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排序方式: 共有993条查询结果,搜索用时 15 毫秒
881.
The preferential blocking of the interior adsorption sites of single walled carbon nanotubes (SWNTs) by n-nonane is demonstrated. Following adsorption of n-nonane and evacuation for 24 h at 323 K, it was found that interior sites with diameters less than ∼14 Å remained filled with n-nonane, blocking the physical adsorption of N2 on these sites at 77.3 K. We demonstrate that “nonane blocking” is a very useful technique for nanotube porosity characterization. 相似文献
882.
Alexey V. Vakhin Irek I. Mukhamatdinov Firdavs A. Aliev Sergey I. Kudryashov Igor S. Afanasiev Oleg V. Petrashov 《Petroleum Science and Technology》2013,31(22):1850-1856
AbstractThis paper discusses aquathermolysis process of heavy crude oil from Boca de Jaruco reservoir, which is developed by CSS method. The catalysts based on cobalt, nickel, iron and cupper are used to intensify the in-situ conversion processes. The active form of catalysts generates after steam injection. In second part of work the conversion of aromatic hydrocarbons depending on thermo-catalytic conditions and composition of catalysts are investigated. The thermo-catalytic treatment destructs resin and asphaltene molecules. The destruction products transform into aromatic fractions. The correlation between the C4-phenanthrene/naphtabenzothiophen ratio and the yields of aromatics and resins are revealed. The increase in high-molecular aromatic hydrocarbon, particularly tetramethyl-phenanthrene content is observed. However, the content of heteroatom compounds such as naphtabenzothiophen is constant. Based on IR-spectroscopy, the changes in composition of aromatic fraction are revealed. The lowest value of aromaticity index is detected for experiments with only hydrogen donor (without catalysts) and for experiments with Ni-, Cu-based catalysts. 相似文献
883.
Stuart Turner Oleg I. Lebedev Olga Shenderova Igor I. Vlasov Jo Verbeeck Gustaaf Van Tendeloo 《Advanced functional materials》2009,19(13):2116-2124
Size, morphology, and nitrogen impurity location, all of which are all thought to be related to the luminescent properties of detonation nanodiamonds, are determined in several detonation nanodiamond samples using a combination of transmission electron microscopy techniques. Results obtained from annealed and cleaned detonation nanodiamond samples are compared to results from conventionally purified detonation nanodiamond. Detailed electron energy loss spectroscopy combined with model‐based quantification provides direct evidence for the sp3 like embedding of nitrogen impurities into the diamond cores of all the studied nanodiamond samples. Simultaneously, the structure and morphology of the cleaned detonation nanodiamond particles are studied using high resolution transmission electron microscopy. The results show that the size and morphology of detonation nanodiamonds can be modified by temperature treatment and that by applying a special cleaning procedure after temperature treatment, nanodiamond particles with clean facets almost free from sp2 carbon can be prepared. These clean facets are clear evidence that nanodiamond cores are not necessarily in coexistence with a graphitic shell of non‐diamond carbon. 相似文献
884.
885.
Oleg Kazak 《Metallurgical and Materials Transactions B》2013,44(5):1243-1250
This article is devoted to the numerical modeling of electrovortex and convection flows in the direct current (DC) electric arc furnace with a different position of the bottom electrode. The electromagnetic, temperature, and hydrodynamic distribution parameters are given. The shear stress on the fettle area is offered as a criterion for the estimation of vortex flow influence on the increased wearing of the fettle. It is shown that lifting the bottom electrode above the fettle surface at the electrode radius leads to the decrease of shear stress on the fettle area by 30 pct. Putting the bottom electrode lower than the fettle surface by the distance equal to the electrode radius and its expanding by the same distance reduces the stress by 10 pct. 相似文献
886.
High-resolution numerical simulations are conducted to analyze transformation of a liquid metal flow in a pipe at the entrance into a transverse magnetic field. The case of laminar flow, perfectly insulating pipe walls, and Hartmann number up to 200 is considered. The simulations reveal detailed structure of velocity and electric current fields and distribution of forces with particular attention given to the flow with an M-shaped velocity profile. They also establish criteria for accurate computations of laminar magnetohydrodynamic flows in strong non-uniform magnetic fields. 相似文献
887.
Dr. Wenjing Chen Dr. Oleg V. Tsodikov Dr. Sylvie Garneau‐Tsodikova 《Chembiochem : a European journal of chemical biology》2013,14(16):2127-2135
A recently discovered cause of tuberculosis resistance to a drug of last resort, the aminoglycoside kanamycin, results from modification of this drug by the enhanced intracellular survival (Eis) protein. Eis is a structurally and functionally unique acetyltransferase with an unusual capability of acetylating aminoglycosides at multiple positions. The extent of this regioversatility and its defining protein features are unclear. Herein, we determined the positions and order of acetylation of five aminoglycosides by NMR spectroscopy. This analysis revealed unprecedented acetylation of the 3′′‐amine of kanamycin, amikacin, and tobramycin, and the γ‐amine of the 4‐amino‐2‐hydroxybutyryl group of amikacin. A crystal structure of Eis in complex with coenzyme A and tobramycin revealed how tobramycin can be accommodated in the Eis active site in two binding modes, consistent with its diacetylation. These studies, describing chemical and structural details of acetylation, will guide future efforts towards designing aminoglycosides and Eis inhibitors to overcome resistance in tuberculosis. 相似文献
888.
889.
Boris A. Katsnelson Larisa I. Privalova Vladimir B. Gurvich Oleg H. Makeyev Vladimir Ya. Shur Yakov B. Beikin Marina P. Sutunkova Ekaterina P. Kireyeva Ilzira A. Minigalieva Nadezhda V. Loginova Marina S. Vasilyeva Artem V. Korotkov Eugene A. Shuman Larisa A. Vlasova Ekaterina V. Shishkina Anastasia E. Tyurnina Roman V. Kozin Irene E. Valamina Svetlana V. Pichugova Ludmila G. Tulakina 《International journal of molecular sciences》2013,14(2):2449-2483
Stable suspensions of nanogold (NG) and nanosilver (NS) with mean particle diameter 50 and 49 nm, respectively, were prepared by laser ablation of metals in water. To assess rat’s pulmonary phagocytosis response to a single intratracheal instillation of these suspensions, we used optical, transmission electron, and semi-contact atomic force microscopy. NG and NS were also repeatedly injected intraperitoneally into rats at a dose of 10 mg/kg (0.5 mg per mL of deionized water) three times a week, up to 20 injections. A group of rats was thus injected with NS after oral administration of a “bioprotective complex” (BPC) comprised of pectin, multivitamins, some amino acids, calcium, selenium, and omega-3 PUFA. After the termination of the injections, many functional and biochemical indices and histopathological features of the spleen, kidneys and liver were evaluated for signs of toxicity, and accumulation of NG or NS in these organs was measured. From the same rats, we obtained cell suspensions of different tissues for performing the RAPD test. It was demonstrated that, although both nanometals were adversely bioactive in all respects considered in this study, NS was more noxious as compared with NG, and that the BPC tested by us attenuated both the toxicity and genotoxicity of NS. 相似文献
890.