Adsorption of Pb(ll) and Eu(III) by oxide minerals in the presence of natural and synthetic hydroxamate siderophores

Trihydroxamate siderophores have been proposed for use as mediators of actinide and heavy metal mobility in contaminated subsurface zones. These microbially produced ligands, common in terrestrial and marine environments, recently have been derivatized synthetically to enhance their affinity for transuranic metal cations. However, the interactions between these synthetic derivative and adsorbed trace metals have not been characterized. In this paper we compare a natural siderophore, desferrioxamine-B (DFO-B), with its actinide-specific catecholate derivative, N-(2,3-dihydroxy-4-(methylamido)benzoyl)desferrioxamine-B (DFOMTA), as to their effect on the adsorption of Pb(II) and Eu(III) by goethite and boehmite. In the presence of 240 microM DFO-B, a strongly depleting effect on Eu(III) adsorption by goethite and boehmite occurred above pH 6. By contrast, almost total removal of Eu(III) from solution in the neutral to slightly acidic pH range was observed in the presence of either 10 or 100 microM DFOMTA, due primarilyto the formation of metal-DFOMTA precipitates. Addition of DFOMTA caused an increase in Pb(II) adsorption by goethite below pH 5, but a decrease above pH 5, such that the Pb(II) adsorption edge in the presence of DFOMTA strongly resembled the DFOMTA adsorption envelope, which showed a maximum near pH 5 and decreasing adsorption toward lower and higher pH.     

Ethernet für die Feldebene

Firmen&;ProdukteSiemens A&;D, I&;S

Ethernet für die Feldebene     

All-solid-state tunable continuous-wave ultraviolet source with high spectral purity and frequency stability

We present a novel approach for the generation of higly frequency-stable, widely tunable, single-frequency cw UV light that is suitable for high-resolution spectroscopy. Sum-frequency generation (SFG) of two solid-state sources with a single cavity resonant for both fundamental waves is employed. Using a highly stable, narrow-linewidth frequency-doubled cw Nd:YAG laser as a master laser and slaving to it the SFG cavity and the other fundamental wave from a Ti:sapphire laser, we generate UV radiation of 33-mW output power around 313 nm. Alternatively, we use a diode laser instead of the Ti:sapphire laser and produce an output power of 2.1 mW at 313 nm. With both setups we obtain a continuous tunability of >15 GHz, short-term frequency fluctuations in the submegahertz range, a long-term frequency drift below 100 MHz/h, and stable operation for several hours. The theory of optimized doubly resonant SFG is also given.     

Single-Row Transformation of Complete Graphs

A complete graph is a fully-connected graph where every node is adjacent to all other nodes in the graph. Very often, many applications in science and engineering are reducible to this type of graph. Hence, a simplified form of a complete graph contributes in providing the solutions to these problems. In this paper, we present a technique for transforming a complete graph into a single-row routing problem. Single-row routing is a classical technique in the VLSI design that is known to be NP-complete. We solved this problem earlier using a method called ESSR, and, the same technique is applied to the present work to transform a complete graph into its single-row routing representation. A parallel computing model is proposed which contributes in making the problem modular and scalable. We also discuss the application of this work on the channel assignment problem in the wireless cellular telephone networks.     

Chemical vapor deposition synthesis of self-aligned carbon nanotube arrays

A procedure for producing arrays of self-aligned carbon nanotubes (CNTs) using standard chemical vapor deposition (CVD) is reported. Using UV photolithography, silicon substrates are patterned with a thin layer of thermally evaporated iron as a CNT catalyst. The CVD synthesis was carried out over a small temperature range (700°C–800°C) using acetylene and methane gasses, producing aligned CNT towers. Scanning electron microscopy (SEM) analysis shows a relationship between CNT tower height and synthesis time. Additionally, results show that impurity particles dramatically effect CNT tower growth. These results indicate that aligned CNTs can be produced in a desired pattern with height control.     

Enhanced Simulated Annealing Technique for the Single-Row Routing Problem

This paper presents ESSR (Enhanced Simulated annealing for Single-row Routing) model for solving the single-row routing problem. The main objective in this problem is to produce a realization that minimizes both the street congestion and the number of doglegs. Simulated annealing (SA) is a stochastic, hill-climbing and gradient-descent technique based on the statistical properties of particles undergoing thermal annealing. By performing slow cooling, the nets in the single-row routing problem align themselves according to a configuration with the lowest energy. The model has been known to produce reasonably good solutions for many NP-complete optimization problems, such as the single-row routing problem. In ESSR, our strategy is to minimize both the street congestion and the number of interstreet crossings (doglegs) by expressing a single energy function as their collective properties. This objective is achieved by representing the energy as the absolute sum of the heights of the net segments. To speed up convergence, we pivot the street congestion value while having the energy drops directly proportional to the number of doglegs. This action has the effect of minimizing the number of doglegs as the energy stabilizes. Our simulation work on ESSR produces optimal results in most cases for both the street congestion and the number of doglegs. Our experimental results compare well against results obtained from our earlier model (SRR-7) and two other methods reported in the literature.     

An automated gantry crane as a large workspace robot

In the context of further automation of manufacturing processes, automated transportation of heavy weights using cranes becomes more and more important. Applying the skills of robots to crane automation, a wide market of new applications could be developed. The main idea is to interpret the crane as a large workspace-serving robot. The crane hook represents the effector of the robot. As an example for the effector, an automated storage and retrieval unit for rack operations by a crane with three active auxiliary effector axes has been developed and integrated into the control concept. The control has been realized for a reconstructed 5-t-bridge crane with workspace dimensions of 30 m×8.7 m×7 m.     

Two-beam cross-correlation: a method to characterize transport phenomena in micrometer-sized structures

To determine flow properties, namely, the velocity and angle of the flow in microstructured channels, an experimental realization based on fluorescence correlation spectroscopy is described. For this purpose, two micrometer-sized spatially separated volume elements have been created. The cross-correlation signal from these has been recorded and evaluated mathematically. In addition to previous results, two-beam cross-correlation allows for fast and easy determination of even small (down to 200 μm/s) flow velocities, as well as simultaneous measurement of diffusion properties of single dye molecules within a rather short detection time of 5-100 s and an error rate of less than 20%. The spatial flow resolution is around 1-2 μm, limited by the diameter of the volume element. Furthermore, vectorial flow data can be obtained and evaluated. A discussion of the theoretical background and an experimental verification of the theoretical results is performed. The feasibility of fast and easy data processing is shown if the flow time is the only desired information. Possible applications of this precise and simple method are the determination of transportation effects within artificial microstructures for CE and HPLC, fast chemical kinetics, and high-throughput screening.     

Schwarz iterations for the efficient solution of screen problems with boundary elements

This paper investigates two domain decomposition algorithms for the numerical solution of boundary integral equations of the first kind. The schemes are based on theh-type boundary element Galerkin method to which the multiplicative and the additive Schwarz methods are applied. As for twodimensional problems, the rates of convergence of both methods are shown to be independent of the number of unknowns. Numerical results for standard model problems arising from Laplaces' equation with Dirichlet or Neumann boundary conditions in both two and three dimensions are discussed. A multidomain decomposition strategy is indicated by means of a screen problem in three dimensions, so as to obtain satisfactory experimental convergence rates.