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排序方式： 共有1038条查询结果，搜索用时 78 毫秒
181.
Dmitry V. Averyanov Ivan S. Sokolov Igor A. Karateev Alexander N. Taldenkov Oleg A. Kondratev Oleg E. Parfenov Andrey M. Tokmachev Vyacheslav G. Storchak 《Advanced functional materials》2021,31(36):2104925
Integration of oxides with silicon fuses advanced functional properties with a mature technological platform. In particular, direct EuO/Si contact holds high promise for spintronics but requires single-crystalline epitaxial films with atomically sharp interfaces. The standard approach employing regular 2D superstructures of metal atoms on the Si surface fails to meet the challenge. Here, an alternative route is designed and shown to solve the problem. This route avoids regular templates; the chaotic 2D distribution of metal atoms on the Si surface prevents stabilization of unwanted crystal orientations. Thus, the disordered submonolayer phase at the interface promotes order in oxide/Si coupling, as witnessed by a combination of diffraction techniques and high-resolution electron microscopy. The results not only mark tangible progress in manufacturing EuO/Si contacts but also provide a general framework for monolithic integration of functional oxides with semiconductor substrates. 相似文献
182.
Mikhail V. Vener Olga D. Parashchuk Oleg G. Kharlanov Dmitry R. Maslennikov Dmitry I. Dominskiy Ivan Yu. Chernyshov Dmitry Yu. Paraschuk Andrey Yu. Sosorev 《Advanced Electronic Materials》2021,7(5):2001281
Efficient operation of organic electronic devices requires high charge-carrier mobilities in their active layers, but only several organic semiconductors show confirmed charge-carrier mobilities exceeding that of amorphous silicon (≈1 cm2 V−1 s−1). Charge transport in high-mobility organic semiconductor crystals is considerably hindered by non-local electron-phonon interaction (NLEPI) transforming dynamic disorder induced by low-frequency (LF) vibrations into fluctuations of charge transfer integrals. In this work, using two crystals of naphthalene diimide derivatives as an example, LF vibrational modes that strongly modulate the charge transfer integrals are computationally revealed. The importance of the discussed LF modes for limiting the charge-carrier mobility is justified by analyzing the effect of the dynamic disorder on the charge-carrier dynamics, estimating the charge-carrier mobility in the two crystals, and observing quite a good agreement of the latter with the experimental values. Finally, it is shown that the contribution of various modes to the NLEPI correlates with their experimental Raman intensities. As a result, it is suggested that LF Raman spectroscopy can be used for experimental study of NLEPI, which can help with screening organic semiconductors showing high charge-carrier mobility and promote rational design of such materials. 相似文献
183.
Konstantin O. Nagornov Oleg Y. Tsybin Edith Nicol Anton N. Kozhinov Yury O. Tsybin 《Mass spectrometry reviews》2022,41(2):314-337
Ion cyclotron resonance (ICR) cells provide stability and coherence of ion oscillations in crossed electric and magnetic fields over extended periods of time. Using the Fourier transform enables precise measurements of ion oscillation frequencies. These precisely measured frequencies are converted into highly accurate mass-to-charge ratios of the analyte ions by calibration procedures. In terms of resolution and mass accuracy, Fourier transform ICR mass spectrometry (FT-ICR MS) offers the highest performance of any MS technology. This is reflected in its wide range of applications. However, in the most challenging MS application, for example, imaging, enhancements in the mass accuracy of fluctuating ion fluxes are required to continue advancing the field. One approach is to shift the ion signal power into the peak corresponding to the true cyclotron frequency instead of the reduced cyclotron frequency peak. The benefits of measuring the true cyclotron frequency include increased tolerance to electric fields within the ICR cell, which enhances frequency measurement precision. As a result, many attempts to implement this mode of FT-ICR MS operation have occurred. Examples of true cyclotron frequency measurements include detection of magnetron inter-harmonics of the reduced cyclotron frequency (i.e., the sidebands), trapping field-free (i.e., screened) ICR cells, and hyperbolic ICR cells with quadrupolar ion detection. More recently, ICR cells with spatially distributed ion clouds have demonstrated attractive performance characteristics for true cyclotron frequency ion detection. Here, we review the corresponding developments in FT-ICR MS over the past 40 years. 相似文献
184.
Kangho Park Woo‐Bin Jung Kiok Kwon Oleg D. Lavrentovich Hee‐Tae Jung 《Advanced functional materials》2019,29(26)
Directed self‐assembly (DSA) using soft materials is an important method for producing periodic nanostructures because it is a simple, cost‐effective process for fabricating high‐resolution patterns. Most of the previously reported DSA methods exploit the self‐assembly of block copolymers, which generates a wide range of nanostructures. In this study, cylinders obtained from supramolecular dendrimer films with a high resolution (<5 nm) exhibit planar ordering over a macroscopic area via guiding topographical templates with a high aspect ratio (>10) and high spatial resolution (≈20 nm) of guiding line patterns. Theoretical and experimental studies reveal that this property is related to geometrical anchoring on the meniscus region and physical surface anchoring on the sidewall. Furthermore, this DSA of dendrimer cylinders is demonstrated by the non‐regular geometry of the patterned template. The macroscopic planar alignment of the dendrimer nanostructure reveals an extremely small feature size (≈4.7 nm) on the wafer scale (>16 cm2). This study is expected to open avenues for the production of a large family of supramolecular dendrimers with different phases and feature dimensions oriented by the DSA approach. 相似文献
185.
Ruturaj Deshpande Sergiy Antonyuk Oleg Iliev 《American Institute of Chemical Engineers》2019,65(4):1294-1303
This study aims to investigate the sedimentation and the consolidation of the packed bed/cake formed due to the monodispersed and bidispersed particles under different flow conditions. Mutual interactions between the bidispersed particles and the liquid are considered by using a polydispersed drag model. The attractive force is considered by using the JKR model. Sensitivity of the void fraction of a sedimented packed bed/cake due to particle–particle interaction parameters is studied. Furthermore, the effect of the fluid flow is analyzed by performing the simulations in two stages. In the first stage, packed bed/cake is formed by the sedimentation of the particles in the absence of the fluid forces and in the second stage flow through the packed bed/cake is simulated by using the CFD coupled with the discrete element method. Based on the simulations, correlations between the sedimented and the consolidated void fractions are developed. © 2019 American Institute of Chemical Engineers AIChE J, 65: 1294–1303, 2019 相似文献
186.
Natalia S Serkhacheva Nikolay I Prokopov Elena V Chernikova Elena Y Kozhunova Inna O Lebedeva Oleg V Borisov 《Polymer International》2019,68(7):1303-1314
Emulsifier‐free batch emulsion polymerization of n‐butyl acrylate and its semi‐batch copolymerization with 2,2,3,3,4,4,5,5‐octafluoropentyl acrylate and 2,2,3,4,4,4‐hexafluorobutyl acrylate both mediated by poly(acrylic acid) containing the trithiocarbonate group in the chain was employed to produce amphiphilic triblock copolymers. The polymerization‐induced self‐assembly of these copolymers in aqueous media gave rise to spherical core–shell particles. Irrespective of the experimental conditions, the polymeric product was characterized by a bimodal molecular weight distribution. The apparent violation of the reversible addition–fragmentation chain transfer polymerization mechanism may be attributed to restricted accessibility of the trithiocarbonate group in the self‐assembled block copolymers for propagating radicals that enter into the particle. Mean‐field theoretical arguments were employed to explain the exclusively spherical morphology of the particles observed in the experiment. © 2019 Society of Chemical Industry 相似文献
187.
Qiao Huang Travis P. Pollard Xiaolei Ren Doyoub Kim Alexandre Magasinski Oleg Borodin Gleb Yushin 《Small (Weinheim an der Bergstrasse, Germany)》2019,15(6)
The rapid development of ultrahigh‐capacity alloying or conversion‐type anodes in rechargeable lithium (Li)‐ion batteries calls for matching cathodes for next‐generation energy storage devices. The high volumetric and gravimetric capacities, low cost, and abundance of iron (Fe) make conversion‐type iron fluoride (FeF2 and FeF3)‐based cathodes extremely promising candidates for high specific energy cells. Here, the substantial boost in the capacity of FeF2 achieved with the addition of NiF2 is reported. A systematic study of a series of FeF2–NiF2 solid solution cathodes with precisely controlled morphology and composition reveals that the presence of Ni may undesirably accelerate capacity fading. Using a powerful combination of state‐of‐the‐art analytical techniques in combination with the density functional theory calculations, fundamental mechanisms responsible for such a behavior are uncovered. The unique insights reported in this study highlight the importance of careful selection of metals and electrolytes for optimizing electrochemical properties of metal fluoride cathodes. 相似文献
188.
Bin‐Bin Yu Min Liao Yudong Zhu Xusheng Zhang Zheng Du Zhixin Jin Di Liu Yiyu Wang Teresa Gatti Oleg Ageev Zhubing He 《Advanced functional materials》2020,30(24)
As the most promising lead‐free branch, tin halide perovskites suffer from the severe oxidation from Sn2+ to Sn4+, which results in the unsatisfactory conversion efficiency far from what they deserve. In this work, by facile incorporation of methylammonium bromide in composition engineering, formamidinium and methylammonium mixed cations tin halide perovskite films with ultrahighly oriented crystallization are synthesized with the preferential facet of (001), and that oxidation is suppressed with obviously declined trap density. MA+ ions are responsible for that impressive orientation while Br‐ ions account for their bandgap modulation. Depending on high quality of the optimal MA0.25FA0.75SnI2.75Br0.25 perovskite films, their device conversion efficiency surges to 9.31% in contrast to 5.02% of the control formamidinium tin triiodide perovskite (FASnI3) device, along with almost eliminated hysteresis. That also results in the outstanding device stability, maintaining above 80% of the initial efficiency after 300 h of light soaking while the control FASnI3 device fails within 120 h. This paper definitely paves a facile and effective way to develop high‐efficiency tin halide perovskites solar cells, optoelectronic devices, and beyond. 相似文献
189.
Mykhailo Ivanov Oleg Sergyienko Vera Tyrsa Lars Lindner Wendy Flores-Fuentes Julio Cesar Rodriguez-Quinonez Wilmar Hernandez Paolo Mercorelli 《IEEE/CAA Journal of Automatica Sinica》2020,7(2):368-385
This paper proposes the solution of tasks set required for autonomous robotic group behavior optimization during the mission on a distributed area in a cluttered hazardous terrain.The navigation scheme uses the benefits of the original real-time technical vision system(TVS)based on a dynamic triangulation principle.The method uses TVS output data with fuzzy logic rules processing for resolution stabilization.Based on previous researches,the dynamic communication network model is modified to implement the propagation of information with a feedback method for more stable data exchange inside the robotic group.According to the comparative analysis of approximation methods,in this paper authors are proposing to use two-steps post-processing path planning aiming to get a smooth and energy-saving trajectory.The article provides a wide range of studies and computational experiment results for different scenarios for evaluation of common cloud point influence on robotic motion planning. 相似文献
190.
Zakhar R. Kudrynskyi Xueting Wang Jake Sutcliffe Mahabub A. Bhuiyan Yuhao Fu Zhuo Yang Oleg Makarovsky Laurence Eaves Andrij Solomon Volodymyr T. Maslyuk Zakhar D. Kovalyuk Lijun Zhang Amalia Patan 《Advanced functional materials》2020,30(9)
The design of advanced functional materials with customized properties often requires the use of an alloy. This approach has been used for decades, but only recently to create van der Waals (vdW) alloys for applications in electronics, optoelectronics, and thermoelectrics. A route to engineering their physical properties is by mixing isoelectronic elements, as done for the SnSe2(1?x)S2x alloy. Here, by experiment and first‐principles modeling, it is shown that the value of x can be adjusted over a wide range, indicating good miscibility of the SnS2 and SnSe2 compounds. The x‐dependence of the indirect bandgap energy from Eind = 1.20 eV for SnSe2 to Eind = 2.14 eV for SnS2, corresponds to a large bowing coefficient b ≈ 1 eV, arising from volume deformation and charge exchange effects due to the different sizes and orbital energies of the S‐ and Se‐atoms. This also causes composition‐dependent phonon energy modes, electron–phonon interaction, and temperature dependence of Eind. The alloys are exfoliable into thin layers with properties that depend on the composition, but only weakly on the layer thickness. This work shows that the electronic and vibrational properties of the SnSe2(1?x)S2x alloy and its thin layers provide a versatile platform for development and exploitation. 相似文献