Using a microstrip bandpass filter to compare different circuit analysis techniques

A 22.5-GHz microstrip bandpass filter is analyzed using three different circuit analysis techniques. Circuit theory modeling fails to provide an accurate prediction when compared to measured data. But a hybrid analysis, which uses electromagnetic field solver computations and circuit theory models, provides good agreement with measured data. A more complete field solver analysis of the filter also shows good agreement when compared to measurements. In the later two cases, the electromagnetic analysis captures the actual current distribution on the filter that circuit theory fails to predict. © 1995 John Wiley & Sons, Inc.     

Poly [2-(cinnamoyloxy)ethyl methacrylate-co-octamethacryl-POSS] nanocomposites: Synthesis and properties

Poly [2-(cinnamoyloxy)ethyl methacrylate-co-octamethacryl-POSS] nanocomposites were synthesized from octamethacryl-POSS and 2-(cinnamoyloxy)ethyl methacrylate (CEM) by free radical polymerization. The chemical structures and morphologies of these nanocomposites were determined by FTIR, ²⁹Si NMR, energy-dispersive spectroscopy (EDS), X-ray powder diffraction (XRD), and scanning electron microscopy (SEM) techniques. The XRD data showed that the materials were amorphous in nature, indicating that POSS formed an aggregate instead of a crystalline form in the polymer matrix. The POSS-CEM nanocomposites exhibited high thermal stability. Excitation and emission of the CEM-incorporated POSS nanocomposites, studied in the solid state, exhibited blue emission with CIE (x, 0.178; y, 0.137) coordinates, in addition to an emission intensity that increased with increasing CEM (monomer) concentration.     

Soft solution fluorine-free synthesis of anatase nanoparticles with tailored morphology

TiO₂ nanoparticles with tailored morphology have been synthesized under exceptionally soft conditions. The strategy is based on the use of a non-aqueous alcoholic reaction medium in which water traces, coming either from the air (atmospheric water) or from an ethanol–water azeotropic mixture (ethanol 96%), are incorporated in order to accelerate hydrolysis of the Ti–precursor. Moreover, organic surfactants have been used as capping agents so as to tailor crystal growth in certain preferential directions. Combinations of oleic acid and oleylamine, which lead to the formation of another surfactant, dioleamide, are employed instead of fluorine-based compounds, thus increasing the sustainability of the process. As a result, TiO₂ nanostructured hierarchical microspheres and individual nanoparticles with exposed high-energy facets can be obtained at atmospheric pressure and temperatures as low as 78 °C.     

A Versatile Flat-Deposit Impactor-Type Aerosol Collector Part 1: Design and Qualitative Study

Cascade impactors provide an efficient method for sampling aerosols according to their size, grossly between 0.1 mu m and a few tens of microns in diameter. We have designed such an apparatus, with rotatable substrate plates and radially aligned rectangular orifices. The nominal cutpoint diameters are, respec tively, for stages 1-7 of the collector: 10, 5, 2, 1, 0.5, 0.25, and 0.1 mu m aed for an airflow of 10/L min. The sampler has an auxiliary set of orifice plates for operation at 20/L min giving the same cutpoint characteristics. Annular deposits are obtained following complete rotation of the collecting substrates. The airflow is controlled with a critical orifice at the last stage. A calculation program was written for a rectangular orifice impactor in order to determine the cutpoints in different conditions. The constant exit pressure mode of operation appears to be the best way to minimize fluctuations of the effective cutpoints against the varying conditions of ambient temperature and pressure. The SPAL sampler has proven satisfactory with respect to manipulations required, maintenance, and results delivered.     

Particle Mixing and Diffusion in the Turbulent Wake of a Sphere

The mixing and diffusion of monodisperse aerosols from a turbulent free stream into the wake created by a solid sphere were studied experimentally and analytically. Experimental measurements with regard to wake velocity profiles and momentum transport were taken in a tubular flow system by hot-wire anemometry. Particle concentration profiles, measured in the wake by means of a screen collection technique, were used to calculate mixing and diffusion parameters for the aerosols used. Experimental results are presented for the mean velocity and particle concentration profiles, wake centerline velocity and particle concentration, wake velocity and concentration half widths, and momentum and particle diffusivities. It is shown that the experimental results may be reasonably described in terms of two phenomenological theories, i.e., Prandtl's mixing length and constant diffusivity in the radial cross section of the wake. Certain departures from predicted concentration behavior are empirically analyzed resulting in the ability to predict overall particle mixing and diffusion characteristics in a turbulent wake.     

High-throughput approach to the catalytic combustion of diesel soot II: Screening of oxide-based catalysts

Following the development of a high-throughput (HT) methodology for the evaluation of diesel soot oxidation catalysts in a 16 parallel channels reactor, a library of over 60 catalysts was tested under optimized conditions. The catalyst compositions were chosen to include solids which specific properties like oxygen storage capacity, oxygen mobility and ionic conductivity. The key parameters for high activity appear related to the presence of active and mobile surface oxygen species, and to an appropriate catalyst particle size in order to favour the number of contacts with the soot. In contrast, high oxygen storage capacity and bulk oxygen ion mobility do not appear as relevant properties for high catalytic activity. Nine new formulations were found to perform better than the reference catalyst “high surface area (HSA) ceria” (Rhodia).