钴卟啉三嗪类化合物的合成与表征

以单羟基苯基钴卟啉与三聚氯氰为原料,通过亲核取代反应合成了钴卟啉的三嗪类化合物,以硅胶为固定相,二氯甲烷为洗脱剂采用柱层析的方法对产物进行分离和提纯。最后采用紫外可见光谱、红外光谱等手段对合成产物进行了结构表征,对主要的紫外光谱、红外光谱吸收带进行了经验归属,初步确定了合成产物的结构。     

煤气化过程中单颗粒吸收剂脱硫反应模型概述

对煤气化过程中吸收剂脱硫反应的气固反应模型进行了概述.气固反应模型大致可分为未反应缩核模型,晶粒模型、孔模型及逾渗模型等几种基本型式.未反应缩核模型结构比较简单,可以作为其它模型的基础和组成部分,晶粒模型应用较为广泛且已经得到了充分的发展和改进,孔模型侧重于颗粒内部孔隙特性对反应影响的分析,逾渗模型则基于孔模型将逾渗理论引入来描述脱硫反应过程.     

电力市场中基于混沌理论的电价预测研究

随着电力市场化的不断深入,边际电价预测的重要性将愈来愈凸显,己成为广大发电企业普遍关注的焦点.如何开展边际电价预测以及如何提高边际电价预测的准确性成为迫切需要解决的问题.结合混沌理论,演绎出新的电价预测方法.     

改进灰色模型在中长期电力负荷预测中的应用

针对中长期电力系统负荷预测,在前人已有成果的基础之上,对普通灰色模型进行了改进.一方面对历史数据进行二次平滑处理,大大消除了干扰因素;另一方面利用带有马尔可夫链符号估计的残差修正技术对未来残差的符号进行预测以修正灰色模型的预测结果.以某地区多年以来的历史数据为基础,建立了数学模型,通过实际数据计算表明:改进后的灰色负荷预测方法可以应用于电力系统中长期负荷预测,而且较普通灰色预测模型在预测精度上有着明显的提高,尤其是对于较远时间的负荷预测有着较为理想的预测精度,表明了该种方法的有效性和实用性.     

8407模具钢表面渗铝的研究

为了防止模具表面产生热疲劳裂纹,通过冷喷涂在8407钢试样表面形成了一层铝涂层,再进行扩散处理,在试样表面形成了渗层.通过理论分析确定低温渗铝的工艺参数,并与渗铝实验进行检验,重点研究了扩散温度和扩散时间对渗层质量的影响.结果表明,8407钢经过冷喷涂铝后再进行扩散处理能够实现低温渗铝.在550℃下扩散4 h左右形成的渗层质量比较理想.     

Effective prediction of DEA model by neural network

In this paper,a fast neural network model for the forecasting of effective points by DEA model is proposed,which is based on the SPDS training algorithm.The SPDS training algorithm overcomes the drawbacks of slow convergent speed and partially minimum result for BP algorithm.Its training speed is much faster and its forecasting precision is much better than those of BP algorithm.By numeric examples,it is showed that adopting the neural network model in the forecasting of effective points by DEA model is valid.     

Prevention of rockburst by guide holes based on numerical simulations

We studied variations in the stress field around guide holes drilled during tunnel excavation to understand the mechanical mechanism by which these holes help prevent rockburst. The study used elasto-plastic analysis of a circular chamber under non-axisymmetrical loads. The results showed that the unloading of in-situ stresses, and the forming of a secondary stress field, leads to a severe change in the stress field around the guide holes. This causes the formation of an X-shaped area of plastic deformation, which prevents the rockburst. Adopting a sub-model finite dement technique, we analyzed the factors that influence the distribution of the plastic area, such as the guide hole distribution and the in-situ stress state. The calculations showed that higher initial stresses result in greater adjustment to the stress field. When the stress concentration is greater the size of the plastic area surrounding the guide hole is larger. A multi-row distribution of the guide holes shaped like a quincunX can increase the interconnectivity of the plastic areas and allow the plastic area to extend from the tunnel wall deep into the surrounding rock. An optimized design was put forward based on the distribution of the plastic area around guide holes and the factors that influence it.     

Relation between structural evolution of the Longmenshan orogenic zone and sedimentation of its foreland basin

In order to determine the area for oil and gas exploration in China's north Sichuan basin, we have divided the time during which the Longmenshan foreland basin was formed into five periods, based on the sedimentary response relationship of the fore-land basin to structural evolution: 1) a late Triassic Noric period; 2) an early-Middle Jurassic period; 3) a late Jurassic to early Cre-taceous period; 4) a late Cretaceous to Paleogene-Neogene period and 5) the Quaternary period. As well, we analyzed the sedimen-tary environment and lithologic features of every basin-forming period. The results show that there are several favorable source-reservoir-cap assemblages in our study area, making it a major region for future oil and gas exploration in China's northern Sichuan basin.