Hydroxyapatite spheres with controlled porosity for eye ball prosthesis: processing and characterization

Porous hydroxyapatite spheres were prepared by a modified gelcasting method producing a ceramic prosthesis with controled porosity. The spheres are approximately 2.2 cm in diameter with a relatively homogeneous pore size distribution from 10 to 40 m in diameter. The samples were characterized by X-ray powder diffractometry (XRD) and Fourier transform infra-red spectroscopy (FTIR) to identify the phases both prior to and after the gelcasting process. Surface morphology analysis and porosity evaluations were performed with scanning electron microscopy (SEM), while surface area measurements were carried out by the BET technique. © 2001 Kluwer Academic Publishers     

A Mexican psychology.

The universality—not the scientific character—of psychology is challenged by data previously reported by the present author and other researchers suggesting the need for a sociocultural psychology of personality. Specific factorial scales of Mexican, natural language, and sociocultural premises are found to be meaningfully associated, at three different ages, with a number of reliable measures of psychological dimensions. A national, local-belief-based, clinical understanding of Mexican youth on the basis of intra- and cross-cultural studies is illustrated. From the evidence, it is proposed (a) that culture, as defined, can account for significant variance of bona fide psychological and other behavioral science dimensions; and (b) that there is a basis to speak about sociocultural psychologies, such as a Mexican psychology. The disclosure is made in the context of the author's attempts to understand the Mexican personality and society. (38 ref) (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Morphological and chemical changes in human deciduous dentin after phosphoric acid,self‐etching adhesive and Er: YAG laser conditioning

The morphological and chemical changes in deciduous dentin produced by different conditioning protocols were evaluated in this in vitro study. Eighty primary dentin samples were divided into eight groups (n = 10): G1, acid etching; G2, self‐etching adhesive; G3, G4, Er: YAG laser irradiation at 25.5 and 38.2 J cm^?2, respectively; 10 Hz and spray irrigation. Groups 5, 6, 7, and 8 were irradiated at previous densities, and then phosphoric acid or self‐etching adhesive conditioning was applied. Scanning electron microscopy (SEM) and energy dispersive X‐ray spectroscopy (EDS) were used to evaluate chemical and morphological changes. Paired t‐test and One‐way ANOVA were used for statistical analysis (p ≤ 0.05). All samples showed different morphology with specific characteristics according to the conditioning protocol. Changing element concentration values are expressed in atomic percent (at %). After conditioning, there were statistically significant differences (p ≤ 0.05) for p at% and Ca/P in all groups; highlighting the following additional findings by group: G1, G7, and G8 showed changes in all elements studied, G2 presented a decrease in C at% and increased Ca at%, G3 and G4 exhibited at% changes in C, trace elements and Ca. Furthermore, G5 showed at% changes in O and trace elements; while G6 changes were observed on C at%, O at% and trace elements at%. Dentin morphology and chemical composition varied in accordance with the conditioning protocol, with characteristics specific for each one that could have clinical implications for the retention and bond strength performance of adhesive materials.     

Synthesis, characterization and evaluation of NiMo/SiO2–Al2O3 catalysts prepared by the pH-swing method

NiMo/(X)SiO₂–Al₂O₃ catalysts were synthesized with various SiO₂ contents (X = 0, 10, 25 and 50 wt%) using the pH-swing method. In order to find the optimum SiO₂ content, the catalysts were evaluated in the hydrodesulfurization of 4,6-DMDBT, hydrogenation of naphthalene and hydrodenitrogenation of carbazole. Kinetic parameters of Langmuir–Hinshelwood type equations for all the reaction systems were estimated. FTIR analysis of CO adsorption for the sulfided catalysts shows that the amount of coordinatively unsaturated Mo sites promoted by nickel (CUS-NiMoS) follows the order NiMo/10ASA > NiMo/25ASA > NiMo/0ASA. This tendency agrees with the results obtained in catalytic activity.     

Singularly perturbed implicit control law for linear time‐varying delay MIMO systems

This paper proposes a control scheme for the problem of stabilizing partly unknown multiple‐input multiple‐output linear time‐varying retarded systems. The control scheme is composed by a singularly perturbed controller and a reference model. We assume the knowledge of a number of structural characteristics of the system as the boundedness and the knowledge of the bounds for the unknown parameters (and their derivatives) that define the system matrices, as well as the structure of these matrices. The results presented here are a generalization of previous results on linear time‐varying Single‐Input Single‐Output (SISO) and multiple‐input multiple‐output systems without delays and linear time‐varying retarded SISO systems. The closed‐loop system is a linear singularly perturbed retarded system with uniform asymptotic stability behavior. The uniform asymptotic stability of the singularly perturbed retarded system is guaranteed. We show how to design a control law such that the system dynamics for each output is given by a Hurwitz polynomial with constant coefficients. Copyright © 2015 John Wiley & Sons, Ltd.     

A new stabilisation approach for level-set based topology optimisation of hyperelastic materials

Structural and Multidisciplinary Optimization - This paper introduces a novel computational approach for level-set based topology optimisation of hyperelastic materials at large strains. This, to...     

Stabilization of the planar vertical take-off and landing using nonlinear feedback control

This article presents a new control strategy for the well-known problem of the planar vertical take-off and landing. The total thrust is computed using a nonlinear feedback compensation so that the altitude reaches the desired altitude. The horizontal position x is then controlled by choosing the orientation angle as a smooth saturation function of x and . A proof of convergence is presented using a Lyapunov approach. The proposed control strategy is successfully tested in numerical simulations.     

Additive and dominance effects of the αs1-casein locus on milk yield and composition traits in dairy goats

The objective of this study was to evaluate the effects of the CSN1S1 locus polymorphism on 305-d records of milk, fat, protein, lactose and total solids yields, fat, protein, lactose and total solids contents in Mexican dairy goats. A total of 514 lactation records belonging to Alpine (n=60), Saanen (n=105) and Toggenburg (n=74) goats, born from 2003 to 2006 in three herds were used. Discrimination between alleles E, F, N, A* (CSN1S1 A, G, H, I, O1 and O2) and B* (CSN1S1 B1, B2, B3, B4, C and L) were made by amplification of fragments of the gene CSN1S1 and digestion with the restriction endonuclease XmnI. In order to estimate additive and dominance effects, data sets including (1) all genotypes, and (2) only homozygote genotypes, were analysed using linear mixed models. The allele A*, had significant additive effects for protein content (0·21±0·07%; P=0·002) and total solids content (0·66±0·23%; P=0·005) when compared with allele F. An unfavourable additive effect of allele A* on milk yield was found in the Alpine breed (-81·4±40·2; P=0·046) when compared with allele F. Favourable dominance effects were found for some genotypes (P<0·05) for milk yield (A*N and B*N), fat yield (A*N and B*E), protein yield (A*N and B*E), lactose yield (A*N) and total solids yield (A*N). Also, unfavourable dominance effects were found (P<0·05) for protein content (A*B* and A*N) and total solids content (A*B*, A*N, and A*F). Allele A* was the only one with a positive effect for protein content. Significant allele-year interaction effects were also observed. The presence of significant dominance effects, estimated between specific pairs of alleles, challenged the purely additive nature of the genetic effect at the CSN1S1 locus. Implications from use of CSN1S1 effects in goat breeding programmes are presented.     

Modeling and vibration mode analysis of a ball screw drive

Positioning systems for machine tools are generally driven by ball screws due to their high stiffness and low sensitivity to external perturbations. However, as modern machine tools increase their velocity and acceleration of positioning, the resonant modes of these systems could be excited degrading the trajectory tracking accuracy. Therefore, a dynamic model including the vibration modes is required for machine design as well as for controller selection and tuning. This work presents a high-frequency dynamic model of a ball screw drive. The analytical formulation follows a comprehensive approach, where the screw is modeled as a continuous subsystem, using Ritz series approximation to obtain an approximate N-degree-of-freedom model. Based on this model, the axial and angular components of each mode function are studied for different transmission ratios to determine the degree of coupling between them. After that, the frequency variation of each mode was studied for different carriage positions and different moving masses. Finally, an analysis of these results applied to controller design and parameter estimation is also presented.     

Assessment of the Prony's method for BWR stability analysis

It is known that Boiling Water Reactors are susceptible to present power oscillations in regions of high power and low coolant flow, in the power-flow operational map. It is possible to fall in one of such instability regions during reactor startup, since both power and coolant flow are being increased but not proportionally. One other possibility for falling into those areas is the occurrence of a trip of recirculation pumps. Stability monitoring in such cases can be difficult, because the amount or quality of power signal data required for calculation of the stability key parameters may not be enough to provide reliable results in an adequate time range. In this work, the Prony's Method is presented as one complementary alternative to determine the degree of stability of a BWR, through time series data. This analysis method can provide information about decay ratio and oscillation frequency from power signals obtained during transient events. However, so far not many applications in Boiling Water Reactors operation have been reported and supported to establish the scope of using such analysis for actual transient events. This work presents first a comparison of decay ratio and frequency oscillation results obtained by Prony's method and those results obtained by the participants of the Forsmark 1 & 2 Boiling Water Reactor Stability Benchmark using diverse techniques. Then, a comparison of decay ratio and frequency oscillation results is performed for four real BWR transient event data, using Prony's method and two other techniques based on an autoregressive modeling. The four different transient signals correspond to BWR conditions from quasi-steady to power oscillations. Power signals from such transients present a challenge for stability analysis, either because of the low number of data points or need of much iteration, and thus reducing their capability for real time analysis. The results show that Prony's method can be a complementary reliable tool in determining BWR's stability degree.