Formation of layered structure on bismuth-borate glass surface

X-ray diffraction analysis shows that the transformation during heat treatment from amorphous to crystalline phases of bismuth-borate glass samples takes place in sequences. After a short heat treatment, 5 min at 550 °C, a layered structure with a preferred orientation of crystallites on the surface is observed. After a long heat treatment, 8 h at the same temperature, normal polycrystalline bulk samples are obtained.     

Factors affecting prior austenite grain size in low alloy steel

The effect of varying normalising and hardening temperatures on the prior austenite grain size in a low alloy Cr–Mo–Ni–V steel has been examined. An initial relative insensitivity of grain size to increasing austenitising temperature was observed followed by a sudden growth of grains at approximately 1000 °C. A detailed study of the precipitates in the steel showed the presence of a bimodal size distribution of vanadium carbides. The grain size increase is attributed to a decrease in volume fraction and an increase in size of V₄C₃ particles with increasing temperature.     

Identification of microstructural zones and thermal cycles in a weldment of modified 9Cr-1Mo steel

This paper presents the results of a study on the microstructural and microchemical variations in a multipass Gas Tungsten Arc weld (GTAW) of modified 9Cr-1Mo steel. The changes brought about in the steel due to the heating and cooling cycles during welding and the subsequent effects due to reheating effects during multipass welding are described. Detailed analytical transmission electron microscopy has been carried to study the type and composition of the primary and secondary phases in this steel. The systematic changes in microstructural parameters such as Prior Austenite Grain Size, martensite lath size, number density, size and microchemistry of carbides, have been understood based on the different transformations that the steel undergoes during the heating and cooling process. Based on the observed microstructure, an attempt has been made to identify distinct microstructural zones and possible thermal cycles experienced by different regions of the weldment.     

Effect of copper additions in directly quenched titanium–boron steels

The present study concerns the effect of copper additions on the microstructural evolution and mechanical properties of directly quenched Ti–B steels. Ti and B are added as microalloying elements with an aim of achieving adequate austenite hardenability and Cu is added to retard the austenite (γ) → ferrite (α) transformation. Therefore, the microalloying and Cu additions together allow the transformation of austenite to occur at a lower temperature, resulting in a finer microstructure containing martensitic constituents. The direct-quenching route is adopted with an aim of facilitating the nucleation of the constituent phases from the deformed austenite. In order to circumvent the hot-shortness due to the Cu addition, 0.79 wt% Ni has been added to one of the 1.5 wt% Cu microalloyed steels. The present study has demonstrated that the Ni-containing 1.5Cu–Ti–B steel is capable of providing an attractive combination of strength and ductility comparable to the high strength varieties of HSLA steels in directly quenched condition.     

On structural and high temperature electrochemical properties of ZrO2 thin film coating on Zr metal produced by carbonate melt

Melt of NaCO₃ can favor oxidation of Zr to form ZrO₂ thin film on Zr surface, which is used to make Zr/ZrO₂ oxidation/reduction electrode of pH sensor for testing elevated temperature aqueous solutions. Using SEM, EPMA, XPS, EXAFS and HRTEM, we found that ZrO₂ film is tightness and solid with 20 μm thickness composed by nanometer-sized monoclinic crystals. Zr/ZrO₂ interface is characterized of zoning structure according to topography and chemical composition in five zones: oxygen-rich ZrO₂, ZrO₂, oxygen-rich Zr metal, oxygen-bearing Zr and Zr from outmost to center. Melt oxidation process of Zr involved oxidation time, air and temperature. The air is important effect on structural and electrochemical properties of ZrO₂ thin film for making elevate temperature electrochemical sensor. If oxygen air largely presented in carbonate melting process, ZrO₂ thin film is not tightness and not for oxidation/reduction electrode.     

Critical slowing down in lead magnesium niobate–zirconate ceramic

Dielectric relaxation behaviour of (1 − x)PMN − xPZ, for x = 0.10, 0.30 and 0.40 have been studied. The nature of relaxational behaviour was found to change with PZ concentration. A crossover from a static freezing to critical slowing down like behaviour is observed with increase in Zr⁴⁺ concentration. We have used Glazounov and Tangastev criterion to distinguish freezing and critical slowing down like behaviour.     

Synthesis and characterization of morphologically different high purity gallium oxide nanopowders

High purity gallium oxide nanopowders have been synthesized by using a simple precipitation technique with calcination at elevated temperature. From the X-ray pattern, the phase purity of the synthesized powders was confirmed as β-Ga₂O_3. Elemental quantification (stoichiometry) of Ga₂O₃ was also examined from the X-ray energy dispersive analysis (EDAX). Based on the recorded Fourier Transform Infrared (FTIR) spectrum of Ga₂O_3, the IR bands due to Ga–O bond and crystal lattice vibrations have been identified in the wavenumber range 400–4,000 cm⁻¹. From the measured SEM images, it is obvious to notice that the pH value has been playing a dominant role in obtaining morphologically different gallium oxide nanopowders. Thermogravimetric analysis reveals 8.3% of weight loss when the sample was heated to the temperature of 1,100 °C from the room temperature, which also shows a crystalline phase transformation. It is very interesting to report that a broad blue emission at 455 nm has been measured from the synthesized gallium oxide nanopowders.     

Hydrogen adsorption studies in micro-size cobalt dots

Hydrogen desorption curves were obtained from a sample composed of a square arrangement of Co dots with average diameter of 4.4 μm, separated by a distance of 11.6 μm. A macroscopic sample of Co dots grown on a 2.5 × 2.5 cm Si substrate was made by standard lithographic techniques and used in these experiments. Thermal programmed desorption (TPD) was performed under ultra-high vacuum conditions. Hydrogen TPD curves were obtained from a 1 × 1 cm Co dots samples displaying a maximum of intensity at 425 K. Hydrogen TPD curve was also obtained from 1 cm× 1 cm samples of Co films and Co foils for comparison. The hydrogen TPD curves have decreasing intensity from the Co foils to the Co dots and finally to the Co films. This indicates that there are more sites for hydrogen adsorption on the Co dots than in the Co films. This is a surprising result because there is approximately 8.7 times less Co atoms exposed in the Co dots that in the Co film sample. A desorption energy of 27 kcal/mol was obtained for the Co dots suggesting that hydrogen is adsorbed on an hcp hollow site of the Co dot crystalline structure.     

A review on the synthesis of in situ aluminum based composites by thermal,mechanical and mechanical–thermal activation of chemical reactions

The aim of the present paper is to review the recent progress in the synthesis of in situ particle reinforced aluminum composites using thermal, mechanical and combined mechanical-thermal activation of aluminothermic reduction reactions. The combination of combustion synthesis (CS) and mechanosynthesis (MS) is the most recent development in the processing of advanced materials like micro and nano aluminum based composites. The combined mechanical thermal synthesis (MTS) has widened the possibilities for both CS and MS. MTS holds great potential for commercial viability and offers exciting processing route for the synthesis of advanced materials. Enhanced reaction kinetics and extended concentration limits in MTS are demonstrated by illustrating the synthesis of aluminum based nanocomposite involving Al–CeO₂.