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71.
The potential of a range of polymer-based activated carbons to remove a non-steroidal anti-inflammatory drug ibuprofen from protein containing and protein-free solutions was studied. The adsorption capacity of five activated carbons produced from phenol-formaldehyde resin precursors (MAST Carbon Ltd) was compared to a cellulose coated activated carbon Norit RBX used in a commercial Adsorba®300C haemoperfusion column (Gambro).Ibuprofen adsorption was studied in batch experiments over 24 h at pH=7.6 and 25 °C and adsorption equilibrium data were correlated with the Langmuir and Freundlich equations.Results showed that uncoated mesoporous MAST carbons can remove ibuprofen from model solutions both in the presence and absence of serum albumin. Ibuprofen is a highly protein-bound drug and the presence of serum albumin significantly affects the adsorption of ibuprofen by cellulose-coated microporous carbon used in Adsorba®300C column. 相似文献
72.
O'Reilly-Wapstra JM Potts BM McArthur C Davies NW Tilyard P 《Journal of chemical ecology》2005,31(3):519-537
Hybridization in plants provides an opportunity to investigate the patterns of inheritance of hybrid resistance to herbivores, and of the plant mechanisms conferring this resistance such as plant secondary metabolites. We investigated how inter-race differences in resistance of Eucalyptus globulus to a generalist mammalian herbivore, Trichosurus vulpecula, are inherited in their F1 hybrids. We assessed browsing damage of three-year-old trees in a common environment field trial on four hybrid types of known progeny. The progency were artificial intra-race crosses and reciprocal inter-race F1 hybrids of two geographically distinct populations (races) of E. globulus; north-eastern Tasmania and south-eastern Tasmania. Populations of trees from north-eastern Tasmania are relatively susceptible to browsing by T. vulpecula, while populations from south-eastern Tasmania are more resistant. We assessed the preferences of these trees in a series of paired feeding trials with captive animals to test the field trial results and also investigated the patterns of inheritance of plant secondary metabolites. Our results demonstrated that the phenotypic expression of resistance of the inter-race F1 hybrids supported the additive pattern of inheritance, as these hybrids were intermediate in resistance compared to the pure parental hybrids. The expression of plant secondary metabolites in the F1 hybrids varied among groups of individual compounds. The most common pattern supported was dominance towards one of the parental types. Together, condensed tannins and essential oils appeared to explain the observed patterns of resistance among the four hybrid types. While both chemical groups were inherited in a dominant manner in the inter-race F1 hybrids, the direction of dominance was opposite. Their combined concentration, however, was inherited in an additive manner, consistent with the phenotypic differences in browsing. 相似文献
73.
Albert W. Alexander Bodhisattwa Chaudhuri AbdulMobeen Faqih Clive Davies 《Powder Technology》2006,164(1):13-21
The flow dynamics of cohesive powders is investigated in rotating cylinders with an L : R ratio of 3 : 1 using experiments and DEM simulations. Flow onset and steady-state behavior are compared for free-flowing (cohesionless) dry glass beads, wet glass beads, and “dry” cohesive powders (lactose, microcrystalline cellulose). The avalanching dynamics of powders is substantially different from those observed for free-flowing or wet-cohesive glass beads. Dry cohesive powders exhibit history-dependent flow dynamics, significant dilation, aperiodic avalanche frequencies, and variable avalanche size. These behaviors also provide a route for effective characterization of cohesive forces under dilated conditions characteristic of unconfined flows. 相似文献
74.
The strength, S , of ceramic and glass fibers often can be estimated from fractographic investigation using the fracture mirror radius, r m , and the relationship S = A m /( r m )1/2 , where A m is the "mirror constant." The present work estimates the value of A m for Tyranno® Si-Ti-C-O fibers in situ in a three-dimensional woven SiC/SiC-based composite to be 2.50 ± 0.09 MPa·m1/2 . This value is within the range of 2–2.51 MPa·m1/2 previously obtained for nominally similar Nicalon® Si-C-O fibers. 相似文献
75.
76.
The formation of non-stoichiometric cubic perovskite solid solutions based on BaZn1/3 Nb2/3 O3 (BZN) was examined along 10 different directions in the BaO–ZnO–Nb2 O5 ternary system. Limited ranges of non-stoichiometry were observed along several pseudo-binaries and the BZN structure can accommodate a variety of different types of defects. Although the deviations from stoichiometry are quite small, typically ∼1 mole%, they induce large changes in the extent and stability of the 1:2 B-site ordering, the sintering and microstructure, and the dielectric loss properties. The highest Q × f s (∼110 000 at 8 GHz) in the system, which coincide with the highest degree of order, were located in two regions along the BZN–Ba5 Nb4 O15 and BZN–BaNb2 O6 lines. The results of this study provide an explanation for the large variations in crystal structure and Q × f s previously reported for BZN and other related systems (e.g., Ba(Zn1/3 Ta2/3 )O3 ), and demonstrate that non-stoichiometric starting compositions provide a route to the highest Q values. 相似文献
77.
Norman S. Allen Kenneth O. Fatinikun A.Keith Davies Barry J. Parsons Glyn O. Phillips 《Dyes and Pigments》1981,2(3):219-229
The photofading of two anthraquinone dyes has been studied in aqueous solution using ultraviolet-visible absorption spectroscopy and flash photolysis. The influence of alcohol concentration, pH, atmosphere, photosensitisers and stabilisers have been examined and these lead to some important conclusions on the mechanism of dye fading. Essentially, the results indicate the photoexcited triplet state of the dye undergoes a process of either electron or hydrogen-atom abstraction depending on the nature of the environment. Other factors such as aggregation and singlet oxygen also appear to play an important role in solution photofading. The relevance of these results to photofading in a polymeric phase is discussed. 相似文献
78.
Simon P. Davies 《International journal of human-computer interaction》2013,29(4):325-346
This article reviews the extensive literature emerging from studies concerned with skill acquisition and the development of knowledge representation in programming. In particular, it focuses upon theories of program comprehension that suggest programming knowledge can be described in terms of stereotypical knowledge structures that can in some way capture programming expertise independently of the programming language used and in isolation from a programmer's specific training experience. An attempt is made to demonstrate why existing views are inappropriate. On the one hand, programs are represented in terms of a variety of formal notations ranging from the quasi‐mathematical to the near textual. It is argued that different languages may lead to different forms of knowledge representation, perhaps emphasizing certain structures at the expense of others or facilitating particular strategies. On the other hand, programmers are typically taught problem‐solving techniques that suggest a strict approach to problem decomposition. Hence, it seems likely that another factor that may mediate the development of knowledge representation, and that has not received significant attention elsewhere, is related to the training experience that programmers typically encounter. In this article, recent empirical studies that have addressed these issues are reviewed, and the implications of these studies for theories of skill acquisition and for knowledge representation are discussed. In conclusion, a more extensive account of knowledge representation in programming is presented that emphasizes training effects and the role played by specific language features in the development of knowledge representation within the programming domain. 相似文献
79.
80.
We describe the design, fabrication, testing, and antenna-range demonstration of a photonic wavelengthmultiplexed true-time-delay steering system for use with broadband phased-array antennas. The prototype system is based on a unique hardware-compressive architecture and can drive 16 antenna elements over the 0.35-2.1-GHz band with 6-bit angular resolution over a ±45° scan angle. 相似文献