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排序方式: 共有1979条查询结果,搜索用时 171 毫秒
81.
82.
Ludwig Leible 《Starch - St?rke》1996,48(4):121-130
Starch as a renewable raw material for chemical/industrial uses has a long tradition. In terms of quantity, starch ranks third behind wood and vegetable oils. In the medium term, this position will be maintained, if not improved. The volume of renewable raw materials used for fuel is even greater and expected to increase in the medium term. By means of a technology assessment on chemical/industrial and energy uses of renewable raw materials, it shall be demonstrated where the specific potentials and risks of starch use can be found. Among others, the following aspects are considered: energy and CO2 balance sheets, biodegradability and competiveness. Under the headings of „saving of raw materials (degree of self-sufficiency)”︁, „area required (reduction of surpluses)”︁, „employment effects”︁, „contribution to CO2 reduction”︁ and „need for subsidies”︁, medium-term (up to 2005) potential use of starch in Germany is studied relative to use of renewable raw materials in total. 相似文献
83.
Janine Will Lars Schneider Dr. Jonathan Becker Jun.-Prof. Dr. Sabine Becker Andreas Miska Christopher Gawlig Prof. Dr. Siegfried Schindler 《Israel journal of chemistry》2020,60(10-11):999-1003
A new tripodal imine ligand tris(2-(propan-2-ylideneamino)ethyl)amine (imine3tren) was prepared in order to stabilize high valent iron-oxido complexes. Iron complexes were synthesized in template reactions from iron(II) salts, tris(2-aminoethyl)amine (tren) and acetone. Due to the reversibility of the imine formation, complexes with different ligands were obtained depending on the reaction conditions. Three complexes, [Fe(imine3tren)(OAc)2] ( 1 ), [Fe(imine3tren)(OAc)]OTf ( 2 ) and [(imine3tren)2Fe2(F)2](SbF6)2 ( 3 ), could be synthesized and structurally characterized. However, reactions with hydrogen peroxide, iodosobenzene or ozone did not lead to any kind of “oxygen adduct” complex that could be spectroscopically observed. 相似文献
84.
Umberto De Rossi Johannes Moll Monika Spieles Günther Bach Siegfried Dhne Jrg Kriwanek Maria Lisk 《Advanced Synthesis \u0026amp; Catalysis》1995,337(1):203-208
Cyanine dyes ( 1a–d ) with the 5,5′,6,6′-tetrachloro-1,1′-dialkyl-3,3′-di-(3-carboxypropyl)-benzimidocarbocyanine chromophore differing only in the chain length of their alkyl groups in 1,1′-position have been synthesized, spectroscopically characterized, and compared with 5,5′6,6′-tetrachloro-1,1′-diethyl-3,3′-di-(4-sulfobutyl)-benzimidocarbocyanine( TDBC ). In aqueous solution the dyes form J-aggregates which, depending on the alkyl group chain length, exhibit J-bands differing in spectral positions, bandwidth, and in the number of peaks. 相似文献
85.
Wei Li Zhen Yue Artur Lozovoi Oleg Petrov Carlos Mattea Siegfried Stapf 《Journal of Polymer Research》2018,25(11):239
The structure of chain entanglements in the solid state is important for revealing the relationship of structure and properties of polyolefin. In this work, low-field solid-state 1H NMR is used to study the chain dynamics of ultra-high molecular weight polyethylene (UHMWPE) in the solid state. It has been found that the relaxation distribution, analyzed by a multi-exponential inversion program, is an effective method to characterize the heterogeneous chain mobility. It is evidenced from the results that the UHMWPE in a less entangled state presents an obviously heterogeneous distribution of chain mobility in the non-crystalline phase, corresponding to its heterogeneous distribution of entangled points. In comparison, the commercial UHMWPE with a large number of entanglements shows a much more uniform mobility of the non-crystalline components. This heterogeneous distribution of chain mobility becomes even more critical after annealing the samples below the melting point, especially for the less entangled UHMWPE. 相似文献
86.
Ming Chen Bengt Hallstedt A. Nicholas Grundy Ludwig J. Gauckler 《Journal of the American Ceramic Society》2003,86(9):1567-1570
Phase equilibria in the CeO2 −CoO system at temperatures above 1500°C were investigated. The microstructures and the phase compositions of the DTA (differential thermal analysis) samples and the quenched solid pellets were analyzed using SEM (scanning electron microscope), EDX (energy dispersive X-ray), and WDX (wavelength dispersive X-ray). A eutectic reaction was found at 1645 ± 5°C. The eutectic point was calculated to be at 82 ± 1.5 mol% CoO. The eutectic phases were the CeO2 -rich phase (containing <5 mol% CoO) and the CoO-rich phase (containing ∼0.5 mol% CeO2 ). At 1580°C, the solubility of CoO in CeO2 was ∼3 mol%. 相似文献
87.
Rodrigues Christian M. G. Ludwig Andreas Wu Menghuai Kharicha Abdellah Vakhrushev Alexander 《Metallurgical and Materials Transactions B》2019,50(3):1334-1350
Metallurgical and Materials Transactions B - A two-phase Eulerian–Eulerian volume-averaged model is used to predict the formation of macrosegregation during the twin-roll casting of... 相似文献
88.
89.
Siegfried Hring Dieter Kleine Joachim Ulbricht 《Advanced Synthesis \u0026amp; Catalysis》1978,320(3):473-481
On the Free Radical Copolymerization of Unsaturated Isocyanates with Vinylchloride The free radical copolymerization of vinyl-, isopropenyl- and p-vinyl-phenylisocyanate with vinylchloride in mass and tetrahydrofurane solution at 50°C is investigated. The incorporation of the isocyanate monomers in the copolymers is favoured. These monomers effect a great decrease of the rate of copolymerization and a crosslinking of the formed homo- and copolymers, whose extent depends on the kind and the quantity of the incorporated monomers. The crosslinking is caused by the forming of isocyanurate units. 相似文献
90.