甘油三乙酸酯超临界酯交换反应及其动力学研究

研究了在超临界条件下甘油三乙酸酯与甲醇或乙醇的酯交换反应,分别考察了超临界状态下醇油摩尔比和温度对反应的影响。实验结果表明,甲醇或乙醇与甘油三乙酸酯的摩尔比为14、反应温度为350℃、反应时间为20m in时,乙酸甲酯或乙酸乙酯的收率分别达100%和60%。对超临界状态下动力学的研究结果表明,甘油三乙酸酯与甲醇或乙醇的酯交换反应为拟一级反应,在相同的反应条件下,采用甲醇时酯交换反应速率比用乙醇时快,相应的甘油三乙酸酯的转化率也高;甘油三乙酸酯在超临界甲醇或乙醇中酯交换反应的表观活化能分别为58.7 kJ/mol和75.1 kJ/mol,甘油三乙酸酯与甲醇酯交换反应的活化能低于与乙醇酯交换反应的活化能,表明碳链短的醇更易进行酯交换反应。     

数控超声加工的初步工艺试验

介绍在经过数控化改造的两坐标超声加工机床上所进行数控超声加工的初步工艺试验,并讨论试验结果。     

Synthesis of Mg-α-sialon from the mixture of silicon, aluminum and magnesia powders in a flowing nitrogen atmosphere

Synthesis of Mg-α-Sialon has been investigated by the mixture of silicon, aluminum and magnesia powders in a flowing nitrogen atmosphere in the range of 1300–1600 °C, when Mg-α-Sialon is designed with a chemical formulation of Mg _x Si_12−3x Al_3x O _x N_16−x in present work. The results showed that Mg-α-sialon initially occurred at 1400 °C and basically increased with elevated temperatures. For the samples of x = 0.6, 0.8 and 1.0 the products mainly consisted of Mg-α-Sialon with small amounts of Si, AlN and 21R AlN-polytypoid phases at 1600° C. However, in final products of x = 1.2, 1.4 and 1.6 only a little of Mg-α-Sialon formed and a great amount of Si remained in these samples at all the fired temperatures. Fortunately, the content of Mg-α-Sialon in these samples were obviously increased by adding a small amount of α-Si₃N₄ as seeds before nitridation.     

Time Characterization of High Density Gas Jet from a Pulsed Supersonic Nozzle via Laser Produced Plasma

A high-density gas jet supersonic nozzle is reported in this paper. The jitter and actuation time of the nozzle is determined by the pin discharge and laser spark radiation respectively. The jitter time of the nozzle is within 10μs with the backing pressure as high as 25 bar. With a nanosecond laser pulse focused on the gas jet about 1 mm below the nozzle, the actuation time is calculated to be about 15 ms by detecting the laser produced spark radiation, which reveals the existence of the gas jet and the relative gas density evolving with time. Consequently the gas density is estimated to be well above 10^19 cm^-3, compared with theoretical simulations from the nozzle parameters.     

高分辨率合成孔径雷达图像舰船检测方法

寻找针对高分辨率SAR图像的舰船目标检测算法。利用KSW双阈值分割技术，其效果比传统检测方法好，有利于进一步的目标分类和识别。且必须根据SAR图像分辨率来选择舰船检测算法。     

CDMA发射分集系统的多用户检测常模算法分析

空时分集技术的最大优点在于在不增加带宽的情况下可以提高系统的可靠性,是目前移动通信的研究热点.常模算法是一种性能优良的码分多址(CDMA)盲多用户检测技术,能确保判决信号与实际传送信号之间的差错较小,误码率性能良好.文中提出将标准线性受限常模算法(LCCMA)与空时分组码(STBC)相结合,设计出一种收敛快、能够改善系统性能的基于2-空时分组码的多用户接收机.     

Highly ordered microstructures of poly(styrene-b-isoprene) block copolymers induced by solution meniscus

Microstructures of hundreds of micron thick poly(styrene-block-isoprene) copolymer films solution-cast in a cylindrical tube with the solvent evaporation controlled were investigated by transmission electron microscope (TEM), small angle X-ray scattering (SAXS) and optical microscope (OM). In a block copolymer with cylindrical polyisoprene microdomains, the orientation of the cylinders was varied along radial direction of the cylindrical tube. Highly aligned hexagonal arrays of in-plane polyisoprene cylinders were formed with their cylindrical axis parallel to the circumference of the tube in the regimes close to the wall edge. In contrast randomly ordered microdomains were observed at the center of the tube. We have also found that the orientation depends on the solvent evaporation rate and an intermediate rate (∼2.3 nL/s) provides the best orientation. In the case of a block copolymer with a bicontinuous double gyroid structure, we obtained a globally ordered microstructure where [111] crystallographic direction was parallel to the circumference of the tube. For both block copolymers, the area of highly ordered arrays of nanoscopic domains is over 1 mm². Development of the orientation was explained by coupling two orthogonal fields: (1) The flow of a solution induced by strong capillary force at a meniscus between the cylindrical tube wall and the block copolymer solution and (2) the solvent evaporation.     

双口RAM在大屏幕LED显示系统中的应用开发

双口RAM与常规RAM的最大区别是双口RAM具有两套独立的地址、数据和控制线,允许两个独立的CPU或控制器同时异步地访问存储单元,双口RAM由片内的仲裁逻辑来确定哪一侧的CPU可以访问内部RAM单元.IDT7132是2kB的标准双口RAM.文中重点介绍采用以自顶向下方法设计的基于CLD(复杂可编程逻辑器件)的大屏幕LED(发光二极管)显示系统中双口RAM的应用,并给出了系统设计方法及相关硬件电路.本设计中IDT7132双口RAM用来连接单片机信号处理模块和CPLD扫描模块.     

油气井智能电子防盗阀门

为了有效扼制油田油井原油被盗的现象，减少因被盗及破坏带来的经济损失，研制出GMS3000油气井智能电子防盗阀门。该电子防盗阀门采用了新颖的防盗控制电路和精密的机械联动机构，通过计算机和管理软件得到相应的阀门授权控制，测量结果自动记录、控制阀门的编号和阀门的联动方式，并给予相应的显示。具有可靠、安全、便捷的特点。应用效果表明，达到了油井防盗、防破坏的目的，收到了良好的使用效果，为油田生产安全和提高经济效益提供了可靠的保障。     

岭澳核电工程38m平台边坡处理

岭澳核电重件道路施工中所遇到的38m的观景平台在大亚湾核电站占有重要地位,在工程施工中发现边坡坡体陡峭,无法达到规范规定的稳定要求,故采取了加固措施。采用抗滑稳定计算的分析方法,对边坡加固的必要性及实施加固后的稳定性进行了分析。