Der Einfluß des Umwandlungsverhaltens auf die Schweißeigenspannungen bei Stahl

Untersuchung des Schrumpfungs- und Umwandlungsverhaltens von Schweißproben aus austenitischem und hochfestem Grund- und Schweißzusatzwerkstoff. Messung von Eigenspannungen im Schweißnahtbereich. Erklärung der Eigenspannungen aus Temperaturverläufen und Härtemessungen im Schweißnahtbereich sowie aus Weg-Zeit-Aufschreibungen für das freie Ende einseitig eingespannter Schweißproben. Deutung der Umwandlungsvorgänge durch Zeit-Temperatur-Umwandlungsschaubilder.     

Evaporation of crude oil at sea

A simple model for describing the simultaneous evaporation and spreading of oil spills at sea has been developed and tested. A previously reported theory was used for calculating the aerodynamic part of the evaporation process. Here, the thermodynamic part, i.e. the oil characterization and the weathering processes, is described in detail. By comparison with the results of laboratory evaporation experiments and sea trials the model is shown to work quite adequately. Also, the influence of the mixing of oil into the water column, e.g. due to wave action, is shown to be small enough to be neglected. The spreading model was purposely kept as simple as possible, in view of the uncertain influences of wave action and emulsion formation. The velocity of the edge of the oil slick is prescribed and a critical thickness beyond which the slick stops spreading is introduced. The latter turns out to have a significant influence on the rate of evaporation. Examples of crude evaporation are given and the influence of temperature and wind velocity is investigated.     

Co-deposition of aluminide and silicide coatings on γ-TiAl by pack cementation process

Thermochemical analyses were carried out for a series of pack powder mixtures for deposition of aluminide and for co-deposition of aluminide and silicide coatings on -TiAl by the pack cementation process. Based on the results obtained, experimental studies were undertaken to identify optimum pack powder mixtures for depositing adherent and coherent aluminide and silicide coatings. Pack powder mixtures activated by 2 wt% AlCl₃ was used to aluminise -TiAl at 1000°C. With proper control of pack compositions and coating conditions, an aluminide coating of TiAl₃ with a coherent structure free from microcracking was deposited on the substrate surface via inward diffusion of aluminium. The results of thermochemical calculations indicated that co-deposition of Al and Si is possible with CrCl₃ · 6H₂O and AlCl₃ activated pack powders containing elemental Al and Si as depositing sources. Experimental results obtained at 1100°C revealed that CrCl₃ · 6H₂O is not suitable for use as an activator for co-depositing aluminide and silicide coatings on -TiAl. It caused a significant degree of degradation instead of coating deposition to the substrate. However, adherent coatings with excellent structural integrity consisting of an outer TiSi₄ layer and an inner TiAl₃ layer were successfully co-deposited at 1100°C and 1000°C using pack powder mixtures activated by AlCl₃. IT is suggested that such coatings were formed via a sequential deposition mechanism through inward diffusion of aluminium and silicon. Discussion is presented on the issues that need to be considered to ensure the deposition of aluminide and silicide coatings with coherent structure free from microcracking on -TiAl by the pack cementation process.     

The Transmogrifier-2: a 1 million gate rapid-prototyping system

This paper describes the Transmogrifier-2 (TM-2), a second-generation multifield programmable gate array (FPGA) rapid-prototyping system. The largest version of the system will comprise 16 boards that each contain two Altera 10K50 FPGA's, four I-Cube interconnect chips, and up to 8 Mbytes of memory. The inter-FPGA routing architecture of the TM-2 uses a novel interconnect structure, a nonuniform partial crossbar, that provides a constant delay between any two FPGA's in the system. The TM-2 architecture is modular and scalable, meaning that systems of various sizes can be constructed from copies of the same board, while maintaining routability and the constant delay feature. Other features include a system-level programmable clock that allows single-cycle access to off-chip memory, and programmable clock waveforms with edge resolution of 10 ns. The first Transmogrifier-2 boards have been manufactured and are functional. They have recently been used successfully in some simple graphics acceleration applications     

A guided wave inspection technique for nuclear steam generator tubing

The utility of guided ultrasonic waves for increasing the efficiency and sensitivity of nuclear steam generator tubing evaluation by nondestructive means is explored. The basic theoretical background of guided waves in tubes is presented, with major emphasis placed on those results with direct relevance to NDE applications. The possibility of increasing the inspection range of the guided wave modes as well as their sensitivity to defects by proper choice of mode and frequency is also discussed.     

X-ray microtomography shows pore structure and tortuosity in alkali-activated binders

Durability of alkali-activated binders is of vital importance in their commercial application, and depends strongly on microstructure and pore network characteristics. X-ray microtomography (μCT) offers, for the first time, direct insight into microstructural and pore structure characteristics in three dimensions. Here, μCT is performed on a set of sodium metasilicate-activated fly ash/slag blends, using a synchrotron beamline instrument. Segmentation of the samples into pore and solid regions is then conducted, and pore tortuosity is calculated by a random walker method. Segmented porosity and diffusion tortuosity are correlated, and vary as a function of slag content (slag addition reduces porosity and increases tortuosity), and sample age (extended curing gives lower porosity and higher tortuosity). This is particularly notable for samples with ≥ 50% slag content, where a space-filling calcium (alumino)silicate hydrate gel provides porosity reductions which are not observed for the sodium aluminosilicate (‘geopolymer’) gels which do not chemically bind water of hydration.     

Visualizing green oil in live algal cells

We report here that BODIPY 505/515, a green lipophilic fluorescent dye, serves as an excellent vital stain for the oil-containing lipid bodies of live algal cells. BODIPY 505/515 vital staining can be used in combination with fluorescent activated cell sorting to detect and isolate algal cells possessing high lipid content.     

Non-financial barriers to combined heat and power in the United States - A qualitative study

The economic viability of new energy technologies is held as a central tenet to their future deployment; conventional wisdom posits economically rational decision-makers will readily invest in proven low-risk and affordable technologies. But what happens when this is not true. This paper examines the non-financial barriers facing economically viable Combined Heat and Power (CHP) projects. CHP is a mature and lower carbon technology that efficiently uses waste heat from thermal electricity generation; CHP can also provide flexibility services to help integrate variable renewable resources. CHP is low risk and many industrialized countries, particularly those in colder climates in Northern Europe and Russia, generate as much as 50% of their electricity and heat needs from CHP, but United States deployment remains low and investment hurdle rates high. While lower U.S. energy costs make some projects un-economic, many economically-viable CHP projects are stalled or killed by non-financial barriers. To better understand why financially viable CHP projects are not getting built, developers, owners and operators, regulators, and other stakeholders of this technology were interviewed and three major barriers emerged a) the business model of the electrical utility b) negative subjective impressions and c) challenges in allocating the risks and benefits.     

Quantitative probing the interfacial structure of TPO/CPO blends by transmission electron microscopy via EDX

High-resolution scanning transmission electron microscope (HR STEM) measurements were performed on a thermoplastic polyolefin (TPO) substrate coated with chlorinated polyolefin (CPO). This CPO was a maleated chlorinated polypropylene containing 21.8 wt% Cl. The TPO investigated was a blend of high-modulus isotactic polypropylene (iPP) with a crystalline ethylene-butene copolymer (EB9) containing 9 wt% butene. For these injection-molded samples, examined ca. 10 mm from the mold gate, a stratified morphology found at TPO surface consisting of thin fibers of EB9 trapped in a transcrystalline iPP matrix, with crystalline lamellae propagating from the matrix across the EB9 domains. This structure was unperturbed when the plaques were coated (from tetrahydrofuran solution) with a 5 μm layer of CPO, but underwent changes of increasing severity when subjected either to a dry bake at 120 °C or annealing at 120 °C in the presence of xylene vapor. The interfacial structure between the CPO and the TPO was probed by TEM with energy dispersive X-ray imaging (EDX). The elemental chlorine across the interface gave good fits to a tan h function, and the interface thickness increased from 23 ± 2 nm to 28 ± 1 nm upon annealing at 120 °C for 30 min. After annealing in the presence of xylene vapor, this value increased to 50 ± 4 nm. As reference points, we determined an interface thickness of 29 ± 3 nm for the CPO-EB interface and 15 ± 2 nm for the interface between CPO and iPP.     

Enzymatic transesterification for production of biodiesel using yeast lipases: An overview

Biodiesel has provided an eco-friendly solution to fuel crisis, as it is renewable, biodegradable and a non-toxic fuel that can be easily produced through enzymatic transesterification of vegetable oils and animal fats. Enzymatic production of biodiesel has many advantages over the conventional methods as high yields can be obtained at low reaction temperatures with easy recovery of glycerol. Microbial lipases are powerful biocatalysts for industrial applications including biodiesel production at lower costs due to its potential in hydrolyzing waste industrial materials. Among them, lipases from yeasts, Candida antarctica, Candida rugosa, Cryptococcus sp., Trichosporon asahii and Yarrowia lipolytica are known to catalyze such reactions. Moreover, stepwise addition of methanol in a three step, two step and single step reactions have been developed using yeast lipases to minimize the inhibitory effects of methanol. The latest trend in biodiesel production is the use of whole-cell as biocatalysts, since the process requires no downstream processing of the enzyme. Synthesis of value added products from the byproduct glycerol further reduces the production cost of biodiesel. This review aims at compiling the information on various yeast lipase catalyzed transesterification reactions for greener production of biodiesel.