Visible PL Phenomenon at Room Temperature in Disordered Structure of SrWO4 Powder

The SrWO₄ (SWO) powders were synthesized by the polymeric precursor method and annealed at different temperatures. The SWO structure was obtained by X-ray diffraction and the corresponding photoluminescence (PL) spectra was measured. The PL results reveal that the structural order–disorder degree in the SWO lattice influences in the PL emission intensity. Only the structurally order–disordered samples present broad and intense PL band in the visible range. To understand the origin of this phenomenon, we performed quantum-mechanical calculations with crystalline and order–disordered SWO periodic models. Their electronic structures were analyzed in terms of band structure. The appearance of localized levels in the band gap of the order–disordered structure was evidenced and is a favorable condition for the intense PL to occur.     

Investigation of the indentation size effect through the measurement of the geometrically necessary dislocations beneath small indents of different depths using EBSD tomography

We study the link between the indentation size effect and the density of geometrically necessary dislocations (GNDs) through the following approach: four indents of different depth and hardness were placed in a Cu single crystal using a conical indenter with a spherical tip. The deformation-induced lattice rotations below the indents were monitored via a three-dimensional electron backscattering diffraction method with a step size of 50 nm. From these data we calculated the first-order gradients of strain and the GND densities below the indents. This approach allowed us to quantify both the mechanical parameters (depth, hardness) and the lattice defects (GNDs) that are believed to be responsible for the indentation size effect. We find that the GND density does not increase with decreasing indentation depth but rather drops instead. More precisely, while the hardness increases from 2.08 GPa for the largest indent (1230 nm depth) to 2.45 GPa for the smallest one (460 nm depth) the GND density decreases from ≈2.34 × 10¹⁵ m^?2 (largest indent) to ≈1.85 × 10¹⁵ m^?2 (smallest indent).     

Heat transfer enhancement in a tube using circular cross sectional rings separated from wall

A numerical study was undertaken for investigating the heat transfer enhancement in a tube with the circular cross sectional rings. The rings were inserted near the tube wall. Five different spacings between the rings were considered as p = d/2, p = d, p = 3d/2, p = 2d and p = 3d. Uniform heat flux was applied to the external surface of the tube and air was selected as working fluid. Numerical calculations were performed with FLUENT 6.1.22 code, in the range of Reynolds number 4475–43725. The results obtained from a smooth tube were compared with those from the studies in literature in order to validate the numerical method. Consequently, the variation of Nusselt number, friction factor and overall enhancement ratios for the tube with rings were presented and the best overall enhancement of 18% was achieved for Re = 15,600 for which the spacing between the rings is 3d.     

Determination of molecular, atomic, electronic cross-sections and effective atomic number of some boron compounds and TSW

The transmission of gamma-rays of some boron compounds (H₃BO₃, Na₂B₄O₇) and the trommel sieve waste (TSW) have been measured by using an extremely narrow-collimated-beam transmission method in the energy range 15.74-40.93 keV. Molecular, atomic and electronic cross-sections and effective atomic numbers have been determinated on the basis of mixture rule and compared with the results obtained from theory.     

Experimental and numerical investigation of heat and mass transfer during drying of Hayward kiwi fruits (Actinidia Deliciosa Planch)

In this paper we undertake an experimental and numerical study on heat and mass transfer analysis during drying of kiwi fruits. In the experimental part, the effects of various drying conditions in terms of air velocity, temperature and relative humidity on drying characteristics of kiwi fruits are investigated. In the numerical part, the external flow and temperature fields are studied using a commercial CFD package. From these fields, the local distributions of the surface convective heat transfer coefficients for the fruits are determined to predict the local convective mass transfer coefficients through the analogy between the thermal and concentration boundary layers (known as the Chilton–Colburn analogy). In addition, the time-dependent temperature and moisture distributions for different cases are obtained using the code developed to investigate heat and mass transfer aspects inside the fruits. Numerical results are then compared with experimental data and a considerably high agreement is obtained.     

Creating and Validating Embedded Assertion Statecharts

Integrating formal assertions into the modeling, implementation, and testing of statechart-based designs can enhance a rapid system prototyping system's robustness by providing runtime monitoring and recovery from assertion failures. An iterative process for developing and verifying statechart prototype models augmented with statechart assertions using the StateRover tool lets system designers write formal specifications using statechart assertions. It also enables them to use JUnit-based simulation to validate statechart assertions and to test statechart prototype models augmented with statechart assertions. A case study using a safety-critical computer assisted resuscitation algorithm software prototype for a casualty intravenous fluid infusion pump illustrates the process.     

The thermal kinetics of texture change and the analysis of texture variability for raw and roasted hazelnuts

Texture changes of hazelnuts which were dry roasted at temperatures from 120 to 180 °C, for durations ranging from 5 up to 60 min, were studied using instrumental analysis. The textural changes in hazelnuts were represented by the fracture force obtained from compression tests. The magnitudes of the parameters for the corresponding texture change model were determined using one step non‐linear regression. The order of the reaction was found by plotting isothermal curves of texture response against time; statistical analysis of the data showed that it was best represented by a first‐order reaction. The rate constants were assumed to have an Arrhenius‐type dependence on temperature. The activation energy and the frequency (pre‐exponential) factor at a reference temperature (150 °C) were determined to be 39.25 kJ mol^?1 and 0.0421 s^?1, respectively. Young's modulus and the fracture stress for roasted hazelnuts were calculated to be 4.93 and 1.54 MPa, respectively. Both roasting temperature and time had significant effects on the textural changes in hazelnuts, and the variability in the texture decreased during the roasting process. The physical properties of hazelnuts were correlated with the texture response. A possible major factor causing the high variability in texture was the internal cavity present at the core of each hazelnut. The development of a model of the thermal kinetics of texture change over a large roasting temperature and time range should allow optimization studies to be used for determining the best roasting schedule in terms of delivering the required product texture.     

Photovoltaic textile structure using polyaniline/carbon nanotube composite materials

In this paper, an investigation of flexible electrodes for photovoltaic textile structures utilizing polymer‐based organic materials is presented. The composite structure consisting of a blend of water dispersible carbon nanotube:polyaniline (CNT:PANI) components with poly(3,4 ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) was applied to be used as the hole collecting electrode in photovoltaic textile applications. Both photovoltaic textiles and conventional solar cells were fabricated by using a blend of poly(3‐hexylthiophene‐2,5‐diyl) (P3HT):(6,6)‐phenyl C61‐butyric acid methyl ester (PCBM). All devices were characterized by measuring current versus voltage characteristics under AM 1.5 conditions. The nanoscale morphology of the photovoltaic structures was investigated using scanning electron microscopy and atomic force microscopy.