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191.
Allan Donnelly 《Network Security》2000,2000(9):8
Sandia National Laboratories already lists the fastest computer in the world (ASCI Red) and the fastest home-assembled computer in the world (C-Plant) among its credentials. Now, the people at Sandia’s US Department of Energy National Security Laboratory are turning their attention toward another arena: developing an intelligent software agent capable of defending against network hackers and computer viruses. 相似文献
192.
Timothy J. White Lalgudi V. Natarajan Pamela F. Lloyd C. Allan Guymon 《Polymer》2007,48(20):5979-5987
The morphology and corresponding performance of holographic polymer dispersed liquid crystals (HPDLCs) based on thiol-ene polymer are dependent on a number of factors including the gel point conversion of the polymer, polymerization kinetics, and extent of liquid crystal (LC) phase separation. Previous research of HPDLC reflection gratings made from thiol-allyl ether polymer indicates that increasing polymerization rate in systems with moderate gel point conversion can improve diffraction efficiency (DE). This work examines HPDLC reflection gratings that contain the ene monomer triallyl isocyanurate (TATATO). In HPDLCs, thiol-TATATO polymerization is two times faster than the thiol-ene polymerization of triallyl ether. By substituting TATATO for triallyl ether, the LC droplet size within HPDLC reflection gratings decreases from 100 nm to 25 nm. The dramatic reduction in LC droplet size for thiol-TATATO HPDLCs increases baseline transmission from 55% in thiol-triallyl ether HPDLCs to 90% at 450 nm. Unfortunately, the DE of thiol-TATATO HPDLCs is only approximately 10% due to poorly defined lamellae in the grating morphology. As determined with real-time IR (RTIR) spectroscopy, thiol-TATATO HPDLCs have significantly faster LC demixing kinetics in comparison to thiol-allyl ether HPDLCs. During holographic photopolymerization, the increased rate of LC demixing causes formation of LC droplets throughout the grating. The low DE of thiol-TATATO HPDLCs can be improved by mixing TATATO and allyl ether monomer. The morphology of ternary thiol-ene HPDLC formulations containing TATATO and allyl ether has a well-defined grating structure due to increased LC solubility in the system, an average LC droplet size of 50 nm, and baseline transmission of nearly 85% at 450 nm. 相似文献
193.
Sensitivity study of a semi-automatic training set generator 总被引:1,自引:0,他引:1
This paper addresses the problem of assessing the robustness with respect to change in parameters of an integrated training and classification routine. Extensions to traditional multivariate statistical methods are applied to perform the classification. Training sets are grown from one or a few seed points by a method that ensures spatial and spectral closeness of observations. Spatial closeness is obtained by requiring connectivity. Spectral closeness is obtained by excluding observations that have high Mahalanobis distances to the training class mean. The marginal effects of changes in the parameters that are input to the seed growing algorithm are evaluated. Initially, the seed is expanded to a small area in order to allow for the estimation of a dispersion matrix. This expansion is controlled by upper limits for the spatial and Euclidean spectral distances from the seed point. Second, after this initial expansion, the growing of the training set is controlled by an upper limit for the Mahalanobis distance to the current estimate of the class centre. Also, the estimates of class centres and dispersion matrices may be continuously updated, or the initial estimates may be used. Finally, the effect of the operator's choice of seed among a number of potential seed points is evaluated. An evaluation of the sensitivity of the seed algorithm with respect to parameter settings is carried out by applying it to the classification of minerals commonly encountered in siliciclastic or carbonate rocks from twelve chemical elements mapped from thin sections by energy-dispersive spectroscopy (EDS) in a scanning electron microscope (SEM), using a standard quadratic classifier. The performance for each parameter setting is measured by the overall misclassification rate on an independently generated validation set. The integrated training and classification method is presently used as a routine petrographical analysis method at Norsk Hydro Research Centre. 相似文献
194.
195.
This article discusses power and sample size calculations for observational studies in which the values of the independent variables cannot be fixed in advance but are themselves outcomes of the study. It reviews the mathematical framework applicable when a multivariate normal distribution can be assumed and describes a method for calculating exact power and sample sizes using a series expansion for the distribution of the multiple correlation coefficient. A table of exact sample sizes for level .05 tests is provided. Approximations to the exact power are discussed, most notably those of J. Cohen (1977). A rigorous justification of Cohen's approximations is given. Comparisons with exact answers show that the approximations are quite accurate in many situations of practical interest. More extensive tables and a computer program for exact calculations can be obtained from the authors. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
196.
Anand Dersingh Ramiro Liscano Allan Jost John Finnson Rajiv Senthilnathan 《Mobile Networks and Applications》2010,15(2):267-282
Controlling access in pervasive environments is crucial and a significant challenge because users and devices can connect
from anywhere which results in users and resources becoming available at any point of time and location depending on the situation.
Access control policies for this type of environment are required to conform to high-level business notions. In pervasive
environments, these high-level notions refer to contexts of the situation which can change unpredictably and must be interpreted
semantically to maintain proper access control. Therefore, it is necessary to have a formal representation that represents
semantics of the contexts, reflects the change of the situation, and can be shared and understood by a policy system. This
paper addresses these issues by introducing a context management system that uses a semantic web approach as an underlying
mechanism to model and represent semantics of the contexts. The system stores current contexts in a semantic knowledge base
which is used by a semantic access control system in order to form access control policies and evaluate policies at run time.
The approach is validated through a proof of concept implementation that includes performance results of the context management
system as it responds to a change of the situation. 相似文献
197.
Chunhua Luo Warren Grigsby Neil Edmonds Allan Easteal Jafar Al‐Hakkak 《应用聚合物科学杂志》2010,117(1):352-360
Reported is the preparation of various condensed tannin stearates and the associated chemical characterization and thermal properties of these products. Stearate esters of condensed tannins from both quebracho and pine bark extracts were prepared in generally high, isolated yields from reaction with stearic acid chloride. Tannin esterification was confirmed by both Fourier transform infrared and nuclear magnetic resonance (NMR), and the average degree of stearate substitution was calculated from 1H‐NMR analysis. Product degree of substitution (DS) was observed to proportionately increase with higher stearic acid chloride ratio with maximum DS values of 4.0 and 5.1 achieved for quebracho and pine tannins, respectively. Thermal analysis revealed that tannin stearate products have increased thermal stability with a degradation onset at significantly higher temperature for those samples possessing relatively greater DS. Analysis using differential scanning calorimetry revealed isolated products to consist of multiple components which exhibit interesting melt behaviors, a likely result from their work up on isolation. However, multiple melt features of the individual components in products were lost on heating to give single, broad melt endotherms due to coalescence of sample components. Furthermore, tannin stearate samples with high DS show relatively greater endothermic melting at higher temperature than those samples with lower DS. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
198.
Spatial scales and methods for dealing with scale have been widely discussed in the water resources literature. Different
spatial processes operate at different scales so interpretations based on data from one scale may not apply to another. Understanding
the behavior of phenomena at multiple-scales of data aggregation is thus imperative to accurate integrations of data and models
at different geographic resolutions. This study tests theoretical concepts of scale by presenting empirical results of multiscale
GIS and statistical analyses on gridded water-availability, water use and population data for the Danube Basin in Europe,
with results corroborated by similar tests in the Ganges (South Asia) and Missouri (North America) Basins. Fine-resolution
datasets were aggregated to coarser grid sizes and standard statistical measures of spatial variability were computed. Statistical
analysis of spatial variability demonstrated two distinctly different cases for unscaled and scaled variables. Results show
that variance (and standard deviation) in unscaled variables like freshwater supply, use and population increases at coarser
scales—contrary to the common assumption of decreasing variability as grid-cell size increases. On the other hand, a decreasing
trend in variability with scale is noted for variables scaled to area or population (like population density, water availability
per capita etc.). Moreover, relationships between variability and scale show strong non-linear trends. No mention of these
relationships has been found in the water resources or socio-economic literature for scale and variability. Regression analyses
suggest that power functions are the most appropriate model to fit trends in increasing variability at multiple scales. These
results can be applied to interpretations of water-stress and water scarcity data and their locations relative to water sources
or topographic barriers. 相似文献
199.
200.
Allan Abraham B. Padama Bhume Chantaramolee Hiroshi Nakanishi Hideaki Kasai 《International Journal of Hydrogen Energy》2014
The absorption of H atom in H-covered Pd(110) (1 × 2) missing-row surface is investigated using density functional theory based calculations. For 1.5 monolayer H coverage, interaction among the adsorbed H atoms is found to be negligible and was verified by analyzing the electronic structure of the system and by comparing the calculated binding energies with low H coverage case. Neither the monoatomic absorption of H nor the assistance from the initially adsorbed H atom explains the experimentally observed presence of subsurface H in Pd(110) at high H coverage. Instead, H absorption is realized through the assistance of incoming H atoms from vacuum. The absorption of H in the H-covered surface is non-activated while the dissociation of H2 is the rate-limiting process. Dissociation on ridge site is energetically more preferred than on trough site and the difference in the activation barrier is elucidated by investigating the electronic structures of the system. 相似文献