Comparison of mechanical properties of ground corn stover,switchgrass, and willow and their pellet qualities

Mechanical and physical properties of ground corn stover, switchgrass, and willow were measured and compared in addition to the quality of pellets. Biomass was size-reduced with two different screen sizes (3.175 and 6.35?mm) and conditioned to obtain samples at two different moisture contents (17.5 and 20% on wet basis). Ground switchgrass had the smallest and willow had the highest D₅₀ when size-reduced with the same screen size. Hydrostatic triaxial compression tests were performed using the cubical triaxial tester to determine the bulk modulus, compression index, and spring-back index at specific unloading pressures (20, 45, 70, and 95?kPa). The trends of pressure vs. volumetric strain and void ratio vs. natural log of pressure were similar for all three materials; however, the magnitudes were different. Willow, size-reduced with 3.175?mm screen size at 17.5% wet basis, had the highest bulk modulus among different conditions of all the three biomass. Pellet durability values for all the three materials were higher than 80%. Corn stover pellets formed with 3.175?mm screen size at 20% wet basis had the highest diametral tensile and axial compressive strengths among different conditions for all the three biomass, however the values were not significantly different (p?>?0.05).     

Measurement of Bulk Mechanical Properties and Modeling the Load-Response of Rootzone Sands. Part 1: Round and Angular Monosize and Binary Mixtures

The bulk mechanical properties of two different types of rootzone sands (round and angular) were measured using a cubical triaxial tester. Two monosize sands (d 50 = 0.375 mm and 0.675 mm) and their 50:50 binary mixtures (d 50 = 0.500 mm) were studied. The compression, shear, and failure responses of the above-mentioned six compositions were analyzed, compared, and modeled. Two elastic parameters (bulk and shear moduli) and two elastoplastic parameters (swelling and consolidation indices) of the six sand compositions were also calculated and compared. The angular sand was more compressible than round sand during isotropic compression. In addition, the angular sands tended to have lower initial bulk density and high porosity values. Among the three different size fractions, the 0.375 mm mixture was least compressible for both sand shapes. The failure strength and shear modulus of the angular sand were higher than the round sands. In addition, due to their simplicity, phenomenological models were developed to predict the compression and shear behavior of the sands. The prediction models were validated using subangular and subround sands. Average relative difference values were calculated to determine the effectiveness of the prediction models. The mean average relative difference values for compression profiles, i.e., volumetric stress vs. volumetric strain, were from 16 % to 39 %, except for the initial load-response portion (< 1 % volumetric strain). The predictive models were effective in reproducing the failure responses: at 17.2 kPa confining pressure, the mean of average relative difference was 23 %; at 34.5 kPa , the mean difference was 24 %.     

Controlling Plastic Flow across Grain Boundaries in a Continuum Model

A framework for modeling controlled plastic flow through grain boundaries using a continuum plasticity theory, phenomenological mesoscopic field dislocation mechanics (PMFDM), is presented in this article. The developed tool is used to analyze the effect of different classes of constraints to plastic flow through grain boundaries, as it relates to dislocation microstructure development and mechanical response of a bicrystal. It is found that in the case of low misorientation angle between adjacent grains, impenetrable grain boundaries cause significant work hardening as compared to penetrable grain boundaries due to the accumulation of excess dislocations along them. However, a penetrable grain boundary with a high misorientation angle effectively behaves as an impenetrable boundary, with respect to the stress-strain response.     

The European construction industry and its competitiveness: a construct of the European Commission

The 'European construction industry' is a fiction that tends to obscure its heterogeneous character and to mar studies and policies of the European Commission aimed at improving the internal and external 'competitiveness' of the sector. In order to assess the process of integration in Europe under the impact of its own dynamics as well as Union policies, this paper looks at the dynamics of the sector from three different aspects: as investment, production and labour process. It shows, in particular, the persistent regional and social disparities dividing the industry into separate entities. Political attention tends to focus on a small number of construction companies competing for a few projects which represent the European dimension. Yet, these companies still rely on their respective national bases and local labour from the place where construction is carried out. Persistent divisions between the states are also reflected in the low level of transnational organization of the construction industry. The policy of the European Commission generally ignores these divisions and attempts to establish principles intended to make a whole sector more 'competitive', while its component parts, operating at hugely different levels of productivity, do not even meet on the same market. This paper argues that, instead of trying in vain to introduce a 'knock-out' system of competition in the EU Member States, a targeted approach might help raise productivity in lagging regions and thus improve the basis of competitiveness on global markets.     

Suppression of fuel and air stream diluted methane–air partially premixed flames in normal and microgravity

The effects of fuel and air stream dilution (ASD) with carbon dioxide on the suppression of normal and microgravity laminar methane–air partially premixed coflow jet flames were experimentally and numerically investigated. Experiments were conducted both in our normal-gravity laboratory and at the NASA Glenn Research Center 2.2 s drop tower. Measurements included flame topology and liftoff heights of diluted flames, critical diluent mole fractions for flame blowout, and the radiant heat loss from flames. The flames were also simulated using an axisymmetric unsteady numerical code that utilizes detailed chemistry and transport models. In addition, counterflow flame simulation results were used to examine similitude between the counterflow and coflow flame suppression, and further characterize the effectiveness of fuel stream versus ASD on flame extinction. A smaller relative fuel stream dilution (FSD) extinguishes partially premixed flames (PPFs) with increasing premixing as compared to dilution of the air stream. Conversely, smaller ASD is required to extinguish PPFs as they become less premixed and approach nonpremixed (NP) behavior. Fuel stream diluted PPFs and air stream diluted NP flames extinguish primarily through a reactant dilution effect while fuel stream diluted NP flames and air stream diluted PPF are extinguished primarily by a thermal cooling effect. Normal gravity flames lift off and blow out with a smaller diluent mole fraction than microgravity flames. The difference between the fuel and ASD effectiveness increases as the gravitational acceleration is reduced. Radiation heat losses are observed to increase with increasing diluent mole fraction and decreasing gravity.     

Release of stored thermochemical energy from dehydrated salts

Thermochemical materials, particularly salt hydrates, have significant potential for use in thermal energy storage applications. When a salt hydrate is heated to a threshold temperature, a chemical reaction is initiated to dissociate it into its anhydrous form and water vapor. The anhydrous salt stores the sensible energy that was supplied for dehydration, which can be later extracted by allowing cooler water or water vapor to flow through the salt, transforming the stored energy into sensible heat. We model the heat release that occurs during a thermochemical hydration reaction using relations for mass and energy conservation, and for chemical kinetics and stoichiometry. A set of physically significant dimensionless parameters reduces the number of design variables. Through a robust sensitivity analysis, we identify those parameters from this group that more significantly influence the performance of the heat release process, namely a modified Damköhler number, the thermochemical heat capacity, and the heat flux and flowrate. There is a strong nonlinear relationship between these parameters and the process efficiency. The optimization of the efficiency with respect to the parameters provides guidance for designing engineering solutions in terms of material selection and system properties.