Relationship between process of withering and aroma characteristics of black tea

Volatile flavour components (VFC), caffeine, crude fibre, ash and total water soluble solids (TSS) were analysed in orthodox and CTC black teas manufactured from normal and hard withered leaves. With the increase of wither, VFC, TSS and caffeine were found to increase but not crude fibre. The withering process in black tea manufacture appears to control the development of terpenoids, improving flavour quality in brewed tea.     

Analysis and design of optimum interleaver for iterative receivers in IDMA scheme

In this paper, we propose a new tree based interleaver (TBI) to generate different chip‐level interleaving sequences for different users in an interleave division multiple access (IDMA) system, which reduces computational complexity. This method of generation also solves the memory cost problem and reduces the amount of information exchange between mobile stations (MSs) and base stations (BSs) required to specify the interleaver. Simulation results are presented to show that the proposed interleavers perform well as compared to random interleavers in an IDMA system. Copyright © 2008 John Wiley & Sons, Ltd.     

Nework topology for maximizing the terminal reliability in a Computer Communication Network

In the design of a Computer Communication Network (CCN), the reliability between any pair of nodes and the maximum permissible installation cost are of great importance. These characteristics are largely dependant upon the topological layout of the links, their costs and reliabilities. Having the knowledge of the topological layout of the various computer centres (nodes) and maximum permissible cost of installing the various links at their pre-assigned positions; in this paper an algorithm for obtaining an optimal network topology which gives the maximum s?t reliability is presented. The developed method is general and is computerized. The proposed method has an additional advantage that the system is not to be redesigned, if at a later stage the permissible cost is enhanced by budgetary provisions. An example illustrates the algorithm.     

A class of efficient tests for increasing-failure-rate-averagedistribution under random censoring

A class of tests for the increasing failure rate average (IFRA) alternatives under random censoring is proposed. The tests are based on a function of the Kaplan-Meier estimator. Most of the IFRA tests in the literature depend on the (nuisance) parameter that appears in the definition of IFRA, and the choice of this parameter is crucial in performing the tests. The proposed class of tests does not have this disadvantage. Under some regularity conditions, the asymptotic normality of the tests is established and asymptotically distribution-free tests are obtained by using estimators for the null standard deviations. The efficacies of the tests under the proportional hazard censoring model are studied. The proposed test is most efficient for the Weibull family of IFRA alternatives among the existing tests available for the censored data. The test is applied to published appliance data     

Biocatalytic Nanoscale Coatings Through Biomimetic Layer‐by‐Layer Mineralization

Recent insight into the molecular mechanisms of biological mineral formation (biomineralization) has enabled biomimetic approaches for the synthesis of functional organic‐inorganic hybrid materials under mild reaction conditions. Here we describe a novel method for enzyme immobilization in thin (nanoscale) conformal mineral coatings using biomimetic layer‐by‐layer (LbL) mineralization. The method utilizes a multifunctional molecule comprised of a naturally‐occurring peptide, protamine (PA), covalently bound to the redox enzyme Glucose oxidase (GOx). PA mimics the mineralizing properties of biomolecules involved in silica biomineralization in diatoms, and its covalent attachment to GOx does not interfere with the catalytic activity. Highly efficient and stable incorporation of this modified enzyme (GOx‐PA) into nanoscale layers (～5–7 nm thickness) of Ti‐O and Si‐O is accomplished during protamine‐enabled LbL mineralization on silica spheres. Depending on the layer location of the enzyme and the type of mineral (silica or titania) within which the enzyme is incorporated, the resulting multilayer biocatalytic hybrid materials exhibit between 20–100% of the activity of the free enzyme in solution. Analyses of kinetic properties (V_max, K_M) of the immobilized enzyme, coupled with characterization of physical properties of the mineral‐bearing layers (thickness, porosity, pore size distribution), indicates that the catalytic activities of the synthesized hybrid nanoscale coatings are largely determined by substrate diffusion rather than enzyme functionality. The GOx‐PA immobilized in these nanoscale layers is substantially stabilized against heat‐induced denaturation and largely protected from proteolytic attack. The method for enzyme immobilization described here enables, for the first time, the high yield immobilization and stabilization of enzymes within continuous, conformal, and nanoscale coatings through biomimetic LbL mineralization. This approach will likely be applicable to a wide variety of surfaces and functional biomolecules. The ability to synthesize thin (nanoscale) conformal enzyme‐loaded layers is of interest for numerous applications, including enzyme‐based biofuel cells and biosensors.     

Crosstalk reduction in mixed-signal 3-D integrated circuits with interdevice layer ground planes

We show nearly 8 dB of crosstalk reduction using ground planes between active device layers in three-dimensional (3-D) integrated circuits. Our experimental work utilizes two planes of MOS transistors with tungsten or polysilicon ground planes designed to attenuate crosstalk. Theoretical simulations, using an electromagnetic solver, and the experimental results are consistent with analytical results. The key result verified is that a ground plane, whose footprint shadows the device area, is sufficiently large for effective attenuation. The interdevice layer ground plane provides an effective means to achieve crosstalk reduction in 3-D mixed-signal/RF integration because of simple fabrication and high coupling isolation.     

A multilevel hybrid anomaly detection scheme for industrial wireless sensor networks

Real-time sensing plays an important role in ensuring the reliability of industrial wireless sensor networks (IWSNs). Sensor nodes in IWSNs have inherent limitations that give rise to different anomalies in the network. These anomalies can lead to disastrous and harmful situations or even serious system failures. This article presents a formulation to the design of an anomaly detection scheme for detecting the anomalous node along with the type of anomaly. The proposed scheme is divided into two major parts. First, spatiotemporal correlation within a cluster is obtained for the normal and anomalous behavior of sensor nodes. Second, the multilevel hybrid classifier is used by combining the sequential minimal optimization support vector machine (SMO-SVM) as a binary classifier with optimally pruned extreme learning machine (OP-ELM) as a multiclass classifier for detection of an anomalous node and type of anomalies, respectively. Mahalanobis distance-based lightweight K-Medoid clustering is used to build a new set of training datasets that represents the original training dataset, by significantly reducing the training time of a multilevel hybrid classifier. Results are analyzed using standard WSN datasets. The proposed model shows high accuracy, i.e., 94.79% and detection rate, i.e., 94.6% with a reduced false positive rate as compared to existing hybrid methods.     

Ball Mill Synthesis of Bulk Quaternary Cu<Subscript>2</Subscript>ZnSnSe<Subscript>4</Subscript> and Thermoelectric Studies

In this work, quaternary chalcogenide Cu₂ZnSnSe₄ (CZTSe) was synthesized using a mechanochemical ball milling process and its thermoelectric properties were studied by electrical resistivity, Seebeck coefficient, and thermal conductivity measurements. The synthesis process comprises three steps viz., wet ball milling of the elemental precursors, vacuum annealing, and densification by hot pressing. The purpose of this is to evaluate the feasibility of introducing wet milling in place of vacuum melting in solid state synthesis for the reaction of starting elements. We report the structural characterization and thermoelectric studies conducted on samples that were milled at 300 rpm and 500 rpm. X-ray diffraction (XRD) analysis showed the existence of multiple phases in the as-milled samples, indicating the requirement for heat treatment. Therefore, the ball milled powders were cold pressed and vacuum annealed to eliminate the secondary phases. Annealed samples were hot pressed and made into dense pellets for further investigations. In addition to XRD, energy dispersive spectroscopy (EDS) studies were performed on hot pressed samples to study the composition. XRD and EDS studies confirm CZTSe phase formation along with ZnSe secondary phase. Electrical resistivity and Seebeck coefficient measurements were done on the hot pressed samples in the temperature range 340–670 K to understand the thermoelectric behaviour. Thermal conductivity was calculated from the specific heat capacity and thermal diffusivity values. The thermoelectric figure of merit zT values for samples milled at 300 rpm and 500 rpm are ～0.15 and ～0.16, respectively, at 630 K, which is in good agreement with the values reported for solid state synthesized compounds.