A Highly Efficient Non‐Fullerene Organic Solar Cell with a Fill Factor over 0.80 Enabled by a Fine‐Tuned Hole‐Transporting Layer

With rapid development for tens of years, organic solar cells (OSCs) have attracted much attention for their potential in practical applications. As an important photovoltaic parameter, the fill factor (FF) of OSCs stands for the effectiveness of charge generation and collection, which significantly depends on the properties of the interlayer and active layer. Here, a facile and effective strategy to improve the FF through hole‐transporting layer (HTL) modification is demonstrated. By mixing WO_x nanoparticles with a poly(3,4‐ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) emulsion, the surface free energy of the HTL is improved and the morphology of the active layer is optimized. Benefiting from increased carrier lifetime, a device based on WO_x:PEDOT:PSS HTL exhibits a boosted performance with an FF of 80.79% and power conversion efficiency of 14.57% PCE. The results are certified by the National Institute of Metrology (NIM), which, to date, are the highest values in this field with certification. This work offers a simple and viable option of HTL modification to realize highly efficient OSCs.     

CtpB Facilitates Mycobacterium tuberculosis Growth in Copper-Limited Niches

Copper is required for aerobic respiration by Mycobacterium tuberculosis and its human host, but this essential element is toxic in abundance. Copper nutritional immunity refers to host processes that modulate levels of free copper to alternately starve and intoxicate invading microbes. Bacteria engulfed by macrophages are initially contained within copper-limited phagosomes, which fuse with ATP7A vesicles that pump in toxic levels of copper. In this report, we examine how CtpB, a P-type ATPase in M. tuberculosis, aids in response to nutritional immunity. In vitro, the induced expression of ctpB in copper-replete medium inhibited mycobacterial growth, while deletion of the gene impaired growth only in copper-starved medium and within copper-limited host cells, suggesting a role for CtpB in copper acquisition or export to the copper-dependent respiration supercomplex. Unexpectedly, the absence of ctpB resulted in hypervirulence in the DBA/2 mouse infection model. As ctpB null strains exhibit diminished growth only in copper-starved conditions, reduced copper transport may have enabled the mutant to acquire a “Goldilocks” amount of the metal during transit through copper-intoxicating environments within this model system. This work reveals CtpB as a component of the M. tuberculosis toolkit to counter host nutritional immunity and underscores the importance of elucidating copper-uptake mechanisms in pathogenic mycobacteria.     

Liquid Letters

Using the interfacial jamming of cellulose nanocrystal (CNC) surfactants, a new concept, termed all‐liquid molding, is introduced to produce all‐liquid objects that retain the shape and details of the mold with high fidelity, yet remain all liquid and are responsive to external stimuli. This simple process, where the viscosity of the CNC dispersion can range from that of water to a crosslinked gel, opens tremendous opportunities for encapsulation, delivery systems, and unique microfluidic devices. The process described is generally applicable to any functionalized nanoparticles dispersed in one liquid and polymer ligands having complementary functionality dissolved in a second immiscible liquid. Such sculpted liquids retain all the characteristics of the liquids but retain shape indefinitely, very much like a solid, and provide a new platform for next‐generation soft materials.     

Dialdehyde Starch Hydrazones: Preparation and Properties of Cationic Dispersions

Cationic dialdehyde starch (DAS) dispersions have been prepared in water at 15% concentration by a new cooking procedure. A stable fluid form of cationic DAS, a wet- and dry-strength agent for paper, should facilitate commercial use. Cationic DAS dispersions of pH 3.0 stored in polyethylene containers at 25°C or below were unchanged after 6 months; other storage conditions were also evaluated. An unexpected benefit of the new preparative conditions was a 40% reduction of cationizing agent, betaine hydrazide hydrochloride, without loss of effectiveness. Further savings may be possible by blending cationic DAS with unmodified starch; wet- and dry-strength improvements were maintained in paper with a blend containing 33% unmodified starch and 67% cationic DAS.     

CME Forum: a response to “Construction flow index: a metric of production flow quality in construction”

The study of types of flow in construction is a relatively new field. This paper reviews the work of Sacks et al. and reveals that they have applied a production-line metaphor with recognition of two production flows. Process flow: locations are equated with products moving down a production line. Operations flow: work crews are equated to work stations. Their work proposes an index of the quality of production flow in construction, but the research design has three significant flaws: the skilled interpretation of flow-line charts is not in turn applied to the interpretation of their example charts; the conceptual framework does recognize that the underlying metaphor requires levels of detail in both location and task that is not supported in their analysis. The meaning of “quality of flow” in this context is not defined. This debate raises important epistemological questions for those working in lean construction and location-based management. While the concept of “production flow quality” is important, the Sacks et al. methodology does not address the detailed planning of individual crews. It is only possible to apply the production-line metaphor if micro-management is adopted as detailed planning.     

Impact of carbon fibre/epoxy corrugated cores

The dynamic compressive response of corrugated carbon-fibre reinforced epoxy sandwich cores has been investigated using a Kolsky-bar set-up. Compression at quasi-static rates up to v₀ = 200 ms⁻¹ have been tested on three different slenderness ratios of strut. High speed photography was used to capture the failure mechanisms and relate these to the measured axial compressive stress. Experiments show significant strength enhancement as the loading rate increases. Although material rate sensitivity accounts for some of this, it has been shown that the majority of the strength enhancement is due to inertial stabilisation of the core members. Inertial strength enhancement rises non-linearly with impact velocity. The largest gains are associated with a shift to buckle modes composed of 2–3 half sine waves. The loading rates tested within this study are similar to those that are expected when a sandwich core is compressed due to a blast event.     

An industrial organization economic supply chain approach for the construction industry: a review

Understanding industries in terms of the concepts of chains, clusters and networks is becoming increasingly important in economies around the world. Supply chain management for an individual organization is an emerging field of research in the construction management discipline, but less attention has been devoted to investigating the nature of the construction supply chains and their industrial organizational economic environment. This selected review of construction and mainstream management supply chain literature is organized around four themes; distribution, production, strategic procurement management and industrial organization economics, and highlights the need to develop an industrial organization economic supply chain framework for construction. The merging of the supply chain concept with the industrial organization model as a methodology for understanding firm conduct and industry structure and performance is an important contribution to both construction supply chain and construction economic theory. Much of the industrial organization supply chain literature has tended to focus upon manufacturing industries, where typically firms are permanent organizations. This raises issues as to the differences between industries founded upon temporary compared with permanent organizations. There is potential for the development of an industrial organization methodology applicable to the project based industry. Ultimately industrial organization research seeks to have direct implications for industry performance and government policies.     

A construction project cash flow model—an idiographic approach

The paper introduces and supports the contention that an idiographic methodology is appropriate to the post- hoc study and interpretation of individual construction project cash flows. A cash flow model based on the logit transformation is proposed to be consistent with this methodology. The model is based on historical data, and yields two parameters to describe each individual project. The model is tested using two samples totalling 72 projects. Goodness of fit for the model, using a measure of standard deviation from 1.0% to 4.6%, with a median of 2.5%, is found for individual projects.

The experimental hypothesis (that there is substantial variation between projects) is supported by the graphical and statistical evidence of deviation, which is argued to be the result of the individual ontology of each project - systematic error - rather than random error from an ideal. The paper concludes that forecasts of individual cash flows are invalid when derived from analysis of grouped data.