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211.
湿浸法制备活性组分非均匀分布负载型催化剂过程的计算机模拟 总被引:1,自引:0,他引:1
对活性组分非均匀分布的负载型催化剂的湿浸法制备过程进行了计算机模拟,其模拟程度可适用于任意多个活性组分的浸渍。发现单组分浸渍时,通过控制浸渍时间可获得活性组分由薄到厚的蛋壳型分布和均匀分布,但通过预浸渍吸附至一定分布后,再在空白溶液中浸渍洗脱,控制洗脱条件也可获得蛋黄、蛋白型的分布;加入竞争吸附剂,进行双组分及多组分浸渍,通过控制浸渍溶液性质及浸渍时间可获得各种类型的活性组分分布,诸如蛋壳型、蛋白型、蛋黄型和均匀型。通过对制备过程参数(如竞争吸附剂的选择、各组分有效扩散系数、初始浓度、吸脱附速率常数等)与活性组分分布形式之间关系的分析,可实现对任一分布形式的催化剂的制备过程参数的优化。这对实际制备催化剂具有指导意义。 相似文献
212.
秦伟 《网络安全技术与应用》2014,(9):205-206
本文通过对存储系统的硬件技术性能分析,结合作者实际工作经验,阐述电子信息数据安全在当前企业信息化建设中越来越重要,探讨如何选择先进的数据存储方法,对企业数据进行主动安全防护,从而保证数据的安全性、可靠性、稳定性. 相似文献
213.
秦爱武 《网络安全技术与应用》2014,(11):168-169
随着社会科技和信息网络技术的飞速发展,慕课成为时代孕育的新时期教育模式,这种课程模式为中职学生学习提供了更大的自由空间。在中职计算机教学中,培养学生对于计算机理论知识的掌握和实际操作的技能固然重要,但对于学生综合素质的培养也是不容忽视的。为此,本文就以培养学生的创新能力和实践能力为要点,不断加强学生动手操作能力,对慕课时代下中职计算机课程知识体系的构建做进一步探讨。 相似文献
214.
Qin Wang Qiong‐Hua Wang Jing‐Long Liang Chun‐Ling Liu 《Journal of the Society for Information Display》2014,22(10):493-498
In order to investigate visual experience for watching the autostereoscopic three‐dimensional (3D) projection display, we conduct a subjective evaluation experiment by a questionnaire when viewing video clips. Factor analysis is adopted to classify the evaluation items for the perpetual constructs of visual experience. Then a mixed design with repeated measurement analysis of variance with dimension and display duration as factors is carried out on the evaluation data to check the factorial effects and interactions for statistical significance. The results of factor analysis extract five factors including visual comfort, image quality, distortion, naturalness, and presence, which can be used as comprehensive indicators to evaluate the autostereoscopic 3D projection display. The results of analysis of variance indicate that image quality, which is used to assess two‐dimensional contents, is no longer applicable. It is necessary to give consideration to depth when evaluating 3D visual experience. Although 3D scenes enhance the overall subjective performance such as naturalness and presence, the health issues and stereoscopic distortion related to the introduction of depth cannot be ignored. 相似文献
215.
本文综述了电力绝缘用SF6替代物的开发方法、发展现状和未来趋势。其开发方法包括替代物的设计与确认(物性、安全性评价、环境影响的评价等)、合成、产业化等内容。目前,开发出的SF6替代物包括SF6混合气体、饱和卤代烃、氢氟烯烃、全氟酮和全氟腈,其中七氟异丁腈的绝缘性能优异,是SF6最佳的替代物。同时文中综述了现有七氟异丁腈的合成路线,其中以碳酰氟和六氟丙烯为起始原料催化反应合成七氟异丁腈的路线,具有高效、绿色、环保的优点。以过去发展历程和现在发现现状为基础,展望了SF6替代物的未来发展趋势,提出今后的研究重点在于全面开发七氟异丁腈的应用配套设备,下一代SF6替代物及其绿色、高效的产业化路线。 相似文献
216.
217.
A prototype wind-powered reverse osmosis desalination system was constructed and tested on Coconut Island off the northern coast of Oahu, Hawaii, for brackish water desalination. The system has four major subsystems: a multi-vaned windmill/pump, a flow/pressure stabilizer, a reverse osmosis module, and a control mechanism. The feedback control mechanism, developed by this study, allowed this prototype system to be operated satisfactorily under mild ambient wind of 5 m/s or less. No auxiliary power source was needed. The system operational data showed that at an average wind speed of 5 m/s, brackish feedwater at a total dissolved solids concentration of 3000 mg/1 and at a flow rate of 13 1/min could be processed by this system. The average rejection rate of this prototype system was 97% and the average recovery ratio was 20%. The energy efficiency of the system was measured at 3 5%, which is comparable to the typical energy efficiency of well-operated multi-vaned windmills. Generally, the system's energy efficiency decreases as wind speed increases. 相似文献
218.
The linear and nonlinear shear rheological behaviors of poly(propylene) (PP)/clay (organophilic‐montmorillonite) nanocomposites (PP/org‐MMT) were investigated by an ARES rheometer. The materials were prepared by melt intercalation with maleic anhydride functionalized PP as a compatibilizer. The storage moduli (G′), loss moduli (G″), and dynamic viscosities of polymer/clay nanocomposites (PPCNs) increase monotonically with org‐MMT content. The presence of org‐MMT leads to pseudo‐solid‐like behaviors and slower relaxation behaviors of PPCN melts. For all samples, the dependence of G′ and G″ on ω shows nonterminal behaviors. At lower frequency, the steady shear viscosities of PPCNs increase with org‐MMT content. However, the PPCN melts show a greater shear thinning tendency than pure PP melt because of the preferential orientation of the MMT layers. Therefore, PPCNs have higher moduli but better processibility compared with pure PP.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2427–2434,2004 相似文献
219.
An in‐line capillary rheometer nozzle equipped to a conventional reciprocating 55‐ton injection molding machine was used to study the viscosity of single phase low density polyethylene (LDPE)/chemical blowing agent (CBA) solutions under high shear rate in the concentration range of 0 to 5 wt%. The steady shear viscosity of LDPE with endothermic and exothermic chemical blowing agents was measured for shear rates ranging from 170 to 200,000 s?1 and under pressure conditions up to 36 MPa. Pressure‐volume‐temperature (pvT) measurements were determined to account for the pressure effects and the changes of the free volume during processing. The viscosity reduction of the polymer‐CBA solution was found to be dependent on the concentration of the chemical blowing agent and melt pressure. A model based on a simplified Cross‐Carreau model, incorporating the pvT behavior of LDPE, and the free volume concept was proposed to estimate the viscosity reduction resulting from the addition of a chemical blowing agent. The model employs a scaling method based on concentration‐dependent and pressure‐dependent shift factors to collapse the viscosity measurement to a master curve at each temperature. POLYM. ENG. SCI., 45:1108–1118, 2005. © 2005 Society of Plastics Engineers 相似文献
220.
The isothermal and nonisothermal cure behaviors of a novel nitrogen‐containing epoxy resin (XT resin) were studied by differential scanning calorimetry (DSC). Various kinetic parameters and details of cure process were obtained based on the Avrami theory. The results indicated that Avrami method is suitable for calculating the kinetic parameters up to the gel point at least. The apparent activation energy (Ea) for isothermal cure process was in agreement with that for nonisothermal cure process. Ea value in the early stage (78.5–81.0 KJ mol?1) was about three times than that in the later stage (23.3–26.5 KJ mol?1). The kinetic results from Avrami theory may present a combined effect of all factors, and which is helpful to understand the cure technique for XT–DDS system. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 3483–3489, 2006 相似文献