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排序方式: 共有993条查询结果,搜索用时 15 毫秒
151.
Oleg B. Malyshev 《Vacuum》2012,86(11):1669-1681
Design of an accelerator vacuum chamber requires an input from different scientific disciplines such as surface science, material science, gas dynamics, particle beam dynamics, and many others. Although vacuum scientists work on the boundary field between these disciplines, gas dynamics is the one that allows joining them to the vacuum science for particle accelerators. The vacuum requirements (usually UHV or XHV) in particle accelerators are defined by beam-gas interactions that should be negligible compared to other phenomena that limit the quality of the beam. At such low pressures the main source of gas in the vacuum chamber is a molecular desorption from materials used for the vacuum chamber and its components. The outgassing rates vary over a very wide range and depend on material, cleaning procedure, treatments, temperature, bombardment by particles and accumulated irradiation dose. The gas dynamics is used to design the research facilities to accurately measure and to study outgassing rates at different conditions. By applying these data to the accelerator vacuum design, one would have to consider that outgassing is often non-uniform and changes with time with different functions. The most time-efficient way of beam vacuum optimization is using a 1D diffusion model where all parameters are defined as a function of longitudinal coordinate (along the beam path). A full 3D modelling with TPMC codes provides much more accurate results, however, being time consuming work is not ideal for pumping and design optimization and is used for complex components and for finalized design. 相似文献
152.
Vasylkiv O Borodianska H Badica P Grasso S Sakka Y Tok A Su LT Bosman M Ma J 《Journal of nanoscience and nanotechnology》2012,12(2):959-965
Boron carbide B4C powders were subject to reactive spark plasma sintering (also known as field assisted sintering, pulsed current sintering or plasma assisted sintering) under nitrogen atmosphere. For an optimum hexagonal BN (h-BN) content estimated from X-ray diffraction measurements at approximately 0.4 wt%, the as-prepared BaCb-(BxOy/BN) ceramic shows values of Berkovich and Vickers hardness of 56.7 +/- 3.1 GPa and 39.3 +/- 7.6 GPa, respectively. These values are higher than for the vacuum SPS processed B4C pristine sample and the h-BN -mechanically-added samples. XRD and electronic microscopy data suggest that in the samples produced by reactive SPS in N2 atmosphere, and containing an estimated amount of 0.3-1.5% h-BN, the crystallite size of the boron carbide grains is decreasing with the increasing amount of N2, while for the newly formed lamellar h-BN the crystallite size is almost constant (approximately 30-50 nm). BN is located at the grain boundaries between the boron carbide grains and it is wrapped and intercalated by a thin layer of boron oxide. BxOy/BN forms a fine and continuous 3D mesh-like structure that is a possible reason for good mechanical properties. 相似文献
153.
Vasylkiv O Demirskyi D Sakka Y Ragulya A Borodianska H 《Journal of nanoscience and nanotechnology》2012,12(6):4577-4582
Two-stage densification process of nanosized 3 mol% yttria-stabilized zirconia (3Y-SZ) polycrystalline compacts during consolidation via microwave and spark-plasma sintering have been observed. The values of activation energies obtained for microwave and spark-plasma sintering 260-275 kJ x mol(-1) are quite similar to that of conventional sintering of zirconia, suggesting that densification during initial stage is controlled by the grain-boundary diffusion mechanism. The sintering behavior during microwave sintering was significantly affected by preliminary pressing conditions, as the surface diffusion mechanism (230 kJ x mol(-1)) is active in case of cold-isostatic pressing procedure was applied. 相似文献
154.
Xie SS Su LT Guo J Vasylkiv O Borodianska H Xi Z Krishnan GM Su H Tokl AI 《Journal of nanoscience and nanotechnology》2012,12(1):596-603
Boron Carbide is one the hardest and lightest material that is also relatively easier to synthesis as compared to other superhard ceramics like cubic boron nitride and diamond. However, the brittle nature of monolithic advanced ceramics material hinders its use in various engineering applications. Thus, strategies that can toughen the material are of fundamental and technological importance. One approach is to use nanostructure materials as building blocks, and organize them into a complex hierarchical structure, which could potentially enhance its mechanical properties to exceed that of the monolithic form. In this paper, we demonstrated a simple approach to synthesize one- and two-dimension nanostructure boron carbide by simply changing the mixing ratio of the initial compound to influence the saturation condition of the process at a relatively low temperature of 1500 degrees C with no catalyst involved in the growing process. Characterization of the resulting nano-structures shows B13C2, which is a superhard phase of boron carbide as its hardness is almost twice as hard as the commonly known B4C. Using ab-initio density functional theory study on the elastic properties of both B12C3 and B13C2, the high hardness of B13C2 is consistent to our calculation results, where bulk modulus of B13C2 is higher than that of B4C. High resolution transmission electron microscopy of the nanoflakes also reveals high density of twinning defects which could potentially inhibit the crack propagation, leading to toughening of the materials. 相似文献
155.
Maksyutenko P Grechko M Rizzo TR Boyarkin OV 《Philosophical transactions. Series A, Mathematical, physical, and engineering sciences》2012,370(1968):2710-2727
We summarize here our experimental studies of the high rovibrational energy levels of water. The use of double-resonance vibrational overtone excitation followed by energy-selective photofragmentation and laser-induced fluorescence detection of OH fragments allowed us to measure previously inaccessible rovibrational energies above the seventh OH-stretch overtone. Extension of the experimental approach to triple-resonance excitation provides access to rovibrational levels via transitions with significant transition dipole moments (mainly OH-stretch overtones) up to the dissociation threshold of the O-H bond. A collisionally assisted excitation scheme enables us to probe vibrations that are not readily accessible via pure laser excitation. Observation of the continuous absorption onset yields a precise value for the O-H bond dissociation threshold, 41?145.94 ± 0.15?cm(-1). Finally, we detect long-lived resonances as sharp peaks in spectra above the dissociation threshold. 相似文献
156.
A two dimensional transient numerical analysis and computational module for simulation of electrical and thermal characteristics during electrode melting and metal transfer involved in Gas-Metal-Arc-Welding (GMAW) processes is presented. Solution of non-linear transient heat transfer equation is carried out using a control volume finite difference technique. The computational module also includes controlling and regulation algorithms of industrial welding power sources. The simulation results are the current and voltage waveforms, mean voltage drops at different parts of circuit, total electric power, cathode, anode and arc powers and arc length. We describe application of the model for normal process (constant voltage) and for pulsed processes with U/I and I/I-modulation modes. The comparisons with experimental waveforms of current and voltage show that the model predicts current, voltage and electric power with a high accuracy. The model is used in simulation package SimWeld for calculation of heat flux into the work-piece and the weld seam formation. From the calculated heat flux and weld pool sizes, an equivalent volumetric heat source according to Goldak model, can be generated. The method was implemented and investigated with the simulation software SimWeld developed by the ISF at RWTH Aachen University. 相似文献
157.
Vladislav Sadykov Natalia MezentsevaVladimir Usoltsev Ekaterina SadovskayaArkady Ishchenko Svetlana PavlovaYulia Bespalko Tamara KharlamovaEkaterina Zevak Aleksei SalanovTamara Krieger Vladimir BelyaevOleg Bobrenok Nikolai UvarovYury Okhlupin Oleg SmorygoAlevtina Smirnova Prabhakar SinghAleksandr Vlasov Mikhail KorobeynikovAleksandr Bryazgin Peter KalininAndrei Arzhannikov 《Journal of power sources》2011,196(17):7104-7109
This work presents the results related to the functionally graded fluorite (F)-perovskite (P) nanocomposite cathodes for IT SOFC. Nanocrystalline fluorites (GDC, ScCeSZ) and perovskites (LSrMn, LSrFNi) were synthesized by Pechini method. Nanocomposites were prepared by the ultrasonic dispersion of F and P powders in isopropanol with addition of polyvinyl butyral. Different techniques for deposition and sintering of functionally graded cathode materials were applied including traditional approaches as well as original methods, such as radiation-thermal sintering under electron beam or microwave radiation. Morphology, microstructure and elemental composition of nanocomposites was characterized by XRD and HRTEM/SEM with EDX. Even for dense composites, the sizes of perovskite and fluorite domains remain in the nanorange providing developed P-F interfaces. Oxygen isotope heteroexchange and conductivity/weight relaxation studies demonstrated that these interfaces provide a path for fast oxygen diffusion. The redistribution of the elements between P and F phases in nanocomposites occurs without formation of insulating zirconate phases. Button-size fuel cells with nanocomposite functionally graded cathodes, thin YSZ layers and anode Ni/YSZ cermet (either bulk or supported on Ni-Al foam substrates) were manufactured. For optimized composition and functionally graded design of P-F nanocomposite cathodes, a stable performance in the intermediate temperature range with maximum power density up to 0.5 W cm−2 at 700 °C in wet H2/air feeds was demonstrated. 相似文献
158.
Igor I. Vlasov Olga Shenderova Stuart Turner Oleg I. Lebedev Artem A. Basov Ilmo Sildos Mickel Rähn Andrey A. Shiryaev Gustaaf Van Tendeloo 《Small (Weinheim an der Bergstrasse, Germany)》2010,6(5):687-694
An efficient method to investigate the microstructure and spatial distribution of nitrogen and nitrogen‐vacancy (N‐V) defects in detonation nanodiamond (DND) with primary particle sizes ranging from approximately 3 to 50 nm is presented. Detailed analysis reveals atomic nitrogen concentrations as high as 3 at% in 50% of diamond primary particles with sizes smaller than 6 nm. A non‐uniform distribution of nitrogen within larger primary DND particles is also presented, indicating a preference for location within the defective central part or at twin boundaries. A photoluminescence (PL) spectrum with well‐pronounced zero‐phonon lines related to the N‐V centers is demonstrated for the first time for electron‐irradiated and annealed DND particles at continuous laser excitation. Combined Raman and PL analysis of DND crystallites dispersed on a Si substrate leads to the conclusion that the observed N‐V luminescence originates from primary particles with sizes exceeding 30 nm. These findings demonstrate that by manipulation of the size/nitrogen content in DND there are prospects for mass production of nanodiamond photoemitters based on bright and stable luminescence from nitrogen‐related defects. 相似文献
159.
Wang Lin Zhang Chen Cai Dexiang Zhang Jianqiang Sasaki Yasushi Ostrovski Oleg 《Metallurgical and Materials Transactions B》2017,48(1):516-526
Metallurgical and Materials Transactions B - This paper investigated the effects of CaO/SiO2 ratio (0.8 to 1.5) and Na2O concentration (6 to 9 wt pct) on melting properties and viscosity... 相似文献
160.
Oleg P. Iliev 《Numerical Heat Transfer, Part A: Applications》2013,63(6):739-748
Numerical investigation of two-dimensional (2D) laminar flow and solute transport in a channel with some sudden symmetric expansions and contractions has been performed using the fictitious regions method. This method allows us, instead of solving Navier-Stokes equations in a complex domain, to solve equations with suitably continued coefficients in a rectangle. Stream function-vorticity variables are used in the present paper. Dependence of the flow and solute transport from the dimensions of the channel expansions and contractions is numerically investigated for different values of Reynolds and Péclet numbers using a finite differences method on a relatively fine grid. 相似文献