频率响应法研究噻吩在CeY分子筛上的吸附行为

以NaY、液相Ce离子交换改性的Y型分子筛(L-CeY)为研究对象,运用N2吸附、XRD、NH3-TPD和Py-FTIR等实验方法表征两种Y型分子筛的物化性能。采用频率响应技术(FR)和智能重量分析仪(IGA)研究噻吩在两种分子筛上的吸附行为,并考察噻吩在稀土离子改性Y型分子筛上的不同吸附作用模式。结果表明,频率响应技术能够有效识别分子筛孔道内发生的不同传质过程。噻吩在NaY分子筛上的吸附行为较为简单,存在孔道吸附和π电子相互作用两种吸附过程;而在L-CeY分子筛上吸附行为较为复杂,同时存在孔道吸附和"S-M"吸附等多种吸附过程,另外,在高温条件下,还存在复杂的催化反应过程。     

Degradability and biocompatibility of bioglass/poly(amino acid) composites with different surface bioactivity as bone repair materials

Bioglass (BG) possesses excellent bioactivity and has been widely used in the manufacture of biomaterials. In this study, a composite with different surface bioactivity was fabricated via in situ melting polymerization by incorporating BG and poly(amino acid) (PAA) at a suitable ratio. The structure of the composite was characterized by Fourier transform infrared spectroscopy and XRD. The compressive strength of the BG/PAA composites was 139 MPa (BG:PAA = 30:70). The BG/PAA composites were degradable, and higher BG in composite showed higher weight loss after 4 weeks of incubation in simulated body fluid. In addition, the BG/PAA composite maintained adequate residual compressive strength during the degradation period. The SEM results showed the differences in surface bioactivities of the composites directly, and 30BG/PAA composite showed thicker apatite layer and higher Ca/p than 15BG/PAA. in vitro MG-63 cell culture experiments showed that the composite was noncytotoxic and thus allows cells to adhere, proliferate, and differentiate. This indicates that the composite has good biocompatibility. The implantations in the bone defects of rabbits for 4 and 12 weeks were studied. The composites had good biocompatibility and were capable of guiding new bone formation without causing any inflammation. The composite may be successfully used in the development of bone implants.     

Oxidation Performance of Fe-Al/WC Composite Coatings Produced by High Velocity Arc Sprayed at 650 ℃

Fe-Al intermetallics with remarkable high-temperatureintensity and excellent erosion,high-temperatureoxidation and sulfuration resistance are potential lowcost high-temperature structural material.ProducingFe-Al/WC composite coating by high velocity arcspraying(HVAS)on structural materials would notonly obviate the problems faced in fabrication of thesealloys into useful shapes,but also allow the effectiveuse of their outstanding high-temperature performance,which might thus promisingly mak…     

高温预析出对Al-Zn-Mg-Cu铝合金显微组织、强度和应力腐蚀抗力的影响

通过改变固溶条件 ,对Al Zn Mg Cu高强铝合金采用先高温后低温的两步固溶处理 (高温预析出 )来改善晶内和晶界的析出状态 ,研究了高温预析出对Al Zn Mg Cu铝合金的金相组织、强度和应力腐蚀性能的影响。结果表明 ,4 6 5℃高温预析出在保持较高强度和塑性的同时 ,可以改善合金的抗应力腐蚀性能     

冶炼不锈钢泡沫渣的实验研究

从理论上阐述冶炼不锈钢时熔渣的发泡机理。并根据上海三钢公司的情况，在2500Hz的中频感应炉上时熔渣进行发泡高度的实验，找出发泡性能较好的渣系，研究渣中各成分对发泡性能的影响。     

The influence of sulphate-reducing bacteria biofilm on the corrosion of stainless steel AISI 316

This work investigates microbially-influenced corrosion (MIC) of stainless steel AISI 316 by two sulphate-reducing bacteria, Desulfovibrio desulfuricans and a local marine isolate. The biofilm and pit morphology that developed with time were analyzed using atomic force microscopy (AFM). Electrochemical impedance spectroscopy (EIS) results were interpreted with an equivalent circuit to model the physicoelectric characteristics of the electrode/biofilm/solution interface. D. desulfuricans formed one biofilm layer on the metal surface, while the marine isolate formed two layers: a biofilm layer and a ferrous sulfide deposit layer. AFM images corroborated results from the EIS modeling which showed biofilm attachment and subsequent detachment over time.     

管理史对MBA的边际效用

近年来 ,我国MBA的社会评价不高 ,其根本原因是MBA毕业生不能满足市场要求。本文通过分析管理史的功能 ,得出学习管理史对MBA的边际效用大 ,MBA培养方案中有必要增设管理史类的课程。     

用计算机图形处理软件定量分析SEM图像

用图形处理软件PHOTOSHOP对SEM图像进行图像定量分析，对高温合金K23σ析出相的体积分数和M8钢样的夹杂物颗粒尺寸进行了定量测定。结果表明，该方法操作方便，有一定的可行性。     

φ114mm直缘成型焊管机组的研制

简介了研制的φ１１４ｍｍ直缘成型焊管机组的技术性能和工艺特点。与普通辊式成型机组相比，该机组工艺先进，焊管精度高。     

铝—钢双金属复合轧制层厚比及轧制力的研究

用实验方法研究了铝－钢双金属复合轧制时层厚比的变化规律。给出了双金属复合时轧制力的计算式。