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排序方式: 共有1146条查询结果,搜索用时 15 毫秒
21.
The stepwise insertion reaction of styrene (St) and p-tert-butoxystyrene (BOSt) into poly(alkoxyamine) macroinitiator was carried out to provide well-defined poly(St)-b-poly(BOSt) multiblock copolymers. Structural confirmation of the multiblock copolymers was accomplished by NMR and IR measurements. The model reaction also supported that the monomer insertion into the macroinitiator proceeded in accordance with a living fashion. 相似文献
22.
Arai Kazuhito; Hishida Atsushi; Ishiyama Mariko; Kamata Takeo; Uchikoba Hiroyuki; Fushinobu Shinya; Matsuzawa Hiroshi; Taguchi Hayao 《Protein engineering, design & selection : PEDS》2002,15(1):35-41
Lactobacillus casei allosteric L-lactate dehydrogenase (L-LDH)absolutely requires fructose 1,6-bisphosphate [Fru(1,6)P2] forits catalytic activity under neutral conditions, but exhibitsmarked catalytic activity in the absence of Fru(1,6)P2 underacidic conditions through the homotropic activation effect ofsubstrate pyruvate. In this enzyme, a single amino acid replacement,i.e. that of His205 conserved in the Fru(1,6)P2-binding siteof certain allosteric L-LDHs of lactic acid bacteria with Thr,did not induce a marked loss of the activation effect of Fru(1,6)P2or divalent metal ions, which are potent activators that improvethe activation function of Fru(1,6)P2 under neutral conditions.However, this replacement induced a great loss of the Fru(1,6)P2-independentactivation effect of pyruvate or pyruvate analogs under acidicconditions, consequently indicating an absolute Fru(1,6)P2 requirementfor the enzyme activity. The replacement also induced a significantreduction in the pH-dependent sensitivity of the enzyme to Fru(1,6)P2,through a slight decrease and increase of the Fru(1,6)P2 sensitivityunder acidic and neutral conditions, respectively, indicatingthat His205 is also largely involved in the pH-dependent sensitivityof L.casei L-LDH to Fru(1,6)P2. The role of His205 in the allostericregulation of the enzyme is discussed on the basis of the knowncrystal structures of L-LDHs. 相似文献
23.
N,O,O′─三(对甲苯磺酰基)双(2─羟乙基)胺的合成 总被引:1,自引:0,他引:1
二乙醇胺和对甲苯磺酰氯在三乙胺存在下,反应生成N,0,O′-三(对甲苯磺酰基)双(2-羟乙基)胺,产率93%。从反应混合物中分离得副产物N,O-二(对甲苯磺酰基)双(2-羟乙基)胺。 相似文献
24.
Monooctadecyl maleate, as a polymerizable surfactant, was synthesized by the mono-esterification of maleic anhydride and octadecanol,
and was utilized to surface-modify nano-Fe3O4 particles. A polymerizable magnetic fluid was obtained by directly dispersing modified nano-Fe3O4 particles into styrene monomer, and the polystyrene/nano-Fe3O4 composite was prepared through free radical polymerization of polymerizable magnetic fluid. The structure and dispersion
status in different dispersion phases of modified nano-Fe3O4 particles were studied by Fourier transform infrared (FTIR) spectrometry, X-ray diffraction (XRD) and transmission electron
microscopy (TEM), respectively. The experimental results show that the nano-Fe3O4 particles modified by monooctadecyl maleate with the size of about 7–10 nm can be uniformly dispersed into styrene and fixed
in the composite during the procedure of polymerization. Thermogravimetric analysis (TGA) and vibrating sample magnetometry
(VSM) indicate that the thermal stability of polystyrene/nano-Fe3O4 composite is improved compared to that of pure polystyrene, and the composite is a sort of superparamagnetic materials. 相似文献
25.
26.
Yoshihisa Shinya Kenji Kamiya Tomoyuki Toyoda Yasumi Endo Nelly Soudakova Hirofumi Kondo 《Journal of the Society for Information Display》2009,17(4):331-336
Abstract— The display used in current cell phones has an air gap between the cover glass and the liquid‐crystal‐display (LCD) module to prevent the LCD glass from being damaged. Reflections at the boundaries of the air gap cause a reduction in the LCD luminance and contrast. To address this problem, a newly proposed LCD structure has been investigated. The “Super View Resin (SVR),” a transparent elastic resin which improves the shock resistance and visibility of the LCD, has been developed. Filling the air gap between the cover glass and LCD module with a refractive‐index‐matching resin solves the light‐reflection problem inherent in the use of a reinforced cover‐glass lens. Moreover, the elastic filler works as a damper, reducing any external shock, which prevents not only the cover glass and LCD module from being damaged, but also the glass from being shattered when it is broken. 相似文献
27.
Shinya Yamamura Akira Nagata Masato Tsuru Hitomi Tamura 《Simulation Modelling Practice and Theory》2011,19(1):30-46
We have proposed the concept of the virtual segment (VS), in which a global communication service is provided by combining a store–carry–forward scheme using vehicles with broadband wireless/wired network infrastructures along roads connected to the Internet. The VS can be a practical framework for non-real-time, asynchronous message transfer (especially for large messages) in a cost-effective manner. In this study, a critical implementation design issue, the message forward scheduling, in the VS approach is discussed and investigated through computer simulation by our developed VS simulator that has reflected the results of the field experiment for realistic performance evaluation. 相似文献
28.
Yuichiro Ezoe Ikuyuki Mitsuishi Utako Takagi Masaki Koshiishi Kazuhisa Mitsuda Noriko Y. Yamasaki Takaya Ohashi Fumiki Kato Susumu Sugiyama Raul E. Riveros Hitomi Yamaguchi Shinya Fujihira Yoshiaki Kanamori Kohei Morishita Kazuo Nakajima Ryutaro Maeda 《Microsystem Technologies》2010,16(8-9):1633-1641
We are developing novel ultra light-weight and high-resolution X-ray micro pore optics for space X-ray telescopes. In our method, curvilinear micro pore structures are firstly fabricated by silicon deep reactive ion etching (DRIE) or X-ray LIGA processes. Secondly, side walls of the micro structures are smoothed by magnetic field assisted finishing and/or hydrogen annealing techniques for high reflectivity mirrors. Thirdly, to focus parallel X-ray lights from astronomical objects, these structures are elastically or plastically bent into a spherical shape. Fourthly, the bent structures are stacked to form a multi-stage X-ray telescope. In this paper, we report on fabrication and X-ray reflection tests of silicon and nickel X-ray mirrors using the DRIE and LIGA processes, respectively. For the first time, X-ray reflections were confirmed on both of the mirrors. Estimated rms roughnesses were 5 nm and 3 nm for the silicon and nickel mirrors, respectively. 相似文献
29.
We solve the light transport problem by introducing a novel unbiased Monte Carlo algorithm called replica exchange light transport, inspired by the replica exchange Monte Carlo method in the fields of computational physics and statistical information processing. The replica exchange Monte Carlo method is a sampling technique whose operation resembles simulated annealing in optimization algorithms using a set of sampling distributions. We apply it to the solution of light transport integration by extending the probability density function of an integrand of the integration to a set of distributions. That set of distributions is composed of combinations of the path densities of different path generation types: uniform distributions in the integral domain, explicit and implicit paths in light (particle/photon) tracing, indirect paths in bidirectional path tracing, explicit and implicit paths in path tracing, and implicit caustics paths seen through specular surfaces including the delta function in path tracing. The replica‐exchange light transport algorithm generates a sequence of path samples from each distribution and samples the simultaneous distribution of those distributions as a stationary distribution by using the Markov chain Monte Carlo method. Then the algorithm combines the obtained path samples from each distribution using multiple importance sampling. We compare the images generated with our algorithm to those generated with bidirectional path tracing and Metropolis light transport based on the primary sample space. Our proposing algorithm has better convergence property than bidirectional path tracing and the Metropolis light transport, and it is easy to implement by extending the Metropolis light transport. 相似文献
30.
Shiro Kumano Kazuhiro Otsuka Junji Yamato Eisaku Maeda Yoichi Sato 《International Journal of Computer Vision》2009,83(2):178-194
In this paper, we propose a method for pose-invariant facial expression recognition from monocular video sequences. The advantage
of our method is that, unlike existing methods, our method uses a simple model, called the variable-intensity template, for
describing different facial expressions. This makes it possible to prepare a model for each person with very little time and
effort. Variable-intensity templates describe how the intensities of multiple points, defined in the vicinity of facial parts,
vary with different facial expressions. By using this model in the framework of a particle filter, our method is capable of
estimating facial poses and expressions simultaneously. Experiments demonstrate the effectiveness of our method. A recognition
rate of over 90% is achieved for all facial orientations, horizontal, vertical, and in-plane, in the range of ±40 degrees,
±20 degrees, and ±40 degrees from the frontal view, respectively.
Electronic Supplementary Material The online version of this article () contains supplementary material, which is available to authorized users. 相似文献