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161.
162.
Chakkedath A. Maiti T. Bohlen J. Yi S. Letzig D. Eisenlohr P. Boehlert C. J. 《Metallurgical and Materials Transactions A》2018,49(6):2441-2454
Metallurgical and Materials Transactions A - Due to their excellent strength-to-weight ratio, Mg alloys are attractive for applications where weight savings are critical. However, the limited cold... 相似文献
163.
Hongbin Gu Jiangning Wu Philip Chan Ginette Turcotte Tianjiang Ye 《Chemical Engineering Research and Design》2012
To improve surface hydrophilicity and to reduce fouling, commercial polypropylene microfiltration membranes were ozonated to generate peroxides as grafting sites for hydrophilic monomers. Ozonation was conducted in aqueous and gaseous phases, respectively. In both phases, the amount of peroxides increased with the ozonation time. A novel way to enhance the generation of peroxides was tested, i.e., adding homogeneous catalyst, CuSO4, to aqueous ozonation. Results showed that with an optimum dose of 0.05 g/L of CuSO4, the peroxides generated were 18.2% more than that by the non-catalyzed ozonation in aqueous phase. It was also confirmed by scavenger tests that during the aqueous ozonation both molecular ozone and free radicals contributed to the oxidation of the membranes, the latter was formed from the self-decomposition of ozone in water. Graft polymerization was also conducted after the generation of peroxides. A hydrophilic monomer, acrylic amide, was graft polymerized onto the membrane surface. The successful grafting of acrylic amide was confirmed by the formation of new peaks corresponding to amide groups in FTIR spectra. Results of contact angle measurements and filtration tests indicated that aqueous ozonation was more effective than its gaseous counterpart in terms of hydrophilicity improvement. In addition, the XRD analysis revealed that the ratio of the membrane surface crystallinity to amorphousity was changed by both ozonation and graft polymerization. Results of SEM scanning also showed changes in membrane surfaces after modification. 相似文献
164.
The interaction of dislocations with low-angle grain boundaries (LAGBs) is considered one important contribution to the mechanical strength of metals. Although LAGBs have been frequently observed in metals, little is known about how they interact with free dislocations that mainly carry the plastic deformation. Using discrete dislocation dynamics simulations, we are able to quantify the resistance of a LAGB—idealized as three sets of dislocations that form a hexagonal dislocation network—against lattice dislocation penetration, and examine the associated dislocation processes. Our results reveal that such a coherent internal boundary can massively obstruct and even terminate dislocation transmission and thus make a substantial contribution to material strength. 相似文献
165.
Sandra Jeck Philip Scharfer Wilhelm Schabel Matthias Kind 《Chemical Engineering and Processing: Process Intensification》2011,50(5-6):543-550
The development of reliable mathematical models for mass transport in crosslinked polymers and their thorough experimental validation are of substantial interest in the design of technical membrane processes or the assessment of polymer performance when applications such as functional films and protective coatings are concerned.The present study aims at the joint experimental and numerical characterisation of mass transport during water vapour sorption into physically crosslinked poly(vinyl alcohol) membranes. A mathematical model comprising both phase equilibrium and the respective mass transport mechanisms is proposed and verified by means of in situ sorption kinetic measurements. Drawing on the independent determination of equilibrium solvent uptake, the comparison of model calculations and experimental sorption data demonstrates that water transport in the crosslinked polymer membrane is successfully described by pure Fickian diffusion with a simple exponential expression for the solvent diffusion coefficient to account for its pronounced concentration dependency, allowing the latter to be specified quantitatively. 相似文献
166.
Ian G. Hamilton David Shipworth Alex J. Summerfield Philip Steadman Tadj Oreszczyn Robert Lowe 《Building Research & Information》2014,42(3):255-275
Little detailed evidence has previously been available regarding the uptake rate or prevalence of energy efficiency interventions among specific household groups. This study uses the Home Energy Efficiency Database (HEED) to investigate both the combination of measures that have been installed, and in which dwellings, according to key neighbourhood socio-demographic variables, including income and tenure. Analysis of 2000–07 data indicates that approximately 40% (9.3 million) dwellings in England had approximately 23.7 million efficiency measures installed, with an average of 2.5 measures per dwelling. Building fabric-related measures were the most frequent (e.g. cavity wall insulation, loft insulation and glazing) with an average of 2.1 million installed each year. Dwellings with the highest number of fabric interventions (the top 20%) were more likely to be found in areas with low income, with more owner-occupied dwellings, experiencing lower winter temperatures, having a lower proportion of flats, and having a slightly higher proportion of older adults and children. Energy efficiency installations have tended to occur among specific types of households or parts of the building stock. These findings have implications for the design of future government programmes for targeting energy efficiency measures to specific household groups or dwelling types. 相似文献
167.
Hydrogenated amorphous silicon films were grown on to thermally oxidized silicon wafers by Radio Frequency magnetron sputtering, and SiNx and Al2O3 capping layers were used to control the residual thermal stress. After annealing, a comparison of the silicon films with and without capping layers indicates that tensile stress induced by the capping layer enhances the crystallinity of the annealed amorphous silicon film. The stress is due to the mismatch between the coefficients of thermal expansion for the capping layer and amorphous silicon film. These results highlight the potential of thermal stress as a means to alter the crystallization in thin film architectures and suggest that even larger effects can be obtained with suitable choices of capping layer chemistry. 相似文献
168.
169.
Philip Yuan 《Architectural Design》2016,86(2):92-99
Philip Yuan , Founding Director of Shanghai-based firm Archi-Union Architects, applies parametric techniques to his design and research in China. Here he explains how Parametricism can provide a highly adaptive and open approach to architectural knowledge and spatial organisation, accommodating regional variations in culture and environment, through an emphasis on local climate, materials and craft traditions. 相似文献
170.
Official architectural education in China remains very traditional and has yet to engage with the digital age. To counter this, Shanghai-based Fab-Union was set up in 2014 to establish a cross-disciplinary community – now over 10,000 strong – that is driving the emergence of digital crafts in the country. Here, its founder Philip Yuan and lead designer Hao Meng describe Fab-Union's online design platform, its offline collective design space, and its robotic factory that functions as an open research facility and fabrication workshop. 相似文献