Effect of ferroelectric polarization on piezo/photocatalysis in Ag nanoparticles loaded 0.5(Ba0.7Ca0.3)TiO3–0.5Ba(Zr0.1Ti0.9)O3 composites towards the degradation of organic pollutants

A 0.5(Ba_0.7Ca_0.3)TiO₃–0.5Ba(Zr_0.1Ti_0.9)O₃ (BCT-BZT) ceramic was studied for photocatalysis and piezocatalysis effects using dye degradation (methylene blue, rhodamine B, and methyl orange) and bacterial (Escherichia coli) disinfection from aqueous solution. To examine the effect of ferroelectric polarization, BCT-BZT powder was poled using the corona poling technique. Same time, BCT-BZT was converted into Ag/BCT-BZT composites as Ag induced surface plasmon resonance effect during photocatalysis. Piezocatalysis performance was assessed for dyes mineralization under ultrasonication. There was a significant impact of silver nanoparticles on the photo/piezocatalysis performance of BCT-BZT. Similarly, electric poling has also played a positive role in improving the photo/piezocatalysis in view of various dye degradation. These samples also showed effective antibacterial performance.     

Computational study on metal hydride based three-stage hydrogen compressor

A mathematical model for predicting the performances of a three-stage metal hydride based hydrogen compressor (MHHC) is presented. The performance of the MHHC is predicted by solving the unsteady heat and mass transfer characteristics of the coupled metal hydride beds of cylindrical configuration. The governing equations for energy, momentum and mass conservations, and reaction kinetic equations are solved simultaneously using the finite volume method. Metal hydrides chosen for a three-stage MHHC are LaNi₅, MmNi_4.6Al_0.4 and Ti_0.99Zr_0.01V_0.43Fe_0.99Cr_0.05Mn_1.5. Numerical results obtained for a single-stage MHHC using MmNi_4.6Al_0.4 are in good agreement with the experimental data reported in the literature. Using three-stage compression, a maximum pressure ratio of 28 is achieved for the supply conditions of 20 °C absorption temperature and 2.5 bar supply pressure. A maximum delivery pressure of 100 bar is obtained for the operating conditions of 20 °C absorption temperature and 120 °C desorption temperature.     

Effect of microwave pretreatment of mixed culture on biohydrogen production from waste of sweet produced from Benincasa hispida

To enhance the production of biohydrogen from biomass, various pretreatment methods play important role. In this study, effect of microwave irradiation on the culture was studied on biohydrogen production from Benincasa hispida (Petha) solid waste at different powers for a fixed interval of time. The highest power studied was 800 W with a frequency of 2450 MHz. The amount of soluble sugars found in the waste was 13.9 mg/L having the chemical oxygen demand (COD) of 3000 mg/L. Studies have been performed in batch reactors using mixed consortia and results were also compared with the reactor operated at the normal conditions i.e. without any inoculum pretreatment. Maximum hydrogen produced was 14 mmol H₂ per mol of soluble sugar consumed in the reactor in which the inoculum was exposed to 320 W of microwave for 5 min. SEM analysis of this microwave pretreated culture was done.     

Enzymic peeling of Indian grapefruit (Citrus paradisi)

The tough nature of grapefruit (Citrus paradisi) peel and its close adherence to the inner fruit sections limit the industrial processing of grapefruit. Two commercial peeling enzymes coded as ‘Brand A’ and ‘Brand B’ were studied for enzymic peeling of Indian grapefruit by vacuum infusion. The peeling process was optimised with respect to process parameters such as scalding time, enzyme concentration, vacuum infusion time and incubation time. © 2001 Society of Chemical Industry     

Computation methods for hydrodynamic problems (Reynold's equation)

This paper deals with the application of numerical methods to finding approximate solutions for a two-dimensional Reynolds' equation.Pressure height parameters ($\text{P}{}^1$) are evaluated at a series of discrete points on a rectangular mesh in the circumferential direction. Using these parameters the Reynold's equation is transformed into its equivalent finite difference form.In this form the equation gives the value of the pressure height parameter $\text{P}{}^1$ in terms of the values at neighbouring points and the corresponding influence coefficients. The finite difference equation is solved using an interactive method.Jacobi, Gauss-Seidel and successive over-relaxation methods are discussed. It is observed that by using an optimum over-relaxation factor, much computer time can be saved. Finally a convergence criterion is discussed which decides the iteration process.     

An Efficient and Scalable Quasi-Aggregate Signature Scheme Based on LFSR Sequences

Aggregate signatures can be a crucial building block for providing scalable authentication of a large number of users in several applications like building efficient certificate chains, authenticating distributed content management systems, and securing path vector routing protocols. Aggregate signatures aim to prevent resources (signature and storage elements, and computation) from growing linearly in the number of signers participating in a network protocol. In this paper, we present an efficient and scalable quasi-aggregate signature scheme, {rm CLFSR}- {rm QA}, based on third-order linear feedback shift register (cubic LFSR) sequences that can be instantiated using both XTR and GH public key cryptosystems. In the proposed {rm CLFSR}-{rm QA} construction, signers sign messages sequentially; however, the verfier need not know the order in which messages were signed. The proposed scheme offers constant length signatures, fast signing, aggregation, and verification operations at each node, and requires the least storage elements (public keys needed to verify the signature), compared to any other aggregate signature scheme. To the best of our knowledge, {rm CLFSR}- {rm QA} is the first aggregate signature scheme to be constructed using LFSR sequences. We believe that the {rm CLFSR}- {rm QA} signature scheme can be catalytic in improving the processing latency as well as reducing space requirements in building secure, large-scale distributed network protocols. We perform extensive theoretical analysis including correctness and security of {rm CLFSR}- {rm QA} and also present a performance (computation and communication costs, storage overhead) comparison of the proposed scheme with well-known traditional constructions.     

Optimization of Aspergillus niger Fermentation for the Production of Glucose Oxidase

A number of nutritional factors influencing glucose oxidase (EC 1.1.3.4) production by Aspergillus niger NCIM 545 were studied. The synthesis of glucose oxidase by A. niger was investigated in two steps using submerged fermentation at 30 ± 2 °C and 180 rpm for 96 h. Primarily, nutritional components were selected by one-factor-at-a-time method, and the significance of each component with respect to glucose oxidase production was identified by Plackett–Burman design (seven variables including six nutritional viz. sucrose, sodium nitrate, peptone, calcium carbonate, magnesium sulfate, and potassium dihydrogen phosphate, and one dummy or unassigned variable were studied with eight experiments). In the second step, concentration of most significant factors and their interaction were studied with response surface methodology (central composite design). Each variable in the design was studied at five different levels, with all variables taken at a central coded value of zero. Considerable amount of glucose oxidase was produced from A. niger species with sucrose as the carbon source, sodium nitrate as the inorganic nitrogen source, and peptone as the organic nitrogen source. Glucose oxidase activity increased remarkably by 28.93 fold (from 0.00993 to 0.29 U ml⁻¹) with CaCO₃-supplemented media. The outcome of Plackett–Burman design showed CaCO₃, peptone, and MgSO₄ as significant parameters. Further optimization using a three-factor central composite design with 20 experiments increased yield of glucose oxidase from 0.29 to 2.05 U ml⁻¹ (sevenfold) with a decrease in cultivation time from 96 to 72 h.     

M.O.S. switched-capacitor amplifiers

Switched-capacitor voltage gain elements, in which the gain is precisely controlled by the ratio of two capacitors, are presented. The voltage gain is obtained by means of a transconductance element operating into a switched-capacitor resistor. Circuit configurations use a single operational amplifier or a unity-gain buffer. In some of these configurations, the offset voltage of the operational amplifier or the buffer is not amplified.     

Yield strength of overaged alloys containing coherent ordered precipitates

The existing models for yielding of overaged alloys do not account for the observed strain rate sensitivity of the yield stress and predict a sharper decrease in stress as a function of particle size than the experimental observations. A dynamic model has been presented here to account for the yield strength of overaged alloys containing coherent ordered precipitates which takes into consideration the intrinsic characteristics of the precipitates. Concentric glide loops are supposed to form around precipitate particles. Their sizes as a function of applied stress have been computed. The stress on the innermost loop rises with increasing applied stress and when it exceeds the opposing force due to antiphase boundary, the loops shrink. The rate of shrinkage of loops has been calculated for different values of applied stresses. The yielding occurs when the external stress is high enough to account for the applied strain rate. The model has been applied to calculate the yield strength of an austenitic stainless steel containingγ’ precipitates. The antiphase boundary energy of the precipitates was measured by dislocation pair spacing method. The mode of variation of calculated yield stress values with particle size is predicted more accurately than by earlier models. The model qualitatively accounts for the observed sensitivity of yield stress to strain rate and antiphase boundary energy of the precipitates. Formerly Manager Research & Development, Alloy Steels Plant, Durgapur     

Augmented photoelectrochemical response of CdS/ZnS quantum dots sensitized hematite photoelectrode

A visible light active and stable photoelectrode has been developed by depositing a passivating layer of ZnS QDs on CdS QDs sensitized hematite photoelectrode (Hematite‐CdS/ZnS) for PEC generation of hydrogen. Photoelectrochemical properties, in terms of stability and efficiency, have been investigated on the various hematite photoelectrodes sensitized with CdS QDs and CdS/ZnS QDs by varying number of SILAR cycles. I–V characteristics show that two layers of ZnS QDs deposited over three layers of CdS could enhance PEC response of hematite and efficiency by a factor of 3 and 11 respectively. Chronoamperometry measurement ensures that after adding a layer of ZnS QDs, CdS sensitized hematite film turns out to be a stable photoelectrode in the electrolyte. Prepared photoelectrodes have been characterized by XRD, SEM, HRTEM and UV–Vis spectrophotometer for various structural, morphological and optical properties to analyze PEC results. Mott–Schottky analysis and incident photon to current conversion efficiency (IPCE) measurements of sensitized hematite photoelectrode supported the improved PEC response of CdS/ZnS QDs sensitized hematite thin films. Copyright © 2016 John Wiley & Sons, Ltd.