Effect of polymers on the nanostructure and on the carbonation of calcium silicate hydrates: a scanning transmission X-ray microscopy study

This study investigated the effects of organic polymers (polyethylene glycol and hexadecyltrimethylammonium) on structures of calcium silicate hydrates (C–S–H) which is the major product of Portland cement hydration. Increased surface areas and expansion of layers were observed for all organic polymer modified C–S–H. The results from attenuated total reflectance–Fourier transform infrared (ATR–FTIR) spectroscopic measurements also suggest lowered water contents in the layered structures for the C–S–H samples that are modified by organic polymers. Scanning transmission X-ray microscopy (STXM) results further supports this observation. We also observed difference in the extent of C–S–H carbonation due to the presence of organic polymers. No calcite formed in the presence of HDTMA whereas formation of calcite was observed with C–S–H sample modified with PEG. We suggest that the difference in the carbonation reaction is possibly due to the ease of penetration and diffusion of the CO₂. This observation suggests that CO₂ reaction strongly depends on the presence of organic polymers and the types of organic polymers incorporated within the C–S–H structure. This is the first comprehensive study using STXM to quantitatively characterize the level of heterogeneity in cementitious materials at high spatial and spectral resolutions. The results from BET, XRD, ATR–FTIR, and STXM measurements are consistent and suggest that C–S–H layer structures are significantly modified due to the presence of organic polymers, and that the chemical composition and structural differences among the organic polymers determine the extent of the changes in the C–S–H nanostructures as well as the extent of carbonation reaction.     

连续稳定循环的三效吸附式热泵两种工况下的COP值计算

设计了连续而又稳定循环的三效吸附式热泵单元－三效冷环。由于各吸附床的吸附循环之间具有先后连贯性，因此既避免了吸附床的过热，又消除了热泵输出端的不稳定工作状态，使得热泵系统的ＣＯＰ值Ｙｏｎｇ效率以及各吸附循环的效率比双效和单效系统均有显著提高。     

过渡金属氧化物对PVC抑烟机理的ESCA研究

用ESCA技术对PVC／V2O5，PVC／MoO3，PVC／ZnO和PVC／Fe2O3体系经过210℃／3h恒温热分解后的主体骨架和过渡金属氧化物的结构演变进行了系统研究，结果表明。加入过渡金属氧化物的体系，主体骨架中有第三种结构形式的碳出现；过渡金属氧化物在反应过程中的结构变化有两种不同的形式,ZnO和Fe2O3转化为ZnCl2和FeCl3，而V2O5和MoO3则保持原结构形式不变。V2O5，MOO3。ZnO和Fe2O3对PVC的阻燃抑烟遵循两类不同的机理。     

采用吸气管过热度调节的户式空气源采暖空调热水三用机

简要介绍户式空气源采暖空调热水三用机的项目背景、技术原理、技术路线。针对三用机的特殊技术要求,首次提出吸气管过热度的定义以及采用电子膨胀阀PID调节吸气管过热度的新概念,利用该调节方法研制一台三用机,并按行业标准进行型式试验检测。测试结果表明,三用机达到国标的节能等级,并可高效制热、低温采暖,以及实现高效率的采暖、空调、热水、空调＋热水等功能。     

一种基于Internet的异地容灾系统的设计和实现

基于Internet设计并实现了一种异地容灾系统.该系统集实时备份和监控、服务自动切换和快速恢复为一体,支持多种操作系统和数据库,并提供基于Web的远程管理.其结构简单、合理,运行稳定,具有较高的应用和推广价值.     

基于虚拟力的群机器人围捕算法

启迪于物理学中的范例,探讨了基于虚拟力的群机器人围捕算法的原理和方法。制定了详细的系统性能评价指标（稳定时间、层数、层间距离、层中机器人个数、机器人密度等参数）。分析了围捕性能与机器人数量、虚拟力的关系;提出了目标对机器人作用力的分层结构思想,实验显示不仅加快了围捕速度,而且提高了围捕分层的质量;提出了机器人绕目标转动的围捕方法,解决了势场法中常见的局部极点问题,并且大大提高了围捕的速度和质量。设计了一个简单的实体机器人实验证实了围捕算法的可行性,指出了今后的研究方向。     

Resolution enhanced light field near eye display using e‐shifting method with birefringent plate

Light field near eye displays (LFNED) can produce lightweight devices and address the accommodation–convergence conflict. However, low spatial resolution creates a poor immersive experience in LFNED. In addition, although many e‐shifting devices have been proposed to enhance resolution in projection system, yet those devices are too bulky to be applied in an LFNED to keep it lightweight. In this paper, a compact e‐shifting component is proposed to enhance image resolution in an LFNED by using a birefringent plate and twisted nematic switch cell. The proposed e‐shifting device is a flat and thin component with only 2.6 mm of thickness, which could be placed in the gap of an LFNED without increasing the thickness. The results show that the proposed components could be easily integrated in an LFNED with the result of resolution enhancement.     

航空发动机的健康指标构建与剩余寿命预测

预测与健康管理技术能够有效的评估系统健康状态、预测系统剩余使用寿命,是提高复杂系统安全性、经济性的重要保障.为全面评估系统健康状态,本文提出了一种基于深度置信网络(DBN)的无监督健康指标构建方法,并结合隐马尔可夫模型(HMM)进行系统剩余寿命预测.首先,通过无监督训练深度置信网络实现历史数据的特征提取,进而构建健康指标;其次,利用健康指标集训练隐马尔可夫模型,实现设备健康状态的自动识别;最后,通过DBN-HMM混合模型来计算系统剩余寿命.采用商用模块化航空推进系统仿真软件(C-MAPSS)给出的航空发动机数据集,验证了上述方法的有效性.     

基于并行支持向量机的多变量非线性模型预测控制

提出一种基于并行支持向量机的多变量系统非线性模型预测控制算法．首先,通过考虑输入、输出间的耦合,建立基于并行支持向量机的多步预测模型;然后,将该模型用于非线性预测控制,提出新的适用于并行预测模型的反馈校正策略,得到最优控制律．连续搅拌槽式反应器（CSTR）的控制仿真结果表明,该算法的性能优于基于并行神经网络的非线性模型预测控制和基于集成模型的非线性模型预测控制．     

用于PDIC的跨阻放大器的优化设计

提出了一种用于PDIC的跨阻放大器.电路由三级相同的推挽放大器级联而成,每级均采用一动态电阻对负载进行补偿,以提高放大器的相位裕度.反馈电阻由一栅极受控的PMOS管替代,避免了大尺寸多晶硅电阻引入的附加相移,增加了电路的稳定性.采用XFAB 0.6μm CMOS工艺提供的PDK,在Cadence Spectre环境下进行电路设计、仿真验证.仿真结果表明,电路的增益、带宽及稳定性均得到满意结果.

Abstract：

Presented is a transimpedance amplifier for PDIC.The designed amplifier is configured on three identical push-pull amplifier stages that use an active load compensated by an active resistor to improve the phase margin of the amplifier.The feedback resistor is replaced by a PMOS transistor which is biased by the gate voltage.The replacement not only avoids the phase-shift introduced by the large ploy-resistor but improves the stability performance of the transimpedance amplifier.Based on XFAB's 0.6 μm CMOS,circuit design and simulation were performed by using Cadence Spectre.The simulation results show that the gain,bandwidth and stability of the amplifier all achieve good performance.