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31.
Babak Fathi Ali Khalifeh Soltani Iraj Amiri Amraei 《Polymer-Plastics Technology and Engineering》2013,52(6):564-567
In this study, the surface modification of carbon fiber by sulfuric acid is investigated. Atomic Force Microscopy was employed to capture the corresponding changes in the surface roughness of the carbon fiber. Moreover, using treated and untreated fibers, unsaturated polyester unidirectional composite rods were prepared and their flexural properties were determined by three-point bending and dynamic mechanical thermal analysis. The results indicated that the carbon fiber surface roughness increases in all samples. It is also found that treating the fiber decreases the magnitude of loss modulus. Besides, the flexural strength of composites made of the treated carbon fiber significantly increased. 相似文献
32.
Strahinja Zecevic Edward M. Patton Parviz Parhami 《Chemical Engineering Communications》2013,200(12):1655-1670
Historically, despite its compelling cost and performance advantages, the use of a molten metal hydroxide electrolyte has been ignored by direct carbon fuel cell (DCFC) researchers, primarily due to the potential for formation of carbonate salt in the cell. This article describes the electrochemistry of a patented medium-temperature DCFC based on a molten hydroxide electrolyte, which overcomes the historical carbonate formation. An important technique discovered for significantly reducing carbonate formation in the DCFC is to ensure a high water content of the electrolyte. To date, four successive generations of DCFC prototypes have been built and tested to demonstrate the technology – all using graphite rods as their fuel source. These cells all used a simple design in which the cell containers served as the air cathodes and successfully demonstrated the ability to deliver more than 40 A with the current density exceeding 250 mA/cm2. Conversion efficiency greater than 60% was achieved. 相似文献
33.
Shrinkage of repair material, especially in patching repairs, is the major factor inducing cracking in concrete repairs. Induced cracks in repair materials are due to restrained shrinkage. Although in usual practice, the free shrinkage of the repair mortar is measured, in reality, cracking is not due to free shrinkage. It is well known that cracking is due to restrained shrinkage. It is very hard to measure the restrained shrinkage; therefore, to overcome this problem a restraint factor (R) is used to modify the free shrinkage and come up with the restrained shrinkage. The restraint factor is influenced by the surface and boundary condition.In this study, the restraint factor for patching repair with different boundary conditions (with eaves and without eaves) and surface condition (rough and smooth) of the substrate concrete is investigated.The results show that the restraint factor R lies between 0.1 and 0.94; with an increase of restraint, the restraint factor is increased. In situations with a high level of restraint (eaves at the perimeter and a rough surface of substrate), the average R is 0.83. while with a low level of restraint (without eaves at the perimeter and a smooth surface of the substrate), the average R is 0.22. 相似文献
34.
Application of the dry‐spinning method to produce poly(ε‐caprolactone) fibers containing bovine serum albumin laden gelatin nanoparticles 下载免费PDF全文
Bahareh Azimi Parviz Nourpanah Mohammad Rabiee Shahram Arbab Maria Grazia Cascone Andrea Baldassare Luigi Lazzeri 《应用聚合物科学杂志》2016,133(48)
We designed and manufactured a polymeric system with combined hydrophilic–hydrophobic properties by loading gelatin nanoparticles (GNPs) containing bovine serum albumin (BSA) into poly(ε‐caprolactone) (PCL) fibers. Our ultimate goal was to create a device capable of carrying and releasing protein drugs. Such a system could find several biomedical applications, such as those in controlled release systems, surgical sutures, and bioactive scaffolds for tissue engineering. A two‐step desolvation method was used to produce GNPs, whereas PCL fibers were produced by a dry‐spinning method. The morphological, mechanical, and thermal properties of the produced system were investigated, and the distribution of nanoparticles both inside and on the surface of the fibers was examined. The effect of the particles on the biodegradability of the fibers was also evaluated. In vitro preliminary tests were performed to study the release of BSA from nanoparticle‐laden fibers and to compare this with its release from free nanoparticles. Our results indicate that the distribution of particles inside the fibers was quite homogeneous and only a few of them were present on the surface. The presence of the particles in the fibers did not affect the thermal properties of the PCL polymer matrix, although it created voids that affected the degradation characteristics so the PCL fibers favored faster erosion compared to the plain fibers. Preliminary results indicate that the release from GNP‐laden fibers occurred much more slowly compared to that in the free GNPs. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44233. 相似文献
35.
Fabrication and characterization of novel nanofibers from cress seed mucilage for food applications 下载免费PDF全文
Cress seed mucilage (CSM) as a new source of biomacromolecule has gained attraction in food science due to its biodegradability and biocompatibility. In this research CSM–poly(vinyl alcohol) (PVA) nanofibers were produced under different conditions by electrospinning technique. Viscosity and electrical conductivity of the produced biopolymers were analyzed. The effect of CSM to PVA volume ratio and applied electrical field were evaluated on nanofiber morphology by scanning electron spectroscopy. The optimum nanofibers showed smooth and uniform surfaces with diameter size range of 95–278 nm. The results of Fourier transform infrared spectroscopy of CSM–PVA nanofiber with volume ratio of 60:40 showed characteristic peaks of CSM and PVA. X‐ray diffractometer data clearly revealed the amorphous structure of the electrospun nanofibers. Thermogravimetric and derivative thermogravimetric analysis indicated that thermal stability of electrospun nanofibers increased in comparison to CSM and PVA. The results of this study indicated that CSM can be applied as a new source of biopolymer for production of nanofibers that could be used for different applications such as delivery systems and packaging film fabrication. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45811. 相似文献
36.
Parviz Mohammadi Shaliza Ibrahim Mohamad Suffian Mohamad Annuar 《Korean Journal of Chemical Engineering》2012,29(10):1347-1351
Five pretreatment methods, namely chemical, acid, heat-shock, freezing and thawing, and base, were evaluated for the enrichment of hydrogen-producing bacteria in anaerobic granulated sludge, which will be subsequently used as seed in biological hydrogen production. All the pretreatments showed positive effects towards improving hydrogen (H2) generation by the microbial population with higher hydrogen production yield and COD removal efficiency as compared to control. The granulated sludge pretreated by heat-shock showed maximum accumulated H2 (19.48mLg?1-COD), COD removal efficiency (62%), and biomass concentration (22.5 gL?1). 相似文献
37.
38.
Reactive plasma spray of TiN ceramic coating attracts much attention over the years because of its ability to deposit thick layers on various metal surfaces. However, some mechanical properties of the coating such as its hardness should be improved. In this study, initially a thin layer of titanium nitride was prepared on a titanium substrate during irradiation of titanium substrate by a thermal DC nitrogen-contained plasma jet. Then, during reactive plasma spraying, Ti particles were injected into plasma jet, converted to titanium nitride and huddled on to the substrate. This new hybrid method (primary plasma irradiation and post-reactive plasma spraying) for deposition of TiN coatings would combine the advantages of both plasma-enhanced chemical vapor deposition and reactive plasma spraying methods in part. It resulted in a thick and hard layer of titanium nitride film. Sample produced by this method was analyzed with x-ray diffraction confirming titanium nitride production. Vickers hardness was measured using optical microscopy which was around 1319 Hv300g. To study the cross section of the layer, optical microscopy and scanning electron microscopy (SEM) were used. 相似文献
39.
Farnoush Faridbod Mohammad Reza Ganjali Bagher Larijani Parviz Norouzi 《Electrochimica acta》2009,55(1):234-239
Solution studies showed the strong interaction of [5-(dimethylamino) naphthalene-1-sulfonyl 4-phenylsemicarbazide] (NSP) with Er(III) ions. NSP was used as a sensing material during construction of carbon paste Er(III) sensors. The electrodes were modified with 1-n-butyl-3-methylimidazolium tetrafluoroborate, [bmim]BF4, as room temperature ionic liquid (RTIL) and multi-walled carbon nanotube (MWCNT). Potentiometric sensors constructed with [bmim]BF4 and MWCNTs show better sensitivity, selectivity, response time, and response stability compared to Er(III) carbon paste sensors. The best performance for the modified sensor was obtained with an electrode composition of 20% [bmim]BF4, 20% NSP, 45% graphite powder and 15% MWCNT. This particular sensor formulation exhibits a Nernstian response (19.8 ± 0.3 mV decade−1) toward Er(III) ions in the range of 1.0 × 10−7 to 1.0 × 10−1 mol L−1 with a detection limit of 5.0 × 10−8 mol L−1. The proposed modified Er(III) sensor can be used over the pH range from 3.5 to 9.0. 相似文献
40.
Poly(o-aminophenol) (POAP) was formed by successive cyclic voltammetry in monomer solution in the presence of sodium dodecyl sulfate (SDS) on the surface of a carbon paste electrode. The electrochemical behavior of the SDS-POAP carbon paste electrode has been investigated by cyclic voltammetry in 0.5 M HClO4 and 5 mM K4[Fe(CN)6]/0.1 M KCl solutions as the supporting electrolyte and model system, respectively. Ni(II) ions were incorporated into the electrode by immersion of the polymeric modified electrode having amine groups in 0.1 M Ni(II) ion solution. Cyclic voltammetric and chronoamperometric experiments were used for the electrochemical study of this modified electrode. A good redox behavior of the Ni(III)/Ni(II) couple at the surface of electrode can be observed. The electrocatalytic oxidations of methanol and ethylene glycol (EG) at the surface of the Ni/SDS-POAP electrode were studied in a 0.1 M NaOH solution. Compared to bare carbon paste and POAP-modified carbon paste electrodes, the SDS-POAP electrode significantly enhanced the catalytic efficiency of Ni ions for methanol oxidation. Finally, using a chronoamperometric method, the catalytic rate constants (k) for methanol and ethylene glycol were found to be 2.04 × 105 and 1.05 × 107 cm3 mol−1 s−1, respectively. 相似文献