Oxidation and quality of soybean oil: A preliminary study of the anisidine test

The anisidine test, a measure of secondary oxidation products in glyceride oils, was applied to a number of soybean salad oils processed from sound and damaged soybeans. A highly significant correlation (−0.68) was found between the anisidine values of salad oils from sound soybeans and their flavor scores. Multiple correlations between flavor scores, anisidine, and peroxide values yielded a correlation of 0.81 and provided a method for predicting the initial flavor scores of sound soybean salad oils. Similar data for oils from damaged beans gave a highly significant, but lower, correlation (−0.65). Comparative studies indicated that sound crude oils usually contain lower levels of oxidation products than damaged crude. Oxidation in both sound and damaged crudes increased roughly in proportion to iron content. Reproducibility of the test and the effects of hydrogenation, accelerated storage, and fluorescent light on anisidine values were studied. Analysis of damaged oils before and after deodorization showed that little, if any, reduction of anisidine value occurred. Deodorization of sound oils, however, lowered anisidine values. In comparison with damaged oils, the anisidine values of sound oils were lower at comparable stages of processing. The poor quality of damaged soybean oil was substantiated by organoleptic evaluations. Flavor scores of oils given special processing treatments increased as anisidine values decreased.     

Non-insulin dependent diabetes mellitus in Psammomys obesus is independent of changes in tissue fatty acid composition

Recently it has been postulated that membrane fatty acid composition may be involved in the pathogenesis of insulin resistance and non-insulin dependent diabetes mellitus (NIDDM). The aim of this study was to determine whether alterations in tissue phospholipid (PL) fatty acids are present in hyperglycemic and hyperinsulinemic Psammomys obesus. On a native diet of salt bush, P. obesus (Israeli sand rat) remains lean and free of diabetes; however, when placed on a normal laboratory chow, a significant proportion of these animals develops a number of metabolic disorders associated with NIDDM, providing an ideal animal model of obesity and NIDDM. Four groups of mature P. obesus were studied: group A; normoglycemic and normoinsulinemic; group B: normoglycemic and hyperinsulinemic; group C: hyperglycemic and hyperinsulinemic; and group D: hyperglycemic hypoinsulinemic. In liver and red gastrocnemius muscle, there were no significant differences between groups, A, B, and in fatty acid composition of PL. Minor differences in individual fatty acids were demonstrated in group D animals (increased liver 20∶4n-6 and increased muscle 22∶5n-3); however, the unsaturation indices in liver and muscle were not significantly different between any of the groups. In considering that the minor changes in group D animals were not demonstrated in hyperinsulinemic group B animals or hyperglycemic, hyperinsulinemic group C animals, it is likely that the differences in group D animals were secondary to the more severe disturbances in glucose homeostasis and hypoinsulinemia present in these animals. The results of this study suggest that in this rodent diabetic model significant disturbances in glucose homeostasis and hyperinsulinemia may develop independently of changes in tissue fatty acid composition.     

A VSE equation of state for liquids. V. Poly(tetrafluoroethylene), 600–725 K

Our volume–entropy–energy (VSE) equation of state for liquids, first proposed in 1973 for use with low molecular weight homogeneous liquids, is here applied for the first time to a high molecular weight liquid that is heterogeneous in molecular weight, namely, a molten polymer. Four thermo-dynamic quantities, T, s, c_p, and ε are calculated over the range of 600–725 K at ambient pressure and are compared with experimental values, with excellent results. The grand average of the standard percentage errors (S.P.E.) for the 24 points is 0.1100%.     

Physico-Chemical Properties of the Egyptian Tamarind Seed Oil

The physico-chemical properties of the Egyptian Tamarind seed oil were investigated. The seeds were found to contain a fair amount of oil (16.25%). It was found that the oil has a high acid and iodine values in comparison with cotton seed oil. Arachidic, linoleic, oleic, stearic, palmitic, myristic, and lauric were fractionated by gas liquid chromatography from the tamarind seed oil. More than 50% of the total acids are unsaturated. The infrared spectroscopy showed the presence of 7 absorption bands at wave-number cm^?1 (730, 1150, 1380, 1480, 1750, 2900 and 2950) in the investigated oil. On the other hand chemical analysis of the cake showed a lower protein content and higher sugar content.     

MOLECULAR PRINCIPLE OF CORRESPONDING STATES FOR VISCOSITY AND THERMAL CONDUCTIVITY OF FLUID MIXTURES

Conformal solution theory is developed for the viscosity and thermal conductivity of fluid mixtures. The procedure involves expanding the transport coefficient for the mixture about the value for an ideal solution, using groupings of the potential parameters and molecular mass as expansion coefficients. The parameters for the ideal solution are chosen so as to annul the first-order term in this expansion, thus encouraging rapid convergence. This yields mixing rules (similar to those of the van der Waals 1 theory for thermodynamic properties) for the potential parameters and molecular mass of the reference fluid. Reference fluid properties are obtained from pure fluid corresponding states correlations

By making calculations for dilute gas mixtures and comparing with Chapman-Enskog theory, it is found that the first-order theory works well for mixtures of quite widely different energy parameters (ε) and molecular masses; it is more sensitive to the size difference of the molecular components, however. For cryogenic liquid mixtures composed of simple liquids good results are obtained using two-parameter corresponding states for the reference fluid. For polyatomic fluids it is necessary to use a three-parameter corresponding states approach for the pure fluids. A method of introducing a third parameter, while retaining the simplicity of having only two independent variables, is used for such fluids. Good results are obtained for a variety of binary mixtures. The method is of particular value for multicomponent fluids. Thus, without fitting any parameters from ternary data the theory predicts viscosities for the system carbon tetrachloride/n-hexane/benzene over the full composition range with a standard deviation of only 1.69%.     

Dietary effect of a symmetrical triacylglycerol, 1,3-biseicosapentaenoyl-2-γ-linolenoyl glycerol, on fatty acid composition of guinea pigs

The dietary effect of 1,3-biseicosapentaenoyl-2-γ-linolenoyl glycerol (STG) on the fatty acid composition of guinea pigs was examined and compared with that of an eicosapentaenoic acid ethyl ester (EPA-F) and of a soybean oil (SBO) diet. In terms of content of plasma lipid, EPA-E had a greater hypolipidemic effect than STG. On the other hand, in terms of EPA incorporation, contents of EPA in liver lipid were almost the same in the STG and EPA-E groups. Considering that the amount of EPA administered in the EPA-E group was almost 1.5 times that of the STG group, FPA may be absorbed more effectively as the glycerol ester than as the ethyl ester in guinea pigs. In all the tissue lipids, the STG group had a higher unsaturation index (UI) than the EPA-E group even though there is a lower UI in the STG diet than the EPA-E diet. These results suggest that greater amounts of desaturase products as a whole were synthesized in the STG group than in the other two groups. The dihomo-γ-linolenic acid/arachidonic acid (DGLA/AA) ratio in plasma total lipids in the STG group was 3.5 times that of SBO group, and the DGLA/AA ratio in the EPA-E group was half that of the SBO group. In liver lipid, the ratios of DGLA/AA and EPA/AA in the STG group were 0.687 and 0.488 (phosphatidylcholine fraction) and 0.237 and 0.752 (phosphatidylethanolamine fraction), respectively. The ratio of DGLA/AA as well as the high EPA/AA ratio obtained in the present study with the STG diet may lead to physiological alterations, including enhanced synthesis of 1-and 3-series eicosanoids.     

The polymerization of N-vinylcarbazole in the presence of carbon black

In order to obtain more detailed information on the mechanism of the polymerization of N-vinyl-carbazole (N-VC) in the presence of carbon black, a comparison of the rates of conversion under various conditions was made and the following results were obtained. The phenolic hydroxyl groups on the surface of carbon black were found to have an ability to initiate the polymerization, and an increase in dielectric constant of the solvent increased the rate of polymerization. Using the mixture of N-VC and comonomers such as styrene or methyl methacrylate, we found that styrene gives a copolymer with N-VC, while methyl methacrylate gives no copolymer during the early stage of polymerization. The phenomena observed here indicate that the nature of polymerization of N-VC initiated by carbon black is cationic.