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11.
    
Additives are often blended into polymers to improve specific performance features of the finished film. Erucamide is a common slip agent used to reduce a film's coefficient of friction (COF), which is a good attribute for high speed packaging operations. Because such additives must migrate to the surface to be effective, this study focuses on erucamide blooming to the surface of linear low-density polyethylene (LLDPE) films. Both the surface and bulk concentrations of erucamide were measured over time to determine the equilibrium additive partitioning. The surface concentration was determined by surface washing for different time intervals and extrapolated back to a “zero” time to offset the solvent extraction of additive from the bulk film. The bulk concentration was determined by a deep microwave extraction. Initial experiments with forced aging at 60°C showed significant evaporative losses of erucamide. The final work focused on room temperature, at whcih additive evaporation was negligible. The room temperature blooming results showed that the erucamide surface and bulk concentrations reached equilibrium within 24 hours. The data also showed that erucamide surface concentration increased with initial additive loading for a fixed film thickness and with increased film thickness for a fixed additive concentration.  相似文献   
12.
In a study with 36 Sprague-Dawley pups it was found that Ss that experienced garlic flavor during 21 days of nursing (in mother's milk) and for a 5-day period after weaning drank considerably more garlic solution over 12 days of testing than did Ss nursed by water-imbibing mothers and weaned on water. Still other Ss that had garlic either during nursing or after weaning manifested intermediate garlic preferences over these same tests, though the initial intake of garlic was greater in the former condition. The durability of such preferences was demonstrated in a 2nd series of 6 daily tests given 1 mo later when the same ordering of groups recurred. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
13.
The traditional college classroom teaching method of lecture and assigned readings was compared with an individual programed instructional method utilizing a programed text. 21 pairs of Ss, matched according to sex, age, intelligence test score, and hours of formal training in the biological sciences, were 1st tested upon completion of the physiological portion of an introductory psychology course. They were then retested 6 wk. later. No significant differences were found in performance on Test 1. However, the level of performance on Test 2 was significantly higher for the program-instructed group. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
14.
Under conditions representative of ignited tokamak operation, ion energy losses are likely to be dominated by transport due to deviation from toroidal field axisymmetry. This asymmetry, termed ripple, induces several distinct physical processes, all of which lead to enhanced ion thermal conduction above the neoclassical value. The net impact of these processes on ignition dynamics is analyzed for an INTOR-like plasma by means of a 1 1/2-D transport code. The radial shift of the plasma to regions of higher ripple during plasma heating results in a substantial broadening of the window of values of ripple consistent with favorable ignition and burn characteristics and also provides some measure of automatic burn control. Because-limiting processes are also prime candidates for burn control, the profiles obtained from the transport analyses are examined for stability with respect to ideal MHD modes. The MHD-limited value increases as the plasma is heated and in fact in the burn phase approaches the value characteristic of a shape-optimized MHD equilibrium. The sensitivity of the transport and MHD results to the choice of plasma density is examined, and it is found that hot-ion mode operation is precluded for devices such as INTOR unless present estimates of both ripple losses and-limits are highly pessimistic.  相似文献   
15.
Methyl esters from seed oils of four Chenopodiaceae species are unusual in that they contain methylcis-5-hexadecenoate (4.6–12%) and methyl 5-octadecenoate (1.1–1.2%). There are indications of small amounts of 18∶25,9 and 18∶35, 9, 12 along with unsaturated acids commonly found in seed oils-oleic (14–21%), linoleic (53–57%) and linolenic (3.5–7.8%). Fatty acid composition of the oils was determined by gas chromatography, and positions of the double bonds were established by application of gas chromatography-mass spectrometry to the methoxylated methyl esters. N. Market. Nutr. Res. Div., ARS, USDA.  相似文献   
16.
Elastic properties are found to be critical parameters for polymers which improve the wrinkle resistance of cotton fabric. Those molecular factors which results in optimum recovery of a polymer film from distortion (i.e., stretching) are shown to be directly related to the ability to improve fabric wrinkle recovery. Further, those molecular factors which inhibit the tendency of a polymer to form ordered structures allow the inherent flexibility of the polymer to be utilized in storing energy of distortion. This energy is then available, if the polymer is properly distributed on the fabric, to help overcome the fabric's frictional resistance to recovery. The most advantageous distribution of polymer is one in which interfiber and interyarn elastic bridges are formed.  相似文献   
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The fracture toughness of dental nanocomposites fabricated by various methods of mixing, silanization, and loadings of nanoparticles had been characterized using fatigue-precracked compact-tension specimens. The fracture mechanisms near the crack tip were characterized using atomic force microscopy (AFM), transmission electron microscopy (TEM), and scanning electron microscopy (SEM). The near-tip fracture processes in the nanocomposties were identified to involve several sequences of fracture events, including: (1) particle bridging, (2) debonding at the poles of particle/matrix interface, and (3) crack deflection around the particles. Analytical and finite-element methods were utilized to model the observed sequences of fracture events to identify the source of fracture toughness in the dental nanocomposites. Theoretical results indicated that silanization and nanoparticle loadings improved the fracture toughness of dental nanocomposites by a factor of 2-3 through a combination of enhanced interface toughness by silanization, crack deflection, as well as crack bridging. A further increase in the fracture toughness of the nanocomposites can be achieved by increasing the fracture toughness of the matrix, nanofilled particles, or the interface.  相似文献   
19.
Lunatic fringe belongs to a family of beta1-3 N-acetyltransferases that modulate the affinity of the Notch receptors for their ligands through the elongation of O-fucose moieties on their extracellular domain. A role for Notch signaling in vertebrate fertility has been predicted by the intricate expression of the Notch receptors and their ligands in the oocyte and granulosa cells of the ovary and the spermatozoa and Sertoli cells of the testis. It has been demonstrated that disruption of Notch signaling by inactivation of lunatic fringe led to infertility associated with pleiotropic defects in follicle development and meiotic maturation of oocytes. Lunatic fringe null males were found to be subfertile. Here, we report that gene expression data demonstrate that fringe and Notch signaling genes are expressed in the developing testis and the intratesticular ductal tract, predicting roles for this pathway during embryonic gonadogenesis and spermatogenesis. Spermatogenesis was not impaired in the majority of the lunatic fringe null males; however, spermatozoa were unilaterally absent in the epididymis of many mice. Histological and immunohistochemical analysis of these testes revealed the development of unilateral cystic dilation of the rete testis. Tracer dye experiments confirm a block in the connection between the rete testis and the efferent ducts. Further, the dye studies demonstrated that many lunatic fringe mutant males had partial blocks of the connection between the rete testis and the efferent ducts bilaterally.  相似文献   
20.
    
Commercially available dental composite resins undergo polymerization shrinkage during curing, setting up internal stress that can result in debonding at the tooth‐composite interface, tooth fracture and composite failure. Debonding can also lead to marginal leakage and recurrent decay. The presence of a compliant phase, in this case polybutadiene in aggregate form with fumed silica, is shown to reduce polymerization shrinkage in the bis‐GMA/TEGDMA resin system. The addition of a small amount of the plasticizer triphenylethylene promoted additional reduction in cure shrinkage by reducing the glass transition temperature, Tg. A trend toward reduced cure shrinkage was noted as the polybutadiene : silica ratio decreased within each molecular weight of polybutadiene tested. The optimal formulation tested was determined to be 0.25 wt. % triphenylethylene in bis‐GMA with aggregates formed from polybutadiene of molecular weight 2–3 million, in a polybutadiene : silica ratio of 0.005. Shrinkage reduction in this system was ~ 42% without loss of Knoop hardness. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 2306–2310, 2005  相似文献   
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