algorithm. A database from computer simulation is verified with experiments. According to comparing errors between simulation and experiment, it is satisfied within 6.6%. This paper was presented at the 4th Asian Conference on Multibody Dynamics(ACMD2008), Jeju, Korea, August 20–23, 2008. Dr. Jeong-Hyun Sohn received his B.S. degree from Pusan National University (1995), M.S. from PNU (1999), and Ph.D. from PNU (2002). He is currently an associate professor in the department of Mechanical Engineering at Pukyong National University in Busan, Korea. He is currently serving as a board member of dynamics and control division, KSME. His major area is vehicle dynamics and flexible multibody dynamics. Dr. Wan-Suk Yoo received his B.S. degree from Seoul National University (1976), M.S. from KAIST (1978) and Ph.D. from University of Iowa(1985). He is professor at Pusan National University, and currently serving as a vice president in KSME. His major area is vehicle dynamics and flexible multibody dynamics.     

Reverse flow in a square duct with an obstruction at the entry

In this paper, the reverse flow in a square duct with an obstruction at the front (which is a square plate), is investigated using particle image velocimetry (PIV). The gap g between the obstruction and the entry to the duct was systematically varied, and it was found that maximum reverse flow occurs around a g/w value of 0.75. The velocity vectors, vorticity plots, and other details described indicate that the flow field is different compared with the two-dimensional channel case.     

Vibration control of smart hull structure with optimally placed piezoelectric composite actuators

Active vibration control to suppress structural vibration of the smart hull structure was investigated based on optimized actuator configurations. Advanced anisotropic piezoelectric composite actuator, Macro-Fiber Composite (MFC), was used for the vibration control. Governing equations of motion of the smart hull structure including MFC actuators were obtained using the Donnell-Mushtari shell theory and Lagrange's equation. The Rayleigh-Ritz method was used to obtain the dynamic characteristics of the smart hull structure. Experimental modal tests were conducted to verify the proposed mathematical model. In order to achieve high control performance, optimal locations and directions of the MFC actuators were determined by genetic algorithm. Optimal control algorithm was then synthesized to suppress structural vibration of the proposed smart hull structure and experimentally implemented to the system. Active vibration control performances were evaluated under various modes excitations. Vibration tests revealed that optimal configurations of MFC actuators improved the control performance of the smart hull structure in case of the limited number of actuators available.