Dynamically adjustable annular laser trapping based on axicons

To study the chemotactic response of sperm to an egg and to characterize sperm motility, an annular laser trap based on axicons is designed, simulated with the ray-tracing tool, and implemented. The diameter of the trapping ring can be adjusted dynamically for a range of over 400 microm by simply translating one axicon along the optical axis. Trapping experiments with microspheres and dog sperm demonstrate the feasibility of the system, and the power requirement agrees with theoretical expectation. This new type of laser trapping could provide a prototype of a parallel, objective, and quantitative tool for animal fertility and biotropism study.     

Preparation,characterization, and lithographic applications of glycidyl methacrylate/methacrylic acid/t‐butyl‐4‐vinylphenyl carbonate terpolymers

At present, most negative working lithographic plates use organic solvents as a developing medium. These developers have the obvious disadvantages of toxicity, fire risk, and are more expensive than the aqueous developers. This work describes the synthesis and characterization of materials that have similar photoactive properties to existing materials, but are soluble in water or aqueous medium rather than organic solvents. These materials are terpolymers comprising of one sort of material to induce water solubility, such as methacrylic acid (MAA) and another material to give the photoactive response such as glycidyl methacrylate (GMA). The tertiary‐butyl‐4‐vinyl phenyl carbonate (t‐BOCVP) was added as a chemically amplifying agent. Various terpolymers were prepared via free‐radical solution polymerization, typically in methyl ethyl ketone (MEK). Crosslinking reaction was induced using mixed arylsulphonium hexafluoroantimonate (MAS+ ‐SbF) as a photogenerating acid. It was found that the films of the terpolymer containing 85 mol % of GMA unit with the addition of 5 mol % rather than 2 mol % of the t‐BOCVP in the feed ratio gave good acid resistance and good adhesion to the surface of the zinc plate. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis and characterizations of poly(ethylene-co-vinylalcohol)-grafted-poly(3-hydroxybutyrate-co-hydroxyvalerate) copolymers

Poly(ethylene-co-vinylalcohol)-grafted-poly(3-hydroxybutyrate-co-hydroxyvalerate) (EVOH-g-PHBV) was prepared by a catalyzed grafting of PHBV onto immiscible EVOH. These reactions were performed at high temperature in the molten state. The choices of Tin(II) bis(2-ethylhexanoate) (Sn(Oct)₂) and 1,5,7-Triazabicyclo[4.4.0]dec-5-ene (TBD), as catalyst, were justified by a first study in an internal mixer. The catalyst quantity, reaction temperature and reaction time were optimized to apply them in the conditions of a reactive extrusion process with a co-rotating twin screw extruder. High reaction temperature, from 180 °C to 220 °C, associated to intensive mixing led to efficient grafting of PHBV onto EVOH, compatible with short residence times required.Rheological, thermal and morphological analyses were conducted to characterize the obtained copolymers. Molecular weights were determined by SEC. SEM imaging were made on cryo-fractured surfaces of blends extruded with and without catalyst. In most of reaction conditions, a compatible blend was obtained with a fine micro phase separation. Grafted copolymers were only obtained when well defined and controlled conditions are applied.     

Radical grafting of polar monomers onto polypropylene by reactive extrusion

Polypropylene (PP) was functionalized in the melt by grafting polar monomers using an internal mixer and a corotating twin‐screw extruder. 2,5‐Bis(tertbutylperoxy)‐2,5‐dimethylhexane (Luperox 101) and dicumyl peroxide (DP) were the used radical initiators. The polar monomers were itaconic acid (IAc), 2‐octen‐1‐ylsuccinic anhydride (OY), 2‐hydroxyethyl methacrylate (HEMA), and 3‐allyloxy‐1,2‐propanediol (AP). Grafting was quantified by FTIR combined to Elemental Analysis. Grafting degree depends mainly on monomer and initiator natures and concentrations. Grafting degree maxima were 3.9, 2, 9.5, and 3.9 wt %, respectively, for IAc, OY, HEMA, and AP. Some properties of the modified PP were evaluated. Thermal analysis indicated that the polarity of PP increased by grafting reaction and size‐exclusion chromatography showed that the grafting was not accompanied by a significant M_w and viscosity decrease. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013     

Effect of the host polymer on the nanomechanical and morphological properties of templated polymer films

Atomic force microscopy and nanoindentation have been applied to the study of thin molecularly templated polymer films. The template was chosen to be the readily hydrogen‐bonded cotinine molecule and three different polymer hosts, Elvamide® nylon, Nylon‐6, and poly(4‐vinylphenol) were compared. The host polymer was shown to affect the nature of the template‐host interaction resulting in varying surface morphologies and differences in the nanohardness. These observations were shown to reflect differences in the underlying interaction chemistry, specifically, whether or not the polymer may be imprinted in the film production process. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 877‐883, 2013     

POWER-Area-Performance Characteristics of FPGA-based Sigma-Delta FIR Filters

While one-bit ΣΔ modulators are widely used in Analog to Digital conversion stages due to their inherent linearity and precision, it is less common for the entire digital processing path to operate in single bit mode at the oversampled rate of the conversion system. The conventional approach has been to decimate the signal bit stream after conversion and for the remaining processing to be performed in standard multi-bit binary at the Nyquist rate and with a resolution mandated by the dynamic range and noise. Using a Finite Impulse Response filter design as an example, we compare the area and performance of this conventional approach with the alternative single bit approach that operates directly on the ΣΔ data stream using ternary coefficients {?1, 0, +1} derived from the ΣΔ modulation of the target impulse response. Filters exhibiting approximately equivalent spectral performance in the two alternative approaches were developed using VHDL and simulated using some commercial FPGA types. In these experiments, the single-bit filters using ternary coefficients were found to dissipate less power compared to the conventional approach despite their need to operate at much higher clock rates. They also exhibit up to 40% higher performance and offer useful area savings at lower filter orders. At higher orders, the ΣΔ approach retains its power and performance advantages but exhibits slightly higher chip area. The simplicity and low power of the ΣΔ approach makes it applicable to mobile communication processing using low cost FPGA technology.     

Review of convective heat transfer enhancement with nanofluids

Nanofluids are considered to offer important advantages over conventional heat transfer fluids. Over a decade ago, researchers focused on measuring and modeling the effective thermal conductivity and viscosity of nanofluids. Recently important theoretical and experimental research works on convective heat transfer appeared in the open literatures on the enhancement of heat transfer using suspensions of nanometer-sized solid particle materials, metallic or nonmetallic in base heat transfer fluids. The purpose of this review article is to summarize the important published articles on the enhancement of the forced convection heat transfer with nanofluids.     

Oxidation stability and compositional characteristics of oils from microwave roasted pumpkin seeds during thermal oxidation

The oxidative stability and compositional characteristics of the pumpkin seed oil (PSO) exposed to microwaves were studied during heating at 170°C. The oxidative indices such as free fatty acid (FFA), peroxide value (PV), p-anisidine value (p-AV), TOTOX, specific extinctions and thiobarbituric acid (TBA) value of oils were significantly increased, and the increments were found to be significantly higher (P < 0.05) in unroasted seed oil as compared to roasted seed oil. The relative contents of polyunsaturated fatty acids (PUFAs) were decreased to 84.7%, and saturated fatty acids (SFAs) were increased to 119.5% in unroasted sample, after 9 h of heating. On the other hand, in 12 min roasted samples, the relative contents of PUFAs were decreased to 97.0%, and SFAs were increased to 102.6% after 9 h of heating. The triacylglycerol species LLL and OLL levels were decreased as a consequence of increased heating time, and the reduction tended to be significantly higher in unroasted samples as compared to roasted ones. The oxidation products formed were also investigated by FTIR. The present results indicated that microwave roasting of pumpkin seeds markedly enhanced the oxidative stability of the oils during heating.