Transient and isotopic studies of the oxygen transport and exchange during oxidative coupling of methane on Sr promoted La2O3

Isotopic transient techniques were applied to study oxidative coupling of methane over lanthanum oxide and strontium promoted La₂O₃ catalysts. Results of the¹⁸O₂/¹⁶O₂ isotopic exchange experiments indicate that Sr promotion increases oxygen uptake from the lattice of the catalyst. Oxygen self diffusion coefficients, which were determined for the series of lanthana catalysts, reach a maximum for the 1% Sr/La₂O₃. Steps of¹⁸O₂ in the presence of a steady flow of methane over Sr/La₂O₃ catalysts, indicate that surface and bulk oxygen appear in the reaction products before gas-phase¹⁸O². Steps of CO₂ over catalysts in which lattice oxygen has been exchanged with¹⁸O₂, show that gas/solid exchange involves over 50% of the lattice oxygen. Under reaction conditions, methane pulses with no gas-phase oxygen yield negligible amounts of products which indicates that methane interacts with lattice oxygen only in the presence of the gas-phase oxygen.     

A predicted three-dimensional structure of human cytochrome P450: implications for substrate specificity

A three-dimensional structure for human cytochrome P450IA1 waspredicted based on the crystal coordinates of cytochrome P450camfrom Pseudomonas putida. As there was only 15% residue identitybetween the two enzymes, additional information was used toestablish an accurate sequence alignment that is a prerequisitefor model building. Twelve representative eukaryotic sequenceswere aligned and a net prediction of secondary structure wasmatched against the known -helices and ß-sheets ofP450cam. The cam secondary structure provided a fixed main-chainframework onto which loops of appropriate length from the humanP450IA1 structure were added. The model-built structure of thehuman cytochrome conformed to the requirements for the segregationof polar and nonpolar residues between the core and the surface.The first 44 residues of human cytochrome P450 could not bebuilt into the model and sequence analysis suggested that residues1–26 formed a single membrane-spanning segment. Examinationof the sequences of cytochrome P450s from distinct gene familiessuggested specific residues that could account for the differencesin substrate specificity. A major substrate for P450IA1, 3-methyl-cholanthrene,was fitted into the proposed active site and this planar aromaticmolecule could be accommodated into the available cavity. Residuesthat are likely to interact with the haem were identified. Thesequence similarity between 59 eukaryotic enzymes was representedas a dendrogram that in general clustered according to genefamily. Until a crystallographic structure is available, thismodel-building study identifies potential residues in cytochromeP450s important in the function of these enzymes and these residuesare candidates for site-directed mutagenesis.     

Quantitation of the human basal ganglia with positron emission tomography: a phantom study of the effect of contrast and axial positioning

The accurate measurement of the concentration of a radioisotope in small structures with positron emission tomography (PET) requires a correction for quantitation loss due to the partial volume effect and the effect of scattered radiation. To evaluate errors associated with measures in the human basal ganglia (BG), a unilateral model of the BG has been inserted in a 20-cm cylinder. The recovery coefficient (RC=measured activity/true activity) for the BG phantom has been measured on a CTI tomograph with different background concentrations (contrast) and at different axial locations in the gantry. The BG was visualized on four or five slices, depending on its position in the gantry and on the contrast used. The RC was 0.75 with no background (contrast equal to 1.0). Increasing the relative radioactivity concentration in the background increased the RC from 0.75 to 2.00 when the contrast was -0.7 (BG相似文献   

Computing Minimum Area Homologies

Calculating and categorizing the similarity of curves is a fundamental problem which has generated much recent interest. However, to date there are no implementations of these algorithms for curves on surfaces with provable guarantees on the quality of the measure. In this paper, we present a similarity measure for any two cycles that are homologous, where we calculate the minimum area of any homology (or connected bounding chain) between the two cycles. The minimum area homology exists for broader classes of cycles than previous measures which are based on homotopy. It is also much easier to compute than previously defined measures, yielding an efficient implementation that is based on linear algebra tools. We demonstrate our algorithm on a range of inputs, showing examples which highlight the feasibility of this similarity measure.     

Oblivious transfer and quantum channels as communication resources

We show that from a communication-complexity perspective, the primitive called oblivious transfer—which was introduced in a cryptographic context—can be seen as the classical analogue to a quantum channel in the same sense as non-local boxes are of maximally entangled qubits. More explicitly, one realization of non-cryptographic oblivious transfer allows for the perfect simulation of sending one qubit and measuring it in an orthogonal basis. On the other hand, a qubit channel allows for realizing non-cryptographic oblivious transfer with probability roughly 85 %, whereas 75 % is the classical limit.     

Frame-level temporal calibration of video sequences from unsynchronized cameras

This paper describes a method for temporally calibrating video sequences from unsynchronized cameras by image processing operations, and presents two search algorithms to match and align trajectories across different camera views. Existing multi-camera systems assume that input video sequences are synchronized either by genlock or by time stamp information and a centralized server. Yet, hardware-based synchronization increases installation cost. Hence, using image information is necessary to align frames from the cameras whose clocks are not synchronized. The system built for temporal calibration is composed of three modules: object tracking module, calibration data extraction module, and the search module. A robust and efficient search algorithm is introduced that recovers the frame offset by matching the trajectories in different views, and finding the most reliable match. Thanks to information obtained from multiple trajectories, this algorithm is robust to possible errors in background subtraction and location extraction. Moreover, the algorithm can handle very large frame offsets. A RANdom SAmple Consensus (RANSAC) based version of this search algorithm is also introduced. Results obtained with different video sequences are presented, which show the robustness of the algorithms in recovering various range of frame offsets for video sequences with varying levels of object activity.     

游戏是什么？

18年前,电子游戏是一个叫“小霸王”的红盒子,伴随着《魂斗罗》“上上下下左右左右BABA”按键下的30条命和《超级玛丽》踩乌龟得到的无数命,我们在懵懂之中第一次见到了那些叫做秘技的非热型性疑似Bug。于是．我们的童年开始与电视游戏密不可分。     

Flux creep and fishtail in melt-textured and single-crystalline YBa2Cu3O7

Time-dependent decay of the magnetic moment and magnetization measurements were used to study pinning and flux creep in two samples with and without aj(B) maximum in nonzero field (fishtail effect). From both measurements theE(j) relation was reconstructed forBc and the characteristic current exponent was obtained. At highj and lowB values are between 1 and 4; with increasingB passes a maximum and approaches negative values. At lowj is below 0.5 and not dependent onB orj. This behavior, which is qualitatively the same in both samples, is compared with proposed phase diagrams of the vortex lattice. Large values are correlated with the plateau of the normalized creep rateS 0.025; both observations indicate low relaxation and are found in that lowB region for whichj(B) has its minimum. This observation rejects a dominating influence of relaxation on the fishtail effect.     

Preparation,characterization and wear behaviour of TiNx-coated cermets obtained by plasma-enhanced chemical vapour deposition

Commercial cermet inserts were coated with titanium nitride by plasma-enhanced chemical vapour deposition (PECVD) using a pulsed direct current (d.c.) glow discharge. The influence of the coating parameters on the deposition rate, on the layer composition, on the layer-substrate interface, on the structure and on the microhardness of the layers was investigated for deposition temperatures in the range 500–700 °C. The adhesive strengths, and some mechanical properties, of the coated cermets were characterized by scratch tests, by friction wear investigations and by measurement of the transverse rupture strength. The wear behaviour was examined in the cutting tests. It was found that TiN _x -coatings deposited with a sufficiently high deposition rate and plasma power density have a low oxygen and chlorine content and that they are nearly stoichiometric. The layers usually have a columnar structure with a 200 texture. A granular, equiaxed structure was observed within a small range of deposition conditions. In interrupted and continuous turning tests with steel and grey cast iron, a high cutting performance of the coated inserts, which depended on the coating thickness and on the deposition temperature, was achieved.