Novel Hyperbranched predominantly Alternating Copolymers Made From A Charge Transfer Complex monomer pair of p-(chloromethyl)styrene and Acrylonitrile via Controlled Living Radical Copolymerization

Summary Novel hyperbranched copolymers were successfully synthesized by the controlled charge transfer complex inimer and living radical copolymerization of p-(chloromethyl)styrene (PCMS) and acrylonitrile (AN). The resulting copolymers were characterized by SEC, NMR, FTIR, DSC and elemental analysis etc.. The influences of reaction conditions, such as the polymerization temperature, the catalyst (CuBr) concentration and the monomer ratio, on the resulting copolymers were investigated in detail. The monomer reactivity ratios were evaluated to be r_PCMS=0.937 and r_AN=0.088 respectively by the Fineman-Ross method. The higher are the polymerization temperature and the ratio of catalyst to monomer, the higher is the branching degree of the resulting copolymer. When the amount of monomer AN was used in excess than that of the monomer PCMS in the raw feed, the hyperbranched predominantly alternating copolymers HP[PCMS-co-AN] could be obtained. These hyperbranched copolymers were successfully used as functional macroinitiators to synthesize the star-shaped poly(PCMS-co-AN)/poly(MMA) block copolymers.     

Plastic deformation and fracture of binary TiAl-base alloys

The mechanical behavior of binary TiAl alloys containing 46 to 60 at. pct Al has been studied in bulk materials preparedvia rapid solidification processing. Bending and tensile tests were carried out at room temperature as a function of Al concentration. A few alloys were also tested from liquid nitrogen temperature to ∼ 1000°C. Deformation substructures were studied by analytical transmission electron microscopy and fracture modes by scanning electron microscopy (SEM). It was found that both microstructure and composition strongly affect the mechanical behavior of TiAl-base alloys. A duplex structure, which contains both primary y grains and transformedγ/α ₂ lamellar grains, is more deformable than a single-phase or a fully transformed structure. The highest plasticities are observed in duplex alloys containing 48–50 at. pct Al after heat treatment in the center of theγ + α phase field. The deformation of these duplex alloys is facilitated by 1/2[110] slip and {111} twinning, but very limited superdislocation slip occurs. The twin deformation is suggested to result from a lowered stacking fault energy due to oxygen depletion or an intrinsic change in chemical bonding. Other factors, such as grain size and grain boundary chemistry and structure, are important from a fracture point of view. The results on the deformation and fracture modes as a function of test temperature are also discussed.     

Peripheral nerve injury as a complication from orthopedic operation

We report a case of pulmonary carcinosarcoma. Surgery is required for this rare mixed type, biphasic tumor. It is generally considered to be a malignant formation issuing from a single cell line but with a two-way differentiation into epithelial and conjunctive components. There is a differentiation continuum between spindle-cell carcinomas (also called monophasic sarcomatoid carcinoma) and carcinosarcoma (or biphasic sarcomatoid carcinoma) leading to debate concerning the immunohistochemical and ultrastructural features.     

实炉底节能连续式加热炉

轧钢生产使用实炉底连续式加热炉加热钢坯，炉内双纵滑管用耐热耐高温材料，无水冷，起到节约水、电的作用，达到节能增效的目的。     

PMMA／PBA乳胶IPN阻尼材料的研究

用乳液聚合方法合成了一系列的互穿聚合物网络，其中包括：ＰＭＭＡ／ＰＢＡ和Ｐ（ＭＭＡ－ｃｏ－ＰＭＡ）／ＰＢＡ乳胶互穿聚合物网络（ＬＩＰＮ），ＰＭＭＡ／ＰＢＡ乳胶双向互穿聚合物网络（ＬＢＩＰＮ）以及ＰＭＭＡ／ＰＢＡ界面交联互穿聚合物网络（ＩＣＬＩＰＮ）。动态力学谱和拉伸试验结果表明：（１）ＰＭＭＡ／ＰＢＡ互穿聚合物网络的两组分相容性和阻尼性能可通过ＭＭＡ和ＰＭＡ共聚来改善；（２）双向互穿技术是一种行之     

Exact evaluation of laser linewidth requirements for optical PSKhomodyne communication systems with balanced PLL receivers

The power penalty induced by imperfect phase recovery in PSK homodyne communication systems with balanced phase-locked loop receivers are exactly evaluated. Optimum phase deviations between the mark-state and the space-state bits are used in this study. This study for the first time shows the imperfect-phase-recovery-induced power penalty as a function of laser linewidth with optimum phase deviations considered. It can be estimated from the theoretical result that an optimal balanced PLL receiver requires the laser linewidth as Δν⩽1.15×10^-6× (bit rate) in contrast to the previous reported one Δν⩽5.88×10^-6× (bit rate). We also point out here that the previously reported laser linewidth requirement was wrongly estimated     

TiAl基合金表面改性对高温抗氧化性的影响

研究了渗碳处理ＴｉＡｌ基合金试样的高温氧化行为，发现渗碳处理可以在ＴｉＡｌ基合金试样表层形成致密的多层结构的渗碳层，并发生表层Ａｌ、Ｔｉ重新分配。致密的渗碳层具有良好的高温抗氧化性和高温热稳定性，同时，Ｔｉ、Ａｌ重新分配形成的富Ａｌ最外层也能进一步提高合金的抗氧化性。     

基于Native Mode ATM API的应用系统模型及关键技术

ＡＴＭ技术作为Ｂ－ＩＳＤ的基础，在传输包括话音、图像、数据的综合业务环境中具有现有其它网络技术所不具备的技术优势，然而目前真正基于ＡＴＭＮａｔｉｖｅＭｏｄｅ的应用还很少，而大量基于Ｏｖｅｒｌａｙ Ｍｏｄｅ的ＡＴＭ应用不能充分发挥ＡＴＭ技术的优势。随着信息技术的发展，将会有大量的综合业务应用出现，它具有和传统数据通信安全不同的业务特性，必须通过一种灵活，高效的应用程序接口给予支持，本文提出基于Ｎａｔ     

Detection of congenital müllerian duct anomalies using three-dimensional ultrasound

PURPOSE: The purpose of this study was to assess the value of 3-dimensional sonography in the diagnosis of congenital müllerian duct anomalies, which cause infertility, preterm labor, and first trimester abortion. METHODS: A prospective study was undertaken in which 40 patients with histories of repeated spontaneous abortions or infertility were first examined using conventional 2-dimensional sonography or hysterosalpingography. Three-dimensional transvaginal sonography was then performed. RESULTS: Twenty-eight women had müllerian duct abnormalities, and 12 women had normal uterine anatomy. Müllerian duct defects detected in this study were unicornuate uterus (3), bicornuate uterus (3), complete or partial septate uterus (12), arcuate uterus (9), and didelphic uterus (1). The diagnosis of müllerian duct anomalies in these patients was confirmed by laparoscopic and/or hysteroscopic examinations. Three-dimensional sonography demonstrated all congenital uterine abnormalities with a sensitivity and specificity of 100%. Separate uterus and bicornuate uterus could be correctly diagnosed using 3-dimensional sonography in 11 (92%) of 12 cases and 3 (100%) of 3 cases, respectively. These 2 abnormalities were commonly confused with each other using hysterosalpingography and conventional sonography. CONCLUSIONS: Three-dimensional sonography with image reconstruction is less expensive and less invasive than hysterosalpingography for the assessment of uterine anatomy and diagnosis of müllerian duct abnormalities. The ability to visualize both the uterine cavity and the myometrium on a 3-dimensional scan facilitates the diagnosis of uterine anomalies and enables the differentiation of septate from bicornuate uteri for preoperative surgical planning.     

聚合物复合材料填充剂的改性

在前人研究的基础之上，归纳总结了聚合物复合材料填充剂的种类，综述了对其进行表面改性的目的、条件、方法、工艺以及对改性结果的表征等。文章还分析了影响填充聚合物复合材料性能的因素，指出了今后发展的方向。