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91.
92.
Asymmetric Contribution of Aromatic Interactions Stems from Spatial Positioning of the Interacting Aryl Pairs in β‐Hairpins 下载免费PDF全文
Kamlesh Madhusudan Makwana Dr. Radhakrishnan Mahalakshmi 《Chembiochem : a European journal of chemical biology》2014,15(16):2357-2360
Isolated aromatic interactions in designed octapeptide β‐hairpin scaffolds display a near‐universal T‐shaped face‐to‐edge geometry in all positional permutations, with the exception of aryl‐Trp interactions. The heterogeneous asymmetric indole ring of Trp competes for a “shielding” face geometry, which lowers the scaffold stability in FtE aryl‐Trp pairs. Assessment of the contributions of aryl pairs (in the absence of solvent‐driven interactions) to the overall β‐hairpin structure reveals the superiority of Trp‐Phe and Trp‐Tyr contributions over the well‐established scaffold stabilization by Trp‐Trp. 相似文献
93.
Starting with Darwin, biologists have asked how populations evolve from a low fitness state that is evolutionarily stable to a high fitness state that is not. Specifically of interest is the emergence of cooperation and multicellularity where the fitness of individuals often appears in conflict with that of the population. Theories of social evolution and evolutionary game theory have produced a number of fruitful results employing two-state two-body frameworks. In this study, we depart from this tradition and instead consider a multi-player, multi-state evolutionary game, in which the fitness of an agent is determined by its relationship to an arbitrary number of other agents. We show that populations organize themselves in one of four distinct phases of interdependence depending on one parameter, selection strength. Some of these phases involve the formation of specialized large-scale structures. We then describe how the evolution of independence can be manipulated through various external perturbations. 相似文献
94.
This paper reinvestigates the energy consumption–GDP growth nexus in a panel error correction model using data on 20 net energy importers and exporters from 1971 to 2002. Among the energy exporters, there was bidirectional causality between economic growth and energy consumption in the developed countries in both the short and long run, while in the developing countries energy consumption stimulates growth only in the short run. The former result is also found for energy importers and the latter result exists only for the developed countries within this category. In addition, compared to the developing countries, the developed countries’ elasticity response in terms of economic growth from an increase in energy consumption is larger although its income elasticity is lower and less than unitary. Lastly, the implications for energy policy calling for a more holistic approach are discussed. 相似文献
95.
V.R. Radhakrishnan M. Ramasamy H. Zabiri V. Do Thanh N.M. Tahir H. Mukhtar M.R. Hamdi N. Ramli 《Applied Thermal Engineering》2007,27(17-18):2791-2802
The crude preheat train (CPT) in a petroleum refinery consists of a set of large heat exchangers which recovers the waste heat from product streams to preheat the crude oil. In these exchangers the overall heat transfer coefficient reduces significantly during operation due to fouling. The rate of fouling is highly dependent on the properties of the crude blends being processed as well as the operating temperature and flow conditions. The objective of this paper is to develop a predictive model using statistical methods which can a priori predict the rate of the fouling and the decrease in heat transfer efficiency in a heat exchanger. A neural network based fouling model has been developed using historical plant operating data. Root mean square error (RMSE) of the predictions in tube- and shell-side outlet temperatures of 1.83% and 0.93%, respectively, with a correlation coefficient, R2, of 0.98 and correct directional change (CDC) values of more than 92% show that the model is adequately accurate. A case study illustrates the methodology by which the predictive model can be used to develop a preventive maintenance scheduling tool. 相似文献
96.
Gurusubrahmaniyan Subrahmaniyan Radhakrishnan Sule Ozev 《Journal of Electronic Testing》2011,27(4):465-476
In this paper, we propose a methodology for adaptive modeling of analog/RF circuits. This modeling technique is specifically
geared towards evaluating the response of a faulty circuit in terms of its specifications and/or measurements. The goal of
this modeling approach is to compute important test metrics, such as fail probability, fault coverage, and/or yield coverage
of a given measurement under process variations. Once the models for the faulty and fault-free circuit are generated, we can
simply use Monte-Carlo sampling (as opposed to Monte-Carlo simulations) to compute these statistical parameters with high
accuracy. We use the error budget that is defined in terms of computing the statistical metrics and the position of the threshold(s)
to decide how precisely we need to extract the necessary models. Experiments on LNA and Mixer confirm that the proposed techniques
can reduce the number of necessary simulations by factor of 7 respectively, in the computation of the fail probability. 相似文献
97.
The constitutional liquation of NbC wrought alloy 718 is discussed in terms of a diffusion couple between NbC and they matrix in a pseudo-ternary of γ-NbC-Laves. Theoretical arguments are presented to show that the diffusion path cannot be
a straight line connecting the terminal compositions. Experimental results indicate the existence of the NbC-γ diffusion couple
and also support the hypothesis that the diffusion path is not a straight line connecting NbC and γ. Consequently, the temperature
at which carbide liquation can occur is below the equilibrium NbC solidus, and hence, carbide liquation is constitutional
in nature. The lowest temperature at which carbide liquation initiates depends upon the extent of deviation of the diffusion
path from the straight line path. The dependence of the relative volume fractions of carbide and Laves phase in cast alloys
on Nb/C ratio is explained using the γ-NbC-Laves pseudo-ternary. The Laves phase present in cast alloys is shown to liquate
at the terminal eutectic temperature of the alloy, which could be lower than the carbide liquation temperature. 相似文献
98.
99.
Briggs F. Cekleov M. Creta K. Khare M. Kulick S. Kumar A. Lily Pao Looi Natarajan C. Radhakrishnan S. Rankin L. 《Micro, IEEE》2002,22(2):36-47
Architects based the Intel 870 system architecture on the scalability port, a coherent system interconnect. The system's building-block approach lets a single chip set support a wide range of server segments. 相似文献
100.