Quantizer offset selection for improved requantization transcoding

In this paper, we provide an analysis of the requantization problem in order to improve the requantization process. This analysis is based on theoretical R-D results of requantized Laplacian sources instead of minimizing requantization errors as commonly found in the literature. We derive the effective quantizer characteristic by applying superposition to the quantizer characteristics of encoder and transcoder. Further investigation shows that the effective quantizer has a periodic property. Using the memoryless property of the probability distribution function and the periodic property of the effective quantizer characteristic, we derive expressions for entropy and distortion. Based on the theoretical R-D model, requantization for fine and coarse quantized signals is investigated. The analysis of the R-D behavior shows that a heuristic can be derived which improves the requantization process. Finally, the results from the R-D analysis are verified for requantization transcoding of H.264/AVC video streams. We show that the transcoding process for H.264/AVC video streams, which corresponds to coarse quantization, is improved with gains up to 1 dB.     

Metal complexation properties of freshwater dissolved organic matter are explained by its aromaticity and by anthropogenic ligands

Dissolved organic matter (DOM) in surface waters affects the fate and environmental effects of trace metals. We measured variability in the Cd, Cu, Ni, and Zn affinity of 23 DOM samples isolated by reverse osmosis from freshwaters in natural, agricultural, and urban areas. Affinities at uniform pH and ionic composition were assayed at low, environmentally relevant free Cd, Cu, Ni, and Zn activities. The C-normalized metal binding of DOM varied 4-fold (Cu) or about 10-fold (Cd, Ni, Zn) among samples. The dissolved organic carbon concentration ranged only 9-fold in the waters, illustrating that DOM quality is an equally important parameter for metal complexation as DOM quantity. The UV-absorbance of DOM explained metal affinity only for waters receiving few urban inputs, indicating that in those waters, aromatic humic substances are the dominant metal chelators. Larger metal affinities were found for DOM from waters with urban inputs. Aminopolycarboxylate ligands (mainly EDTA) were detected at concentrations up to 0.14 μM and partly explained the larger metal affinity. Nickel concentrations in these surface waters are strongly related to EDTA concentrations (R2=0.96) and this is underpinned by speciation calculations. It is concluded that metal complexation in waters with anthropogenic discharges is larger than that estimated with models that only take into account binding on humic substances.     

The effect of family climate on risky driving of young novices: The moderating role of attitude and locus of control

The aim of the study was to examine the relative importance of young novice drivers’ family climate on their driving behavior. A sample of young novice drivers (N = 171) between the age of 17 and 24, who held their permanent (or temporary) driver's license for no longer than one year, participated. The questionnaire included items related to the participants’ family climate, 3 socio-cognitive determinants (i.e., attitude, locus of control and social norm), and risky driving behaviors. We expected both family climate and the socio-cognitive determinants to exert a direct effect on risky driving. Furthermore we hypothesized that the socio-cognitive determinants would moderate the impact of family climate on risky driving. The results showed that the effect of family climate on risky driving only originated from one single factor (i.e., noncommitment). Besides that, the results confirmed the importance of the three socio-cognitive determinants to the degree that attitude, locus of control, and social norm significantly predicted the self-reported risky driving. In line of what we hypothesized, attitude moderated the relationship between noncommitment and risky driving. Lastly, we found an unexpected three-way interaction which indicated that locus of control moderated the relation between noncommitment and risky driving only when young drivers’ attitude was risk-supportive. We recommend scholars and practitioners to take into account the interaction between external sources of influence (such as an individual's family climate) and more personally oriented dispositions (such as an individual's attitude, social norm and locus of control) when trying to explain and change young novices’ risky driving.     

Mirror‐based reflection in AmbientTalk

This paper introduces a novel mechanism to perform intercession (a form of reflection) in an object‐oriented programming language with the goal of making the language extensible from within itself. The proposed mechanism builds upon a mirror‐based architecture, leading to a reusable reflective application programming interface that cleanly separates interface from implementation details. However, support for intercession has been limited in contemporary mirror‐based architectures. This is due to the fact that mirror‐based architectures only support reflection explicitly triggered by metaprograms, while intercession requires reflection implicitly triggered by the language interpreter. This work reconciles mirrors with intercession in the context of an actor‐based, object‐oriented programming language named AmbientTalk. We describe this language's full reflective architecture, highlighting its novel mirror‐based approach to reflect upon both objects and concurrently executing actors. Subsequently, we apply AmbientTalk's mirror‐based reflection to implement two language features, which crucially depend on intercession, to wit future‐type message passing and leased object references. Copyright © 2008 John Wiley & Sons, Ltd.     

Bond characteristics of carbon and stainless steel flat rebars with an alternate rib pattern

The good performance of reinforced concrete depends on the appropriate transfer of forces between reinforcing rebars and concrete, which relies on the bond interaction between the two materials. At an uncracked section, both materials work together by means of the bond forces; however, if the tensile strength of the concrete is reached at a certain part of the structure, a crack will appear and the steel will be the only active element at the cracked section. At increasing loads, the crack will continue opening and large crack openings may lead to a failure of the rebar and to the collapse of the whole structure. A new idea to positively influence the cracking behaviour has emerged, which is based on the combination of smooth and rib zones within the same reinforcing rebar. Furthermore, use of stainless steel flat reinforcement has been considered as an option to optimize the reinforcing of shallow slabs. This paper presents bond tests performed on carbon and stainless steel flat reinforcements embedded in concrete and with different alternate rib configurations. Test results are presented in terms of bond strength and force transfer stiffness, as well as in terms of bond stress–slip relationship. Results show no differences between the bond capacity of carbon and stainless steel rebars if other parameters are kept constant. The use of an alternate surface configuration combining smooth and ribbed zones within the bond length, does affect the bond capacity of the rebar, and the position of the smooth zone within the bond length plays an important role.     

High resolution mapping of surface reduction in ceria nanoparticles

Surface reduction of ceria nano octahedra with predominant {111} and {100} type surfaces is studied using a combination of aberration-corrected Transmission Electron Microscopy (TEM) and spatially resolved electron energy-loss spectroscopy (EELS) at high energy resolution and atomic spatial resolution. The valency of cerium ions at the surface of the nanoparticles is mapped using the fine structure of the Ce M(4,5) edge as a fingerprint. The valency of the surface cerium ions is found to change from 4+ to 3+ owing to oxygen deficiency (vacancies) close to the surface. The thickness of this Ce(3+) shell is measured using atomic-resolution Scanning Transmission Electron Microscopy (STEM)-EELS mapping over a {111} surface (the predominant facet for this ceria morphology), {111} type surface island steps and {100} terminating planes. For the {111} facets and for {111} surface islands, the reduction shell is found to extend over a single fully reduced surface plane and 1-2 underlying mixed valency planes. For the {100} facets the reduction shell extends over a larger area of 5-6 oxygen vacancy-rich planes. This finding provides a plausible explanation for the higher catalytic activity of the {100} surface facets in ceria.     

The Effects of Process-Induced Pectin Changes on the Viscosity of Carrot and Tomato Sera

The influence of process-induced pectin changes on the kinematic viscosity of the serum phases of carrot and tomato purées was investigated in this study. Variations in the amount of pectin present in the serum phase and pectin’s fine structure were induced by subjecting carrot and tomato to different thermal treatments, i.e. a mild and a strong heat treatment, followed by blending and high-pressure homogenisation at different pressure levels (0, 20 and 100 MPa). Changes in pectin structure were monitored by determination of the degree of methoxylation, analysing the molar mass distribution and immuno-dot blotting using anti-pectin antibodies. Characterisation of serum pectins revealed that a strong thermal treatment caused pectin thermosolubilisation and depolymerisation, especially in carrot sera, and high-pressure homogenisation provoked predominantly mechanical pectin solubilisation in carrot sera and pectin depolymerisation in tomato sera. It was observed that the kinematic viscosity of carrot sera was mainly affected by the amount of solubilised pectin, whereas in tomato sera, the kinematic viscosity could mainly be explained in terms of polysaccharide chain length. The degree of methoxylation of pectin, which has a broader distribution in tomato sera than in carrot sera, seemed to have a less pronounced role in determining the kinematic viscosity. In general, it could be concluded that serum viscosity is mainly determined by the amount and size of the solubilised pectin. The influence of serum viscosity on the rheology of the studied purées was limited as the rheology of this type of system is largely determined by the particle properties of the dispersed phase.