细颗粒循环料腿的自力平衡原理及实验研究

本文介绍了一种固体细颗粒循环料腿的自力平衡结构模型（单气路式）及其工作原理，对该结构模型进行了流体力学分析，并分析了各种因素对自力平衡效果的影响趋势。在冷态模型装置上进行的实验测定验证了料腿的自平衡效果，并获得了与理论分析相一致的结论。由于该结构简单，无机械运动部件，并且易满足耐高温、耐高压及耐磨损等性能要求，特别是它能在较宽的工作范围内使料腿自力稳定，它的应用可望改善固体料循环控制的可操作性，从而对特定的工作系统有利。     

CS_2中毒法研究Pt-Al_2O_3系催化剂活性中心的性质

本文对金属催化剂活性中心性质提出了新的表征方法,即用活性频率量度活性中心的强度,用原子组合数的概念描述原子组成活性中心的方式,在此基础上提出了活性频率和活性中心原子组合数的计算公式与新的测定方法。 从测出的活性频率和活性中心原于组合数的数据,发现了Pt-Al_2O_3催化剂具有两种活性中心即α和β中心。α中心CS_2的吸附能力比β中心强,但β中心对环己烷的脱氢活性比α中心强。同时证明了不管在α中心或在β中心上环己烷的脱氢反应都是在双位中心上进行的。 本文还考察了锡和铼对铂催化剂性能的影响,实验表明锡和铼都能从结构效应和电子效应方面影响铂的催化性能。     

细鳞片石墨化学氧化法制备可膨胀石墨技术问题探讨

采用分步氧化法制备了80目细鳞片可膨胀石墨。通过L9（3^4）正交试验确定了最佳工艺条件。在液固比-5：1，C：KMnO4=1：0．12，Ⅰ H2SO4：Ⅱ H2SO4=4：1，H2SO4：H2O2=12：1（均为质量比g／g）条件下获得膨胀容积为290mL／g。对制备过程中液固比、硫酸浓度、双氧水的加入方式、可膨胀石墨烘手温度、原料粒度等因素对膨胀容积的影响以及可膨胀石墨的稳定性的改善方法进行了探讨。     

Supercritical CO2‐assisted synthesis of poly(acrylic acid)/Antheraea pernyi SF blend

Monomer acrylic acid (AA) and initiator azo‐bis(isobutyronitrile)were carried into Antheraea pernyi silk fibroin (SF) fibers using supercritical CO₂ as a solvent and carrier, followed by free radical polymerization at a suitable temperature, resulting in PAA/SF blends. The binary system of CO₂/AA and the ternary system of CO₂/AA/AIBN systems were studied. Different impregnation conditions, such as time, pressure, and concentration of AA in the fluid phase on mass uptake, were studied. Fourier transform infrared spectroscopy and X‐ray diffraction results confirmed that PAA was indeed present in the silk and that there were intermolecular hydrogen bonds between PAA and SF. According to thermogravimetry and DTG, blending with PAA could enhance the thermal stability of SF slightly. The water retention values indicated that the hydrophilic nature of the fibers was improved. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 864–868, 2005     

建筑塑料的阻燃和抑烟

建筑塑料是化学建材的重要组成部分，人们关注建筑塑料的阻燃和抑烟问题。本文论述建筑塑料的燃烧过程、阻燃机理、成烟机理，提出了阻燃和抑烟的技术措施。     

安阳市水资源生态足迹与生态承载力研究

利用水资源生态足迹分析方法对安阳市2005~2014年的水资源生态足迹、生态承栽力进行了计算分析。结果表明,2005~2014年安阳市人均水资源生态足迹均值为0.45 hm~2/cap,且呈波动下降趋势。其中生产用水生态足迹占水资源生态足迹比重最大,达82.8%~91.4%,生活用水足迹其次,生态用水足迹最小,但呈上升趋势。安阳市水资源人均生态承载力较小,在0.048 hm~2/cap~0.068 hm~2/cap之间,受气候、水文起伏波动较大。安阳市2005—2014年间,水资源生态足迹均处于赤字状态,说明安阳市水资源利用长期以来一直是不可持续的。近10年来,安阳市万元GDP水资源生态足迹整体呈较快下降趋势,表明安阳市水资源利用效率正逐步提高。     

小型合成氨厂节气节能工艺评价 (Ⅷ)换热式转化深冷净化工艺

作者对“换热式转化深冷净化工艺”用于改造以间歇蒸汽转化工艺生产合成氨小厂的工艺流程、主要原料消耗、技术经济指标和风险性进行了研究、计算、分析和比较,为国内105家以天然气为原料的小型合成氨厂节气节能改造的方案选择提供依据。     

Maximum error-bounded Piecewise Linear Representation for online stream approximation

Given a time series data stream, the generation of error-bounded Piecewise Linear Representation (error-bounded PLR) is to construct a number of consecutive line segments to approximate the stream, such that the approximation error does not exceed a prescribed error bound. In this work, we consider the error bound in \(L_\infty \) norm as approximation criterion, which constrains the approximation error on each corresponding data point, and aim on designing algorithms to generate the minimal number of segments. In the literature, the optimal approximation algorithms are effectively designed based on transformed space other than time-value space, while desirable optimal solutions based on original time domain (i.e., time-value space) are still lacked. In this article, we proposed two linear-time algorithms to construct error-bounded PLR for data stream based on time domain, which are named OptimalPLR and GreedyPLR, respectively. The OptimalPLR is an optimal algorithm that generates minimal number of line segments for the stream approximation, and the GreedyPLR is an alternative solution for the requirements of high efficiency and resource-constrained environment. In order to evaluate the superiority of OptimalPLR, we theoretically analyzed and compared OptimalPLR with the state-of-art optimal solution in transformed space, which also achieves linear complexity. We successfully proved the theoretical equivalence between time-value space and such transformed space, and also discovered the superiority of OptimalPLR on processing efficiency in practice. The extensive results of empirical evaluation support and demonstrate the effectiveness and efficiency of our proposed algorithms.     

基于遗传二进制粒子群混合算法的测试点决策研究

测试点选择是测试性分析和设计的前提。通过对测试问题的分析,建立了数学模型和构造了衡量测试集优劣程度的启发式函数,提出了一种遗传-二进制粒子群混合算法求解满足测试性指标要求的最小完备子集。应用实例表明,该算法能够有效的克服单一算法陷入局部最优和早熟收敛等不足,提高了搜索效率,能够有效快速的获得全局最优解。     

二茂铁及其衍生物的应用

综述了二茂铁及其衍生物在添加剂、燃速催化剂、医学、液晶材料、感光材料以及二茂铁有机磁体等方面的应用和最新研究进展。