Double auction-inspired meta-scheduling of parallel applications on global grids

Meta-schedulers map jobs to computational resources that are part of a Grid, such as clusters, that in turn have their own local job schedulers. Existing Grid meta-schedulers either target system-centric metrics, such as utilisation and throughput, or prioritise jobs based on utility metrics provided by the users. The system-centric approach gives less importance to users’ individual utility, while the user-centric approach may have adverse effects such as poor system performance and unfair treatment of users. Therefore, this paper proposes a novel meta-scheduler, based on the well-known double auction mechanism that aims to satisfy users’ service requirements as well as ensuring balanced utilisation of resources across a Grid. We have designed valuation metrics that commodify both the complex resource requirements of users and the capabilities of available computational resources. Through simulation using real traces, we compare our scheduling mechanism with other common mechanisms widely used by both existing market-based and traditional meta-schedulers. The results show that our meta-scheduling mechanism not only satisfies up to 15% more user requirements than others, but also improves system utilisation through load balancing.     

Delineation of glacial zones of Gangotri and other glaciers of Central Himalaya using RISAT-1 C-band dual-pol SAR

The Himalayan glaciers, being unique in nature, need more detailed study over their evolution in the Himalayan glacial zones. A methodology has been developed using two-dimensional signatures from synthetic aperture radar (SAR) C-band dual-polarized data. A linear decision rule-based model has been generated using the signatures and the result further filtered by the use of a digital elevation model (DEM) to delineate glacial zones in the Himalayas. The advantage of using cross-polarized data is the addition of extra information from the volume of the glacial mass. Some important prerequisites for the analysis are SAR image ortho-rectification and calibration, glacier boundary delineation, and the development of sites for collecting SAR backscattering signatures from glaciers along the profile. The study deals with the evolution of glacial snow cover and glacial zones/facies in the Himalayan region under a subtropical humid climate from the ablation to the accumulation season. SAR images from 15 July 2012 to 30 June 2013 over the Gangotri and Mana glaciers were evaluated with the developed model. The identification of a superimposed zone during the ablation season is among the key results. The identified snowlines and other boundaries of glacial facies are studied on a temporal scale. The highest snowline altitude of Mana was recorded at 5768 and 5194 m for the Gangotri glacier in 2012. SAR data are also important in identifying glacial zones buried under winter snow cover. The results obtained are useful in regard to further glaciological studies of the Himalayan glaciers.     

PtRu nanoparticles supported on nitrogen-doped multiwalled carbon nanotubes as catalyst for methanol electrooxidation

Nitrogen-doped carbon nanotubes (N-CNT) obtained by plasma treatment were compared to the conventional acid-treated carbon nanotubes (O-CNT) as catalyst support for platinum-ruthenium (PtRu) nanoparticles in the anodic oxidation of methanol in direct methanol fuel cells. PtRu catalysts were prepared by an impregnation-reduction method from chloride precursors with metal loadings of 20 wt.%, and were characterised by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy and electrochemical methods. Voltammetry and chronoamperometry studies showed that the performance of PtRu/N-CNT was significantly higher compared to PtRu/O-CNT and also to the commercial E-TEK PtRu/C catalyst, indicating that N-CNT are an interesting support material for fuel cell electrocatalyst. Nitrogen plasma treatment produced pyridinic and pyrrollic species on the CNT surface, which acts as the anchoring sites for the deposition of PtRu particles. A mechanism for the deposition of PtRu on N-CNT is tentatively proposed and discussed.     

Performance of symmetric polygonal fins with and without tip loss — A comparison of different methods of prediction

No analytical solution exists for estimating the efficiency of symmetric polygonal fins (SPFs) circumscribing circular tubes. Performance of such fins is conventionally determined from either of the two approximate techniques, namely, the equivalent annulus method and the sector method. The present work aims to judge the relative merits and applicability of these two methods critically. To this end, the results obtained from the approximate techniques have compared with those obtained from a semi‐analytical technique. It has been noted that, with the increase of the tip heat loss, the accuracy of prediction from any of the approximate methods decreases. For the sector method, a modification has been suggested. The prediction from the modified version of the sector method is always more accurate than that from the equivalent annulus method. It has been further illustrated that though the approximate techniques can be employed for the prediction of efficiency, they cannot be used to predict the tip temperatures accurately.     

Influence of process parameters on the formation of Silicalite-1 zeolite particles

Silicalite-1 particles with minimum twinning have been synthesized inside the polar core of non-ionic surfactant/co-surfactant-stabilized water-in-oil (w/o) type emulsions at 150° ± 1 °C within a short reaction time of 5 h. The non-ionic surfactants of varying hydrophilic–lipophilic balance (HLB) values, i.e. sorbitan monooleate (Span 80, HLB: 4.3), sorbitan monolaurate (Span 20, HLB: 8.6), polyoxyethylene (4) lauryl ether (Brij 30, HLB: 9.7) and polyoxyethylene sorbitan monooleate (Tween 80, HLB: 15), the cationic surfactant, i.e. cetyl trimethyl ammonium bromide (CTAB), surfactant concentration, co-surfactant, synthesis temperature and time have been found to play significant role in controlling size and characteristics of Silicalite-1. It has been observed that the crystallinity and size of Silicalite-1 can be tailored by adjusting the interactions between the polar surfactant head groups at the w/o interface and the growing crystallographic surfaces (or silicate/TPA ions) in the aqueous medium of the emulsion.     

Enhanced performance of direct methanol fuel cells: a study on the combined effect of various supporting electrolytes,flow channel designs and operating temperatures

Establishing a better coordination between operating parameters and flow channel design is one of the most critical factors in achieving an optimum final performance of a fuel cell, since even a marginal change in any of the parameters can sharply affect the cell's performance. In this study, we report the use of three different acids, viz. sulphuric acid (H₂SO₄), formic acid (HCOOH) and phosphoric acid (H₃PO₄) as supporting electrolytes in combination with 2 M methanol fuel, wherein we demonstrated the effects of different combinations of acidic fuels and channel designs on the final cell performance. For this purpose, we made use of four different types of serpentine flow design. In the process, it was observed that an addition of 2 M concentrations of H₂SO₄ and H₃PO₄ enhanced the cell performance sharply in terms of current density, reaching values of 210 mAcm^?2 and 180 mAcm^?2, respectively, when analyzed at 0.2 V potential. This result was a considerable improvement over the current density value of 90 mAcm^?2 achieved while using only 2 M methanol analyzed at the same potential. Moreover, the open‐circuit voltage showed a value of greater than 0.6 V for both fuel samples. With a flow channel length of 650 mm (A5SF2) and at an open ratio of 52%, we obtained maximum power values of 42 mWcm^?2 and 36 mWcm^?2 for fuels containing 2 M H₂SO₄ (M2S2) and 2 M H₃PO₄ (M2P2), respectively, when analyzed at 70°C. Copyright © 2013 John Wiley & Sons, Ltd.     

Studies on in vitro release of CPM from semi-interpenetrating polymer network (IPN) composed of chitosan and glutamic acid

Interpenetrating polymer network (IPN) beads consisting of chitosan-glutamic acid were prepared for in vitro study of controlled release of chlorpheniramine maleate (CPM). A viscous solution of chitosan-glutamic acid was prepared in 2% acetic acid solution, extruded as droplets through a syringe to alkalimethanol solution and the precipitated beads were crosslinked using glutaraldehyde solution. Swelling and drug release studies were carried out. Transport of release medium through the semi-IPN depended upon its pH and extent of crosslinking. The structural and morphological studies of beads were carried out by using a scanning electron microscope (SEM). The larger surface area of beads as well as their ease of handling makes them ideal agents of controlled release.     

Acoustic material signature of a layered plate

A technique is presented for the theoretical calculation of the acoustic material signature (AMS) of a multilayered plate with its bottom surface free of traction. The layers are composed of homogeneous isotropic linearly elastic materials and are assumed to be firmly bonded at the interfaces. The plate model can serve to represent either a self supporting membrane, or a multilayered composite with extensive debonding on a plane parallel to the layers. Calculated AMS curves are presented for a uniform plate, a two layered plate and a two layered half-space at 60 MHz exciting frequency. The striking differences in these curves indicate the possibility of using them as quantitative diagnostics for extensive debonding in a layered specimen.