Photocatalytic activity of La-doped ZnO nanostructure materials synthesized by sonochemical method

ZnO nanostructure materials doped with different La contents were synthesized by sonochemical method. The products were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM),transmission electron microscopy(TEM), Raman spectroscopy, and Fourier transform infrared spectroscopy(FTIR). In this research, XRD patterns of pure ZnO and La-doped ZnO are specified as hexagonal wurtzite ZnO structure with no detection of La2O3 phase. SEM and TEM characterization revealed the flower shape of pure ZnO built-up from petals of hexagonal prisms with hexagonal pyramid tips. Upon doping with La, the flower-shaped ZnO is broken into individual 1D prism-like nanorods. Photocatalytic activities of the as-synthesized products were determined by measuring the degradation of methylene blue(MB) under ultraviolet–visible(UV) light irradiation.Among them, the 2.0 mol% La-doped ZnO shows better photocatalytic properties than any other products.     

Solvothermal synthesis of CdS nanowires templated by polyethylene glycol

CdS nanowires were solvothermally synthesized from Cd(NO₃)₂ and S powder using ethylenediamine as a solvent and polyethylene glycol (PEG) as a template. Hexagonal CdS with P6₃mc space group was detected using XRD and SAED, results which are in good accordance with those obtained by the simulation. SEM, TEM and HRTEM revealed the gradual development of nanowires in the [0 0 1] direction with a number of atoms aligning in a crystal lattice. Raman spectra of different products showed the fundamental and overtone modes at the same wavenumbers of 300 and 601 cm⁻¹, respectively. Their relative intensities at different molecular weight PEG were influenced by the anisotropic geometry of the products. Their photoluminescence peaks were detected at the same wavelengths of 518 nm. A formation mechanism for CdS nanowires was also proposed to relate to the experimental results.     

Formation of LiNi0.5Co0.5VO4 nano-crystals by solvothermal reaction

LiNi_0.5Co_0.5VO₄ nano-crystals were solvothermally prepared using a mixture of LiOH·H₂O, Ni(NO₃)₂·6H₂O, Co(NO₃)₂·6H₂O and NH₄VO₃ in isopropanol at 150–200 °C followed by 300–600 °C calcination to form powders. TGA curves of the solvothermal products show weight losses due to evaporation and decomposition processes. The purified products seem to form at 500 °C and above. The products analyzed by XRD, selected area electron diffraction (SAED), energy dispersive X-ray (EDX) and atomic absorption spectrophotometer (AAS) correspond to LiNi_0.5Co_0.5VO₄. V–O stretching vibrations of VO₄ tetrahedrons analyzed using FTIR and Raman spectrometer are in the range of 620–900 cm⁻¹. A solvothermal reaction at 150 °C for 10 h followed by calcination at 600 °C for 6 h yields crystals with lattice parameter of 0.8252 ± 0.0008 nm. Transmission electron microscope (TEM) images clearly show that the solvothermal temperatures play a more important role in the size formation than the reaction times.     

Flow pattern, mass flow rate, pressure distribution, and temperature distribution of two-phase flow of HFC-134a inside short-tube orifices

New experimental data on the influence of short-tube orifice configuration, including diameter, length, length-to-diameter ratio (L/D), and orientation on the flow pattern, mass flow rate, and pressure distribution of HFC-134a inside the short-tube orifice are presented. Short-tube orifice diameters ranging between 0.605 and 1.2 mm with L/D ranging between 1.87 and 33 are used in the experiments. Three different forms of the metastable liquid flow, which are metastable liquid core flow, conical metastable liquid core flow, and full metastable liquid flow are visually observed. The short-tube orifice diameter has a significant effect on the increase in the flow rate. Conversely, the change in the orientation of the test section has no significant effect on the flow rate. The choke flow phenomenon disappears inside the short-tube orifice when L/D is less than 2.91. Based on the present data, a correlation for predicting the mass flow rate through short-tube orifices is proposed.     

Conversion of Methylesters to Hydrocarbons Over Zn-Modified H-ZSM-5 Zeolite Catalyst

The conversion of methyloctanoate has been studied on Zn- and H-ZSM-5 catalysts. While the addition of Zn has a promoting effect in the aromatization of light alkanes, the effect is much lower when the feed is a methylester. Direct ring closure at the C adjacent to the CO group has been identified.     

Silica gel-assisted solvothermal production of CdS,CuxS(x=1,2) and ZnS with different morphologies

CdS, Cu_xS (x=1, 2) and ZnS with different morphologies were produced by the solvothermal reactions of M(CH₃COO)₂·2H₂O (M=Cd, Cu and Zn) and NH₂CSNH₂ in hexane with and without silica gel as a hard template at 200 °C for 24 h. The product phases were detected using X-ray diffraction (XRD). Different morphologies were characterized using a scanning electron microscope (SEM). The existence of silica gel in modeling morphologies of the sulfides was characterized using Fourier transform infrared (FTIR) spectrometer. Raman spectra of different products show the vibrations at the same wavenumbers, although they are composed of different morphologies. Photoluminescence (PL) emissions of the corresponding phases with different morphologies are at the same values, but their intensities are increased by template adding.     

Sulfur- and water-tolerance of Pt/KL aromatization catalysts promoted with Ce and Yb

Different Pt/KL catalysts containing rare earth (RE; Ce and Yb) promoters were prepared by two techniques, incipient wetness impregnation (IWI) and vapor phase impregnation (VPI). The catalysts were tested for the activity and the selectivity of n-hexane aromatization to benzene under clean, sulfur-containing, and water-containing feeds at 500 °C. It was observed that the catalysts prepared by the VPI technique exhibited much higher activity and selectivity than those prepared by IWI. It was also found that although under clean conditions, the addition of Ce or Yb caused a decrease in activity, in the presence of sulfur the addition of Ce and to a lesser extent Yb, significantly inhibited catalyst deactivation.

The influence of water in the feed was investigated by contacting the catalysts for 1 h to a feed containing 3 mol.% water. After this treatment, all the catalysts exhibited a significant activity loss. This loss was more pronounced for the catalyst prepared by the VPI method. The catalyst prepared by IWI already had suffered a significant deactivation before the water treatment, so the activity drop was not so pronounced. The sample prepared by VPI not only showed a drop in activity immediately after the water treatment but it became more susceptible to deactivation afterwards. By contrast, the Ce-promoted catalyst showed a more stable activity after the water treatment.

All catalysts were characterized before and after reaction by a number of techniques. In agreement with previous studies, FT-IR of adsorbed CO and chemisorption results indicated that the VPI method resulted in higher Pt dispersion than that obtained by the IWI method. After reaction in the presence of sulfur, the Ce-promoted Pt/KL catalyst showed a higher resistance to metal agglomeration and a lower rate of coke formation than the unpromoted Pt/KL. On all the catalysts, the amount of carbon deposits was greater in the presence of sulfur and after exposure to water vapor than under the reaction with clean feeds. This difference is explained in terms of metal particle growth and location in the zeolite.     

Predicting performance of radial flow type impeller of centrifugal pump using CFD

The main objective of this work is to use the computational fluid dynamics (CFD) technique in analyzing and predicting the performance of a radial flow-type impeller of centrifugal pump. The impeller analyzed is at the following design condition: flow rate of 528 m³/hr; speed of 1450 rpm; and head of 20 m or specific speed (N_s) of 3033 1/min in US-Units. The first stage involves the mesh generation and refinement on domain of the designed impeller. The second stage deals with the identification of initial and boundary conditions of the mesh-equipped module. In the final stage, various results are calculated and analyzed for factors affecting impeller performance. The results indicate that the total head rise of the impeller at the design point is approximately 19.8 m. The loss coefficient of the impeller is 0.015 when 0.6 < Q/Q_design < 1.2. Maximum hydraulic efficiency of impeller is 0.98 at Q/Q_design = 0.7. Based on the comparison of the theoretical head coefficient and static pressure rise coefficient between simulation results and experimental data, from previous work reported in the literature [Guelich, Kreiselpumpen, Springer, Berlin, 2004], it is possible to use this method to simulate the performance of a radial-flow type impeller of a centrifugal pump. This paper was recommended for publication in revised form by Associate Editor Seungbae Lee Somchai Wongwises is currently a Professor of Mechanical Engineering at King Mongkut’s University of Technology Thonburi, Bangmod, Thailand. He received his Doktor Ingenieur (Dr.Ing.) in Mechanical Engineering from the University of Hannover, Germany, in 1994. His research interests include two-phase flow, heat transfer enhancement, and thermal system design. Professor Wongwises is the head of the Fluid Mechanics, Thermal Engineering and Two-Phase Flow Research Laboratory (FUTURE). Suthep Kaewnai obtained a B. S. degree in Mechanical Engineering, 1980 from the King Monkut’s University of Technology Thonburi and M. S. degree in Mechanical Engineering, 1983 from Chulalongkorn University. He is currently an assistant professor at King Mongkut’s University of Technology Thonburi. Suthep’s research interests are in the area of pumps and small hydroturbine. Manuspong Chamaoot received a B. S. degree, 1972 and M.S. degree in Mechanical Engineering, 1979 from the King Monkut’s University of Technology Thonburi. He is currently an assistant professor at King Monkut’s University of Technology Thonburi. His research interests are in the field of mechanical vibration for rotating equipment and computational fluid dynamics.