Organic PM Emissions from Vehicles: Composition,O/C Ratio,and Dependence on PM Concentration

A suite of real-time instruments was used to sample vehicle emissions at the California Air Resources Board Haagen-Smit facility. Eight on-road, spark-ignition gasoline and three alternative vehicles were tested on a chassis dynamometer and the emissions were diluted to atmospherically relevant concentrations (0.5–30 μg/m³). An Aerodyne high resolution time-of-flight aerosol mass spectrometer (HR-ToF-MS) characterized the real-time behavior of the nonrefractory organic and inorganic particulate matter (PM) in vehicle emissions. It was found that the emission of particulate organic matter (POM) was strongly affected by engine temperature and engine load and that the emission concentrations could vary significantly by vehicle. Despite the small sample size, consistent trends in chemical characteristics were observed. The composition of vehicle POM was found to be related to overall PM mass concentration where the oxygen-to-carbon (O/C) ratio tended to increase at lower concentration and had an average value of 0.057 ± 0.047, with a range from 0.022 to 0.15. The corresponding fraction of particle-phase CO₂⁺, or f₄₄, ranged from 1.1% to 8.6% (average = 2.1%) and exhibited a linear variation with O/C. The average mass spectrum from all vehicles tested was also compared to those of hydrocarbon-like organic aerosol (HOA) observed in ambient air and the agreement is very high. The results of these tests offer the vehicle emissions community a first glimpse at the real-time chemical composition and variation of vehicle PM emissions for a variety of conditions and vehicle types at atmospherically relevant conditions and without chemical interferences from other primary or secondary aerosol sources.

Copyright 2015 American Association for Aerosol Research     

Enhancement of fiber orientation distribution reconstruction in diffusion-weighted imaging by single channel blind source separation

In diffusion-weighted imaging (DWI), reliable fiber tracking results rely on the accurate reconstruction of the fiber orientation distribution function (fODF) in each individual voxel. For high angular resolution diffusion imaging (HARDI), deconvolution-based approaches can reconstruct the complex fODF and have advantages in terms of computational efficiency and no need to estimate the number of distinct fiber populations. However, HARDI-based methods usually require relatively high b-values and a large number of gradient directions to produce good results. Such requirements are not always easy to meet in common clinical studies due to limitations in MRI facilities. Moreover, most of these approaches are sensitive to noise. In this study, we propose a new framework to enhance the performance of the spherical deconvolution (SD) approach in low angular resolution DWI by employing a single channel blind source separation (BSS) technique to decompose the fODF initially estimated by SD such that the desired fODF can be extracted from the noisy background. The results based on numerical simulations and two phantom datasets demonstrate that the proposed method achieves better performance than SD in terms of robustness to noise and variation in b-values. In addition, the results show that the proposed method has the potential to be applied to low angular resolution DWI which is commonly used in clinical studies.     

Isothermal crystallization of lightly sulfonated syndiotactic polystyrene/montmorillonite clay nanocomposites

Lightly sulfonated syndiotactic polystyrene (sPS) nanocomposites were prepared using a solution intercalation technique, and the effect of montmorillonite clay on the crystallization kinetics of sulfonated sPS ionomer nanocomposites was systematically studied. Wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM) were used to evaluate the dispersion of clay platelets within sPS and sulfonated sPS ionomer (SsPS) matrices. Experimental results obtained from WAXD and TEM revealed a predominately exfoliated morphology within the SsPS ionomer containing 5 wt.% of organically-modified clay. The corresponding non-sulfonated sPS control exhibited a mixed morphological structure consisting of intercalated platelets and many platelets that were present as micron-sized agglomerates. Using differential scanning calorimetry (DSC), the Avrami approach was used to elucidate information related to nucleation and growth within the sPS and SsPS systems during the isothermal crystallization process. Pristine and organically-modified clays significantly increased the overall crystallization rate of the SsPS ionomer, while the nanoclays slightly decreased the crystallization rate of the non-ionic sPS. The mechanistic origins of increased crystallization rates within the SsPS ionomer clay nanocomposites were attributed to multiple phenomena including disruption of the ionomer electrostatic network and a nucleating effect due to the presence of well-separated, homogeneously dispersed clay platelets.     

Aerosol Metrology Supporting Air Quality Monitoring in the United Kingdom and Europe

Regulatory measurements of particle mass concentration in air, such as PM₁₀ and PM_2.5, have been required in Europe for many years, but have been problematic as issues affecting the comparability of measurements, even when made by the reference method, have become apparent. The importance of airborne particulate matter for human health, and the complexity of the atmospheric processes affecting it, have led to many other parameters, such as particle number concentration, size distribution and composition being monitored, in some cases also as a regulatory requirement. Generally the metrological aspects have been covered by the monitoring network operators, with little involvement from National Metrology Institutes (NMIs). The United Kingdom (UK) National Physical Laboratory is unusual in being an NMI that also operates air quality networks on behalf of the government, directly involved in the full range of activities from fundamental metrology, standardisation of methods, and field operation. More recently, some of the measurement issues have started to be addressed by a group of NMIs within the European Metrology Research Programme. This paper outlines some of the key metrological problems in this area, and the current position in dealing with them from a UK and European perspective.     

Functionalized Polyelectrolytes Assembling on Nano‐BioFETs for Biosensing Applications

A new surface functionalization scheme for nano‐Bio field effect transistors (FETs) using biocompatible polyelectrolyte thin films (PET) is developed. PET assemblies on Si nanowires (Si‐NWs) are driven by electrostatic interactions between the positively charged polymer backbone and negatively charged Si/SiO₂ surface. Such assemblies can be directly coated from PET aqueous solutions and result in a uniform nanoscale thin film, which is more stable compared to the conventional amine silanization. Short oligo‐ethylene glycol chains are grafted on the PETs to prevent nonspecific protein binding. Moreover, the reactive groups of the polymer chains can be further functionalized to other chemical groups in specific stoichiometry for biomolecules detection. Therefore, it opens a new strategy to precisely control the functional group densities on various biosensor surfaces at the molecular level. In addition, such assemblies of the polymers together with the bound analytes can be removed with the pH stimulation resulting in regeneration of a bare sensor surface without compromising the integrity and performance of the Si‐NWs. Thus, it is believed that the developed PET coating and sensing systems on Si‐NW FETs represent a versatile, promising approach for regenerative biosensors which can be applied to other biosensors and will benefit real device applications, enhancing sensor lifetime, reliability, and repeatability.     

Cultural strengths as moderators of the relationship between acculturation to the mainstream U.S. Society and eating- and body-related concerns among Mexican American women.

This study explored whether 3 culturally relevant variables (i.e., ethnic identity, familism, and enculturation) operated as sources of strength for 209 Mexican American women by buffering the relationship between their acculturation to the mainstream U.S. society and eating- and body-related concerns. In an effort to capture the underlying dimensions of women’s eating- and body-related concerns, the authors used principal components analysis to identify 3 components: control concerns, restricted eating, and body dissatisfaction. As hypothesized, results from a series of hierarchical regressions suggested familism significantly buffered the links between acculturation to the mainstream U.S. society and all 3 eating- and body-related variables. However, enculturation did not moderate the associations, and ethnic identity moderated only the link between acculturation and restricted eating. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Fermented goats’ milk produced with selected multiple starters as a potentially functional food

A screening among five lactic acid bacteria, used alone or in combination, led to select a mixed starter (Streptococcus thermophilus CR12, Lactobacillus casei LC01, Lactobacillus helveticus PR4, Lactobacillus plantarum 1288) capable to produce a fermented goats’ milk containing γ-aminobutyric acid (GABA) and angiotensin-I converting enzyme (ACE)-inhibitory peptides. The fermented milk was characterized by cell counts of lactic acid bacteria not lower than 7.0 log cfu g⁻¹, even after 45 days of storage at 4 °C. Fermentation of goats’ milk resulted in the production of ca. 28 mg kg⁻¹ of GABA. Furthermore the fermented goats’ milk had an in vitro ACE-inhibitory activity of ca. 73%. Prolonged cold storage did not significantly affect both the concentration of GABA and the ACE-inhibitory activity. Moreover, the taurine content did not significantly vary during both fermentation and the entire storage period.     

Perceptions of European American and African American instructors teaching race-focused courses.

In 2 studies (N = 907), we developed and validated the Perceptions of Diversity Instructors (PDI-32) measure, which assesses college students' ratings of instructors teaching a race-focused diversity course. We also explored how the professor's race/ethnicity, students' attitudes toward similarities and differences, and perceived professor bias influenced students' ratings. Supporting the source effects outlined in the persuasion literature and prior qualitative research, the results indicated that students expect African American instructors to be more biased (subjective/judgmental) but assume European American instructors to have less content expertise (inexpert/unaware). Also, students who are more open to discussing diversity issues rated the instructors more positively. Finally, students' expectation of professor bias mediated the relationship between the professor's race/ethnicity and students' evaluations. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Volunteering: A Community Response to the Rena Oil Spill in New Zealand

We explore the experiences of people who volunteer to help remediate the effects of non‐natural environmental disasters. Following the grounding of the Rena, volunteers were engaged to clean up the resulting oil spill on the beaches of Tauranga, New Zealand. Volunteers were later invited to respond to an online questionnaire about their experiences. More women than men responded, and respondents tended to be older, and engaged in the paid workforce or retired. Greater membership in community organizations was associated with a greater participation in clean‐up events. Respondents were positive about the experience, and were more positive when they had actually participated in a clean‐up event, with positivity remaining high even after multiple volunteer occasions. Recommendations are made for increasing volunteer participation.