Reversible and irreversible low-pressure membrane foulants in drinking water treatment: Identification by principal component analysis of fluorescence EEM and mitigation by biofiltration pretreatment

With the increased use of membranes in drinking water treatment, fouling - particularly the hydraulically irreversible type - remains the main operating issue that hinders performance and increases operational costs. The main challenge in assessing fouling potential of feed water is to accurately detect and quantify feed water constituents responsible for membrane fouling. Utilizing fluorescence excitation-emission matrices (EEM), protein-like substances, humic and fulvic acids, and particulate/colloidal matter can be detected with high sensitivity in surface waters. The application of principal component analysis to fluorescence EEMs allowed estimation of the impact of surface water constituents on reversible and irreversible membrane fouling. This technique was applied to experimental data from a two year bench-scale study that included thirteen experiments investigating the fouling potential of Grand River water (Ontario, Canada) and the effect of biofiltration pre-treatment on the level of foulants during ultrafiltration (UF). Results showed that, although the content of protein-like substances in this membrane feed water (= biofiltered natural water) was much lower than commonly found in wastewater applications, the content of protein-like substances was still highly correlated with irreversible fouling of the UF membrane. In addition, there is evidence that protein-like substances and particulate/colloidal matter formed a combined fouling layer, which contributed to both reversible and irreversible fouling. It is suggested that fouling transitions from a reversible to an irreversible regime depending on feed composition and operating time. Direct biofiltration without prior coagulant addition reduced the protein-like content of the membrane feed water which in turn reduced the irreversible fouling potential for UF membranes. Biofilters also decreased reversible fouling, and for both types of fouling higher biofilter contact times were beneficial.     

Was? Wie? Warum? Jugendliche erforschen Flusslandschaften – Förderung des Systemverständnisses als Basis für gelebte Partizipation im Flussgebietsmanagement

River landscape planning and management to promote the positive long-term development of river landscapes must adhere to the principle of sustainability. In this context, the goal is to initiate a development process for river landscapes that successfully reconciles the requirements of nature and water conservation with social and economic aspects, and which actively involves affected citizens in the decision-making process. A systems-based understanding and the opportunity to make ecologically relevant decisions are essential prerequisites for participative processes.     

A flow-based tabu search algorithm for the RCPSP with transfer times

In this paper, we propose a tabu search algorithm for the resource-constrained project scheduling problem with transfer times. Solutions are represented by resource flows extending the disjunctive graph model for shop scheduling problems. Neighborhoods are defined by parallel and serial modifications rerouting or reversing flow on certain arcs. This approach is evaluated from a theoretical and experimental point of view. Besides studying the connectivity of different neighborhoods, computational results are presented for benchmark instances with and without transfer times.     

Time‐resolved small‐angle X‐ray scattering study of void fraction evolution in high‐density polyethylene during stress unloading and strain recovery

By means of time‐resolved small‐angle X‐ray scattering, we developed an analysis methodology to assess the void volume fraction ?_v in high‐density polyethylene (HDPE) during tensile testing. The specimens were first drawn up to different imposed strains, and subsequently were subjected to stress unloading and strain recovery stages. During the loading stage, ?_v progressively increased with the strain level, starting from a well‐defined onset strain prior to the yield point. In particular, ?_v reached a maximum of 8.75 vol% for a strain of 12.5% in the case of a HDPE grade with a molecular weight of 105 000 g mol^?1. Stress unloading and strain recovery caused a decrease in ?_v attained at the end of the loading stage. For a HDPE grade with a molecular weight of 55 000 g mol^?1, ?_v was more important during the loading stage and the decrease in ?_v was less marked during the stress unloading stage when compared to the HDPE with molecular weight of 105 000 g mol^?1. The residual and reversible components of void volume fraction were revealed. © 2015 Society of Chemical Industry     

Scheduling in sports: An annotated bibliography

Sports have worldwide appeal. Professional sport leagues involve significant investments in players. Events such as the Olympics Games, the Football World Cup and the major golf and tennis tournaments generate huge worldwide television audiences and many sports are multi-million dollar industries. A key aspect of sporting events is the ability to generate schedules that optimize logistic issues and that are seen as fair to all those who have an interest. This is not just restricted to generating the fixtures, but also to other areas such as assigning officials to the games in the competitions. This paper provides an annotated bibliography for sports scheduling articles. This area can be traced back over 40 years. It is noticeable that the number of papers has risen in recent years, demonstrating that scientific interest is increasing in this area.     

Effect of calcination atmosphere and temperature on γ-Al2O3 supported cobalt Fischer-Tropsch catalysts

The effect of calcination temperature and atmosphere on the properties of γ-Al₂O₃ supported cobalt Fischer-Tropsch catalysts has been investigated. One common precursor for all the catalysts was prepared by incipient wetness impregnation of γ-Al₂O₃ with an aqueous solution of cobalt nitrate hexahydrate. It was subjected to four different calcination atmospheres (air/50% steam: 30 mL/min, air: 30 mL/min, air: 50 mL/min, N₂: 30 mL/min) and eight different calcination temperatures (range: 473–723 K), making the total number of samples 32. Both the post calcination nitrogen content and the cobalt dispersion were measured. The results demonstrated that in order to maximise the cobalt dispersion, it is necessary to use low calcination temperatures and remove the precursor decomposition products (NO, NO₂, H₂O) efficiently. The Fischer-Tropsch synthesis performance of two catalysts calcined at the same temperature, but at different air flow rates was evaluated. No significant effect of the air flow rate was found on the turnover frequency or C₅₊ selectivity, but a high flow rate resulted in 30% higher activity per gram catalyst.     

Structural analysis of small span textile reinforced concrete shells with double curvature

The reinforcement of cement with glass fibre textiles imbues the composite with a tensile as well as compressive load-bearing capacity. The tensile capacity allows the elimination of steel reinforcement as well as the concrete corrosion cover in structural applications. With textile reinforced concrete (TRC) thin and/or free form shells could be realized. In this paper, a parametric study is used to evaluate the structural applicability of TRC for small span (2–15 m) doubly curved roof shells. The application of two different, existing TRC material combinations demonstrates the influence of the applied composite material on the design of the shell.