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991.
Jagannathan Rajagopalan Christian Rentenberger H. Peter Karnthaler Gerhard Dehm M. Taher A. Saif 《Acta Materialia》2010,58(14):4772-4782
In situ transmission electron microscopy straining experiments with concurrent macroscopic stress–strain measurements were performed to study the effect of microstructural heterogeneity on the deformation behavior of nanocrystalline metal films. In microstructurally heterogeneous gold films (mean grain size dm = 70 nm) comprising randomly oriented grains, dislocation activity is confined to relatively larger grains, with smaller grains deforming elastically, even at applied strains approaching 1.2%. This extended microplasticity leads to build-up of internal stresses, inducing a large Bauschinger effect during unloading. Microstructurally heterogeneous aluminum films (dm = 140 nm) also show similar behavior. In contrast, microstructurally homogeneous aluminum films comprising mainly two grain families, both favorably oriented for dislocation glide, show limited microplastic deformation and minimal Bauschinger effect despite having a comparable mean grain size (dm = 120 nm). A simple model is proposed to describe these observations. Overall, our results emphasize the need to consider both microstructural size and heterogeneity in modeling the mechanical behavior of nanocrystalline metals. 相似文献
992.
Shenyan Huang Daniel L. Worthington Mark Asta Vidvuds Ozolins Gautam Ghosh Peter K. Liaw 《Acta Materialia》2010,58(6):1982-1993
Self- and impurity diffusivities in body-centered-cubic (bcc) iron have been calculated within the formalisms of harmonic transition-state theory and the Le Claire nine-frequency model for vacancy-mediated diffusion. The approach combines first-principles calculations of vacancy formation, migration, and solute-binding enthalpies and entropies in the ferromagnetic phase, with an empirical relationship for the effect of magnetic disorder on diffusion activation energies. Calculated Fe self-diffusion and Mo and W impurity-diffusion coefficients are shown to agree within a factor of five with the most recent experimental measurements in both the ferromagnetic and paramagnetic phases. Calculated diffusion coefficients for Mo and W impurities are comparable to or larger than that for Fe self-diffusion at all temperatures below the α–γ phase transition. Calculated activation energies for Ta and Hf impurities suggest that these solutes should also display impurity-diffusion coefficients larger than that for self-diffusion in body-centered cubic Fe. 相似文献
993.
Robert M. Boddey Mark B. Peoples Brian Palmer Peter J. Dart 《Nutrient Cycling in Agroecosystems》2000,57(3):235-270
Biological nitrogen fixation (BNF) associated with trees and shrubs plays a major role in the functioning of many ecosystems, from natural woodlands to plantations and agroforestry systems, but it is surprisingly difficult to quantify the amounts of N2 fixed. Some of the problems involved in measuring N2 fixation by woody perennials include: (a) diversity in occurrence, and large plant-to-plant variation in growth and nodulation status of N2-fixing species, especially in natural ecosystems; (b) long-term, perennial nature of growth and the seasonal or year-to-year changes in patterns of N assimilation; and (c) logistical limitations of working with mature trees which are generally impossible to harvest in their entirety. The methodology which holds most promise to quantify the contributions of N2 fixation to trees is the so-called `15N natural abundance' technique which exploits naturally occurring differences in 15N composition between plant-available N sources in the soil and that of atmospheric N2. In this review we discuss probable explanations for the origin of the small differences in 15N abundance found in different N pools in both natural and man-made ecosystems and utilise previously published information and unpublished data to examine the potential advantages and limitations inherent in the application of the technique to study N2 fixation by woody perennials. Calculation of the proportion of the plant N derived from atmospheric N2 (%Ndfa) using the natural abundance procedure requires that both the 15N natural abundance of the N derived from BNF and that derived from the soil by the target N2-fixing species be determined. It is then assumed that the 15N abundance of the N2-fixing species reflects the relative contributions of the N derived from these two sources. The 15N abundance of the N derived from BNF (B) can vary with micro-symbiont, plant species/provenance and growth stage, all of which create considerable difficulties for its precise evaluation. If the%Ndfa is large and the 15N abundance of the N acquired from other sources is not several 15N units higher or lower than B, then this can be a major source of error. Further difficulties can arise in determining the 15N abundance of the N derived from soil (and plant litter, etc.) by the target plant as it is usually impossible to predict which, if any, non-N2-fixing reference species will obtain N from the same N sources in the same proportions with the same temporal and spatial patterns as the N2-fixing perennial. The compromise solution is to evaluate the 15N abundance of a diverse range of neighbouring non-N2-fixing plants and to compare these values with that of the N2-fixing species and the estimate of B. Only then can it be determined whether the contribution of BNF to the target species can be quantified with any degree of confidence. This review of the literature suggests that while the natural abundance technique appears to provide quantitative measures of BNF in tree plantation and agroforestry systems, particular difficulties may arise which can often limit its application in natural ecosystems. 相似文献
994.
Phase Analysis and Thermal Stability of Hot Isostatically Pressed Zirconia–Hydroxyapatite Composites
Erik Adolfsson Peter Alberius-Henning Leif Hermansson 《Journal of the American Ceramic Society》2000,83(11):2798-2802
Composites of zirconia and hydroxyapatite (OHAp) have been processed via hot isostatic pressing (HIP) or sintering in air. When the composites were sintered in air at a temperature of 950°C, decomposition of the OHAp to tricalcium phosphate occurred. Using the HIP technique, composites without any detectable degradation of the OHAp phase were produced at 1200°C. The reactivity between zirconia and OHAp was dependent on both the amount of water lost from OHAp and the geometry of the interaction. The phase composition of the materials prepared was evaluated from their powder X-ray diffraction patterns, and their microstructures were studied via electron microscopy. 相似文献
995.
Achim Neubrand Reinhard Lindner Peter Hoffmann 《Journal of the American Ceramic Society》2000,83(4):860-864
In the present study, the incongruent dissolution of barium from barium titanate (BaTiO3 ) has been studied as a function of dispersion pH and powder volume fraction for two different BaTiO3 powders. In alkaline dispersions, the barium solubility strongly increases as the pH increases, as suggested by thermodynamic considerations. At pH <7, the barium solubility reaches a plateau, the height of which is dependent on the surface area of the powder and the solids loading of the slip. The BaTiO3 surface is completely depleted of barium in this region. 相似文献
996.
S. Mariccor A. B. Batoy Sabine Borgmann Karin Flick Josephine Griffith Jeffrey J. Jones Viswanathan Saraswathi Alyssa H. Hasty Peter Kaiser Charles L. Wilkins 《Lipids》2009,44(4):367-371
Here we describe a study of the feasibility of lipid and phospholipid (PL) profiling using matrix assisted laser desorption/ionization
(MALDI) Fourier transform mass spectrometry (FTMS) for two different applications. In this work PL profiles of different mammalian
tissues as well as those of whole cell organisms were examined. In particular, comparative analysis of lipid and PL profiles
of tissues from mice fed different diets was done and, in another application, MALDI FTMS was used to analyze PL profiles
of genetically modified Saccharomyces cerevisiae. Computational sorting of the observed ions was done in order to group the lipid and PL ions from complex MALDI spectra.
The PL profiles of liver tissues from mice fed different diets showed a cross correlation coefficient of 0.2580, indicating
significant dissimilarity, and revealed more than 30 significantly different peaks at the 99.9% confidence level. Histogram
plots derived from the spectra of wild type and genetically modified yeast resulted in a cross correlation coefficient 0.8941
showing greater similarity, but still revealing a number of significantly different peaks. Based on these results, it appears
possible to use MALDI FTMS to identify PLs as potential biomarkers for metabolic processes in whole cells and tissues. 相似文献
997.
Nielsen Per F.; Roepstorff Peter; Clausen Ib G.; Jensen Ejner B.; Jonassen Ib; Svendsen Allan; Balschmidt Per; Hansen Finn B. 《Protein engineering, design & selection : PEDS》1989,2(6):449-457
Californium-252 plasma desorption mass spectrometry (PDMS) hasbeen employed for the characterization of a series of humaninsulin derivatives in order to evaluate the performance ofthis technique as an analytical tool in protein engineering.Several of the characterized modifications result in a 1 a.m.u.mass change. The precision in mass determination obtainableby PDMS analysis is not sufficient for unambiguous verificationof such modifications based on the molecular weight alone. Itis, however, possible to carry out in situ enzymatic digestionof the sample. Subsequent PDMS analysis will in most cases revealif the modification has been introduced as intended. 相似文献
998.
Carlos E. Bamberger Peter Angelini Theodore A. Nolan 《Journal of the American Ceramic Society》1989,72(4):587-592
The production of titanium nitride, TiN, whiskers by reaction of sodium titanium bronze, Nax TiO2 (STB), with excess sodium cyanide, NaCN, at 1000°C is reported. The solubility of Ti from a STB in molten NaCN has been estimated experimentally. The TiN whiskers obtained under different experimental conditions have been examined by scanning electron microscopy and analyzed by analytical electron microscopy. 相似文献
999.
Vijay Jain Arun K. Varshneya Peter P. Bihuniak 《Journal of the American Ceramic Society》1989,72(5):843-845
The steady-state dc ionic resistivity measurements on GE 124 commercial fused silica glass were carried cut in nonblocking mode between 300° and 650°C using fused Li+ , Na+ , and K+ nitrate salts as electrodes. The alkali ions were electrolyzed through a sample disk in a U-tube-type dc conductivity cell until steady state was achieved. Sequential conduction experiments at varying temperatures using various ions in a given sample showed that the resistivity of an ion could vary by as much as 1 order of magnitude depending upon the conduction history of the specimen, i.e., which ions had been electrolyzed through the specimen during prior experiments. 相似文献
1000.
Peter Anderl 《化学,工程师,技术》1989,61(10):767-774
Comparison of laser with electron beam welding . International industry requires products of the highest technical standards thus requiring application of the technologically most efficient and most economical processes. For this reason, the electron beam and laser welding processes are becoming more and more important. To provide a workpiece-relevant basis for deciding which technique should be used the following aspects will be investigated: generation of the beam, beam guidance systems, welding processes, application and power ranges, process controls, and equipment for industrial use. Finally a tabulated comparison should facilitate a detailed distinction between the two techniques. 相似文献