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A technique for forming Langmuir films from antibodies based on an amphiphilic polyelectrolyte was developed. The physicochemical and immunochemical properties of the Langmuir films obtained were studied. The interaction of HBsAg with the films was found to be described by a model with one binding site, whereas that of HBsAg with antibodies adsorbed on a polystyrene plate, by a model with a positive cooperativity. The use of the novel Langmuir films from antibodies increases the sensitivity of the immunoenzyme assay.  相似文献   
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Two derivations of the loss parameter R, entirely from wave considerations in the presence of a metallic interface, are presented. R, which represents surface losses, occurs in transmission line equations for propagation of the voltage across the plates and of the current in the plates. Explanation of the surface losses involves some radiation of the interior fields into the metallic surfaces that absorb electromagnetic energy, and that ultimately convert it into ohmic losses (heat). Although the approach may restrict the derivation to a planar interface, i.e., to a parallel-plate transmission line, that restriction is not so essential that it cannot be softened  相似文献   
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Surface recombination velocities as low as 10 cm/s have been obtained by treated atomic layer deposition (ALD) of Al2O3 layers on p-type CZ silicon wafers. Low surface recombination is achieved by means of field induced surface passivation due to a high density of negative charges stored at the interface. In comparison to a diffused back surface field, an external field source allows for higher band bending, that is, a better performance. While this process yields state of the art results, it is not suited for large-scale production. Preliminary results on an industrially viable, alternative process based on a pseudo-binary system containing Al2O3 are presented, too. With this process, surface recombination velocities of 500–1000 cm/s have been attained on mc-Si wafers.  相似文献   
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Anomalous diffusion profiles of Ag in single crystalline CdTe were observed using the radiotracer 111Ag. The diffusion anneals were performed at 800 K under Cd or Te vapor and in vacuum with low Ag concentrations. The measured Ag profiles directly reflect the distribution of the self-interstitials and vacancies of the Cd sublattice and are the result of chemical self-diffusion which describes the variation of the deviation from stoichiometry of the binary crystal as a function of depth and time. It turned out that the spread of the Ag dopant essentially is determined by the drift of the charged defects within the electric field caused by the distribution of the extrinsic and intrinsic defects.  相似文献   
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A new calculation procedure for free‐volume parameters is considered in this work by using viscosity prediction methods and the Levenberg‐Marquardt calculation scheme. All parameters used in the Vrentas–Duda free‐volume theory can be estimated from pure component properties. The prediction results are compared with experimental data for some polymer/solvent systems. The diffusion coefficient calculated by Vrentas–Duda theory can be used in the modeling of membrane separation processes. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008  相似文献   
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A revised and greatly improved version of the 3D continuum radiative transfer code MC3D is presented. It is based on the Monte Carlo method and solves the radiative transfer problem self-consistently. It is designed for the simulation of dust temperatures in arbitrary geometric configurations and the resulting observables: spectral energy distributions, wavelength-dependent images, and polarization maps. The main objective is the investigation of “dust-dominated” astrophysical systems such as young stellar objects surrounded by an optically thick circumstellar disk and an optically thin(ner) envelope, debris disks around more evolved stars, asymptotic giant branch stars, the dust component of the interstellar medium, and active galactic nuclei.  相似文献   
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