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Mingliang Yu Si Zhou Zhiyu Wang Wei Pei Xuejun Liu Chang Liu Chenglin Yan Xiangyu Meng Song Wang Jijun Zhao Jieshan Qiu 《Advanced functional materials》2019,29(46)
Using high‐capacity and metallic Li‐free lithium sulfide (Li2S) cathodes offers an alternative solution to address serious safety risks and performance decay caused by uncontrolled dendrite hazards of Li metal anodes in next‐generation Li metal batteries. Practical applications of such a cathode, however, still suffer from low redox activity, unaffordable cost, and poor processability of infusible and moisture‐sensitive Li2S. Herein, these difficulties are addressed by developing a molecular cage–engaged strategy that enables low‐cost production and interfacial engineering of Li2S cathodes for rechargeable Li2S//Si cells. An efficient chemisorption–electrocatalytic interface is built in extremely nanostructured Li2S cathodes by harnessing the confinement/separation effect of metal–organic molecular cages on ionic clusters of air‐stable, soluble, and low‐cost Li salt and their chemical transformation. It effectively boosts the redox activity toward Li2S activation/dissociation and polysulfide chemisorption–conversion in Li‐S batteries, leading to low activation voltage barrier, stable cycle life of 1000 cycles, ultrafast current rate up to 8 C, and high areal capacities of Li2S cathodes with high mass loading. Encouragingly, this highly active Li2S cathode can be applied for constructing truly workable Li2S//Si cells with a high specific energy of 673 Wh kg?1 and stable performance for 200 cycles at high rates against hollow nanostructured Si anode. 相似文献
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Porous Cu(I) Triazolate Framework and Derived Hybrid Membrane with Exceptionally High Sensing Efficiency for Gaseous Oxygen 下载免费PDF全文
Si‐Yang Liu Xiao‐Lin Qi Rui‐Biao Lin Xiao‐Ning Cheng Pei‐Qin Liao Jie‐Peng Zhang Xiao‐Ming Chen 《Advanced functional materials》2014,24(37):5866-5872
Phosphorescent complexes of precious metal ions are widely studied as optical sensing materials for molecular oxygen. Combining the advantages of luminescent complexes and porous matrixes, porous coordination polymers show great potential for oxygen‐sensing, although their sensitivity, requirement of precious metal, and device fabrication remain challenging issues. In this work, the photoluminescence and oxygen‐sensing properties of the porous Cu(I) triazolate framework [Cu(detz)] (MAF‐2, Hdetz = 3,5‐diethyl‐1,2,4‐trizole) is studied in detail, which shows high chemical stability in moisture and water, very long phosphorescent lifetime (116 μs) and large Stokes shift (14 562 cm?1), as well as considerable oxygen permeability (1.7 × 10?11 mol cm?1 s?1 bar?1) at ambient conditions, giving rise to exceptionally high luminescence quenching efficiency of 99.7% at 1 bar O2 (I 0/I 100 = 356) with a perfectly linear Stern‐Volmer plot (K SV = 356 bar?1, R 2 = 0.9998), fast response and good reversibility. Further, a counter‐diffusion crystal‐growth method was developed to fabricate MAF‐2 thin films protected by silicone rubbers as the first example of soft membrane oxygen sensor based on coordination polymer or metal‐organic framework, which exhibited extraordinary oxygen‐sensing performance (limit of detection = 0.047 mbar) and outstanding mechanical property, as well as outstanding chemical stability even in an acidic atmosphere. 相似文献
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Xiaozhen Li Chao Yin Si Si Liew Chun-Sing Lee Kanyi Pu 《Advanced functional materials》2021,31(46):2106154
Optical imaging has played a pivotal role in deciphering in vivo bioinformatics but is limited by shallow penetration depth and poor imaging performance owing to interfering tissue autofluorescence induced by concurrent photoexcitation. The emergence of near-infrared (NIR) self-luminescence imaging independent of real-time irradiation has timely addressed these problems. There are two main kinds of self-luminescent agents, namely inorganic and organic luminophores. Inorganic luminophores usually suffer from long-term biotoxicity concerns resulting from potential heavy-metal ions leakage and nonbiodegradability, which hinders their further translational application. In contrast, organic luminophores, especially organic semiconducting luminophores (OSLs) with good biodegradable potential, tunable design, and outstanding optical properties, are preferred in biological applications. This review summarizes the recent progress of OSLs used in NIR afterglow, chemiluminescence, and bioluminescence imaging. Molecular manipulation and nanoengineering approaches of OSLs are discussed, with emphasis on strategies that can extend the emission wavelength from visible to NIR range and amplify luminescence signals. This review concludes with a discussion of current challenges and possible solutions of OSLs in the self-luminescence field. 相似文献
125.
Yoonseok Ka Eungkyu Lee Si Yun Park Jaewon Seo Dae-Gyeon Kwon Hyun Hwi Lee Yongsup Park Youn Sang Kim Changsoon Kim 《Organic Electronics》2013,14(1):100-104
We investigate the effects of ZnO annealing temperature (TA) on the performance of inverted polymer solar cells with ZnO electron-selective layers deposited by spin coating aqueous solutions of an ammine-hydroxo zinc complex. The inverted solar cells based on poly(3-hexylthiophene):[6,6]-phenyl-C61-butyric acid methyl ester with TA as low as 80 °C exhibit power-conversion efficiencies of 3.6%, which is equal to those of devices with higher TA. Characterizations of the ZnO films using X-ray photoelectron spectroscopy, ultraviolet photoelectron spectroscopy, grazing incidence wide-angle X-ray scattering, and optical transmittance measurements show that the abrupt improvement of device performance from TA = 60 to 80 °C is due to the improvement of energy-level alignment arising from the increases in the relative amount and the crystallinity of ZnO. 相似文献
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The paper addresses the problem of target recognition using High-resolution Radar Range Profiles (HRRP). A novel approach of feature extraction and dimension reduction based on extended high order central moments is proposed in order to reduce the dimension of range profiles. Features extracted from radar HRRPs are normalized and smoothed, and then comparative analysis of the similar approaches is done. The range profiles are obtained by step frequency technique using the two-dimensional backscatters distribution data of four different aircraft models. The template matching method by nearest neighbor rules, which is based on the theory of kernel methods for pattern analysis, is used to classify and identify the range profiles from four different aircrafts. Numerical simulation results show that the proposed approach can achieve good performance of stability, shift independence and higher recognition rate. It is helpful for real-time identification and the engineering implements of automatic target recognition using HRRP. The number of required templates could be reduced considerably while maintaining an equivalent recognition rate. 相似文献
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