Effect of chlorination practice on soluble organics

As the practice of chlorination for the disinfection of waste effluents is apparently to be extended, this study was initiated to examine the possibility that chlorinated organics could be formed in the disinfection process. A group of pure compounds that had been demonstrated to be susceptible to chlorination were examined under conditions likely to apply under normal disinfection practice.From the results obtained, it appears only organics with ring structures and electron activating substituents, or amino groupings are capable of chlorination. The frequent presence of ammonia or amino groups means that chloramine formation with its asociated toxicity is likely. However, the presence of ammonia or amino groups will retard the reaction with other compounds making chlorination of these unlikely.     

Conceptual aspects of water re-use

A simplified model of a municipal water recycle system is presented and gives a clear picture of the relationship between process variables such as the intensity of the treatment, the accumulation of pollutants and the number of times the water is re-used. The model can be used to determine the necessary requirements for the treatment process in order to reach a certain desired drinking water quality. This model is extended to cover a variety of practical conditions. It is also shown that accumulation under practical conditions is limited, even if there is no treatment. The model predicts that the recycle system can utilise a low quality supplementary supply, e.g. brackish water. Although the model is derived for a recycle system for domestic water supply it can be used for any closed loop water system.     

Blue mountains sewage transfer scheme: a review of tunnelling

To preserve the natural surroundings of the Blue Mountains of New South Wales while simultaneously serving the needs of the region's growing population, the Sydney Water Board has developed an improved, but complex, sewage transfer scheme for the area. This paper traces the development of the scheme, with particular attention to the geology of the area, the equipment used to construct the tunnels for the project, and elements of the directional drilling that connects the sewer areas to the tunnel.     

Determination of flexibility of beam-to-column connectors used in thin walled cold-formed steel pallet racking systems

This paper describes a new test to determine flexibility of beam-to-column connectors used in conventional pallet racking systems. In this study, two different ways were used to find the flexibility of a connector. The connector developed was tested using the conventional cantilever method [Bajoria, KM. Three dimensional progressive collapse of warehouse racking, PhD Thesis, University of Cambridge, UK 1986], and then also using a newly proposed double cantilever method. To verify the results obtained from both the tests, a full scale frame test was carried out. In the double cantilever test the connector is subjected to three types of forces namely moment, shear and the axial pull by the beams, thereby giving behavior close to practical usage of connectors. Non-linear finite element analysis of both the tests and also of the full scale test were carried out using ANSYS [ANSYS 7.0—User's Manual, ANSYS Inc., 2005] software. The results obtained from the double cantilever test were found to match well with the full scale frame test. The experimental results and the finite element results are compared in this paper.     

Aggregate and concrete microfracture

Thin sections cut from cast concrete cylinders have been examined in transmitted light to investigate the significance of coarse aggregate type in “primary” microfracturing. Concretes manufactured with crushed-rock aggregates and gravel aggregates were studied and, in every case, the dominant fracture type was a parting of the aggregate-matrix bond. Bond cracking was least severe with the marble aggregate where epitaxial calcite over-growth was indicated. The ability of bond cracks to maintain continuity by bridging surface irregularities, via mortar cracks, reduced the inhibiting influence of rough-surfaced aggregate on bond-crack development.     

Lead in glasgow street dirt and soul

The levels of lead in city street dirt and in soil from various locations in Glasgow were investigated during spring 1976. Lead concentrations in street dirt ranged from 150–2300 ppm, mean 960 ppm, and were significantly elevated with respect to the observed “natural” level of 78 ppm. Lead derived from anti-knock compounds in petrol and introduced to the environment via automobile exhausts was clearly implicated as the main source of lead pollution in a series of soil lead measurements at the centre and periphery of eight Glasgow parks.Various chemical leaching techniques were employed and compared. Less than 5% of street dirt and soil lead was found to be associated with the organic phase.     

Cigarette characteristics,smoker characteristics,and the relationship to cigarette fires

Data were collected from eight cities on a wide range of cigarette and smoker characteristics for a sample of smokers. Of these, 564 smokers had had fires and were identified through fire department response to those fires, while the other 1,611 smokers had not had fires and were identified through a telephone sample survey of the communities. The characteristics analyzed included those that had shown evidence of a relationship to the risk of a cigarette-initiated fire, either in laboratory studies or in previous statistical analyses of fire experience.The smoker characteristics analyzed were household income, education, age, gender, and race. The cigarette characteristics analyzed were filter, tobacco column length, filter length, circumference, density, amount of tobacco, menthol, citrate, porosity, and pack type. In addition, a variable was used to control for the smoker's city.After controlling for all smoker characteristics and city, logistic regression modeling showed four cigarette characteristics to be significant: filter, filter length, porosity, and type of pack. Filter, filter length, and porosity all affect air intake, which, therefore, appears to be an important physical element in the combustion process associated with risk. Analysis limited to filtered cigarettes only showed the same characteristics to be significant, plus tobacco column length. Extension of the analysis to two-way interaction terms did not change any of the conclusions on which cigarette characteristics are important, but it did indicate that the role of pack type was different for men and women.Sensitivity analyses, shown in the appendix, supported the main conclusions that cigarette characteristics are significant after controlling for smoker characteristics and that the four specific cigarette characteristics—filter, filter length, porosity, and pack—are the ones that are significant. These analyses checked the impact of cluster sampling, sensitivity to missing data on smoker characteristics, and sensitivity to nonfire smoker cases with responses by people other than the smokers themselves.All this means that there are already cigarettes commercially available that exhibit a reduced propensity for ignition when one controls for smoker characteristics.This report was originally written as the final report in June 1993 as part of CPSC-P-91-1147 Contract Cigarette Fire Incident Study that the National Fire Protection Association conducted for the U.S. Consumer Product Safety Commission.Harwood, formerly with the Consumer Product Safety Commission, is retired.     

Assessment of nitrification in groundwater filters for drinking water production by qPCR and activity measurement

In groundwater treatment for drinking water production, the causes of nitrification problems and the effectiveness of process optimization in rapid sand filters are often not clear. To assess both issues, the performance of a full-scale groundwater filter with nitrification problems and another filter with complete nitrification and pretreatment by subsurface aeration was monitored over nine months. Quantitative real-time polymerase chain reaction (qPCR) targeting the amoA gene of bacteria and archaea and activity measurements of ammonia oxidation were used to regularly evaluate water and filter sand samples. Results demonstrated that subsurface aeration stimulated the growth of ammonia-oxidizing prokaryotes (AOP) in the aquifer. Cell balances, using qPCR counts of AOP for each filter, showed that the inoculated AOP numbers from the aquifer were marginal compared with AOP numbers detected in the filter. Excessive washout of AOP was not observed and did not cause the nitrification problems. Ammonia-oxidizing archaea grew in both filters, but only in low numbers compared to bacteria. The cell-specific nitrification rate in the sand and backwash water samples was high for the subsurface aerated filter, but systematically much lower for the filter with nitrification problems. From this, we conclude that incomplete nitrification was caused by nutrient limitation.     

The relative influence of wind,sunlight and temperature on user comfort in urban outdoor spaces

This paper presents the development of a comfort index that measures adaptivity in outdoor spaces. Over a 9-month period 649 people were surveyed in three locations, in temperatures between 10 and 28 °C. An exploratory factor analysis develops a 15-item scale of comfort that includes measures of adaptivity: clothing, exposure time and seating location. The scale is regressed on physical measures: average instantaneous wind speed; maximum wind speed; mean-exposed radiant temperature; mean-shaded radiant temperature and ambient temperature. The results model the relative contributions of the microclimatic factors for the comfort in the outdoor space. Analyses suggest gustiness and wind speed are most important in determining user satisfaction. There is strong support for the theory that people actively adapt to microclimatic conditions.     

Terrain analysis for development studies: Typical mountainous area along the Eastern Mediterranean coast-lebanon

The limited areal extent of small countries means that reliance has to be placed on mountainous terrain in developing more land needed for continuous growth. These terrains, especially along the Eastern Mediterranean, usually have rugged morphologies which makes their evaluation difficult. The Australian P.U.C.E. system for terrain assessment and classification proved to be an optimal approach for engineering-geology related studies for the above task in the Aley-Chouf area. Basic land properties having an impact on land development are singled out. They constitute mainly the geological formations, relief, drainage, land forms, soils and the vegetation cover. The land divisions used are Province, Pattern and Unit which cover ten rock formations of varying lithologies, water character and stability features. The area is divided into 7 provinces, 26 terrain patterns and 152 units. These land divisions imply finding similar engineering geological problems and applying similar solutions when planning to develop the area, or some other equivalent areas.