Effect of 2D MoS2 and Graphene interfaces with CoSb3 nanoparticles in enhancing thermoelectric properties of 2D MoS2-CoSb3 and Graphene-CoSb3 nanocomposites

The approach of incorporating a secondary phase in the bulk thermoelectric (TE) material has proved to be beneficial for enhancing the thermoelectric performance. We have investigated the effect of the presence of two-dimensional (2D) materials (MoS₂ or graphene) on the structural, electrical, and thermoelectric properties of CoSb₃ nanocomposite, in which CoSb₃ nanoparticles of sizes 20–50?nm are uniformly anchored on the surface of 2D-sheets of MoS₂ or graphene. The presence of 2D nanosheets enhances TE power factor and figure of merit (ZT). Inclusion of graphene in CoSb₃ causes large enhancement in power factor as a result of significantly high electrical conductivity and appreciable Seebeck coefficient. 2D graphene seems to work by providing extra carrier conduction channels along with a low interfacial potential barrier for charge transport. Homogeneously dispersed 2D-sheets of MoS₂ in CoSb₃ seem to cause interfacial modulation of charge carrier effective mass assisted by relatively larger interfacial barrier to result in significantly larger Seebeck coefficient and highly suppressed phonon conductivity, much more than graphene. The ZT value in both nanocomposites gets significantly enhanced in the entire studied temperature range of 300–700?K, the gain increasing with temperature over the CoSb₃. Whereas CoSb₃/graphene nanocomposites exhibit unusually high ZT at higher temperatures (550–700?K), the CoSb₃/2D-MoS₂ nanocomposites exhibit better performance (over graphene) in near room temperature range. The present study provides a possible strategy to enhance the conversion efficiency of various TE materials and has significant potential for waste heat recovery applications in various temperature ranges.     

Universal models of colour emotion and colour harmony

A new set of quantitative models of colour emotion and colour harmony were developed in this study using psychophysical data collected from 12 regions in the world, including Argentina, China, France, Germany, Hungary, Iran, Japan, Spain, Sweden, Taiwan, Thailand, and the UK. These data have previously been published in journals or conferences (for details see Tables 1 and 2 ). For colour emotion, three new models were derived, showing satisfactory predictive performance in terms of an average correlation coefficient of 0.78 for “warm/cool”, 0.80 for “heavy/light” and 0.81 for “active/passive”. The new colour harmony model also had satisfactory predictive performance, with an average correlation coefficient of 0.72. Principal component analysis shows that the common colour harmony principles, including hue similarity, chroma similarity, lightness difference and high lightness principles, were partly agreed by observers of the same region. The findings suggest that it is feasible to develop universal models of colour emotion and colour harmony, and that the former was found to be relatively more culture‐independent than the latter.     

Investigation of colour appearance models for illumination changes across media

The key to achieving successful cross‐media colour reproduction is a reliable colour appearance model, which is capable of predicting the colour appearance across a variety of imaging devices under different viewing conditions. The two most commonly used media, CRT displays (soft copy) and printed images (hard copy), were included in this study using four complex images. The original printed images were captured using a digital camera and processed using eight colour appearance models (CIELAB, RLAB, LLAB, ATD, Hunt96, Nayatani97, CIECAM97s, and CAM97s2) and two chromatic adaptation transforms (von Kries and CMCCAT97). Psychophysical experiments were carried out to assess colour model performance in terms of colour fidelity by comparing soft‐copy and hard‐copy images. By employing the memory‐matching method, observers categorized the reproductions displayed on a CRT and compared them to the original printed images viewed in a viewing cabinet. The experiment was divided into three phases according to the different colour temperatures between the CRT and light source, i.e., print (D50, A, and A) and CRT (D93, D93, and D50), respectively). It was found that the CIECAM97s‐type models performed better than the other models. In addition, input parameters for each model had a distinct impact on model performance. © 2001 John Wiley & Sons, Inc. Col Res Appl, 26, 428–435, 2001     

Influence of calcination ambient and film thickness on the optical and structural properties of sol-gel TiO2 thin films

Influence of both calcination ambient and film thickness on the optical and structural properties of sol-gel derived TiO₂ thin films have been studied. X-ray diffraction results show that prepared films are in an anatase form of TiO₂. Films calcined in argon or in low vacuum (∼2 × 10⁻¹ mbar) are found to be smaller in crystallite size, more transparent at low wavelength region of ∼300-450 nm, denser, have higher refractive index and band gap energy compared to air-calcined films. Scanning electron microscopic study reveals that surfaces of TiO₂ films calcined in argon or in low vacuum are formed by densely packed nano-sized particulates. Presence of voids and signs of agglomeration can be seen clearly in the surface microstructure of air-calcined films. In the thickness range ∼200-300 nm, band gap energy and crystallite size of TiO₂ films remain practically unaffected with film thickness but refractive index of thinner film is found to be marginally higher than that of thicker film. In this work, it has been shown that apart from temperature and soaking time, partial pressure of oxygen of the ambient is also an important parameter by which crystallite size, microstructure and optical properties of the TiO₂ films may be tailored during calcination period.     

Multiwalled carbon nanotubes‐based polypropylene composites: Influence of interfacial interaction on the crystallization behavior of polypropylene

Composites of polypropylene (PP) and multi‐walled carbon nanotubes (MWCNTs) were prepared via melt‐mixing utilizing Li‐salt of 6‐amino heaxanoic acid (Li‐AHA) modified MWCNTs in the presence of a compatibilizer (polypropylene‐g‐maleic anhydride; PP‐g‐MA). Improved interaction between the anhydride group of PP‐g‐MA and the amine functionality of Li‐AHA was confirmed via FTIR and Raman spectroscopic analysis. A higher glass transition temperature (T_g) of the PP phase has been observed in these composites as compared to pristine MWCNTs‐based composites. The crystallization temperature (T_c) of the PP phase was increased as a function of pristine MWCNTs concentration in PP/MWCNTs composites indicating hetero‐nucleating action of MWCNTs. However, T_c value was decreased in the presence of Li‐AHA modified MWCNTs indicating the adsorbed Li‐AHA on the MWCNTs surface. Moreover, T_c value was higher in the presence of Li‐AHA modified MWCNTs with PP‐g‐MA as compared to that of without PP‐g‐MA, suggesting the desorbed Li‐AHA from the MWCNTs surface due to melt‐interfacial reaction. Further, MWCNTs were extracted by hot vacuum filtration technique from PP/MWCNTs composites containing Li‐AHA and PP‐g‐MA. The isothermal crystallization kinetics showed a variation in crystallization behavior of the PP phase in the corresponding composites as compared to the “extracted MWCNTs.” POLYM. ENG. SCI., 57:183–196, 2017. © 2016 Society of Plastics Engineers     

Ranking of selected residues for biocoal production: Case of Thailand

A ranking of ten agricultural and forestry residues was carried out in terms of their suitability for biocoal production. The residues considered were paddy husk, paddy straw, sawdust, sugar cane bagasse, cotton stalk, corn cob, groundnut shell, cassava stalk, coconut husk and coconut shell. Ranking was carried out on the basis of annual production of the residues and the estimated cost of biocoal produced from them. Five residues that were found to be economically feasible for biocoal production, in their decreasing order of attractiveness, are coconut shell, sawdust, paddy husk, coconut husk and groundnut shell. The remaining residues were found to be unattractive for biocoal production mostly owing to their prohibitively high biocoal production costs.     

Preparation and thermal evolution of sol-gel derived transparent ZrO2 and MgO-ZrO2 gel monolith

Transparent gel monoliths of pure and MgO-doped zirconia having dopant concentrations in the range 0 to 15 mol % were prepared by chemical polymerization of zirconium n-propoxide and magnesium acetate tetrahydrate using 2-methoxy ethanol as solvent. The thermal evolution of amorphous gels was studied by differential thermal analysis, X-ray diffraction and transmission electron microscopy. The crystallization of pure and doped zirconia gels occurred in the temperature range 360 to 450° C. The first crystalline phase to appear is tetragonal for pure and 2 mol % doped zirconia, and cubic for 3 to 15 mol % doped samples. Both crystallization and decomposition temperatures are found to increase with increasing dopant concentration, approaching a saturation value for 10 mol % doped samples. It has been established that the transformation of the cubic to the monoclinic phase takes place via a metastable tetragonal phase. A linear relationship between the lattice parameter of cubic zirconia and MgO concentration has been established. X-ray diffraction studies have also revealed that the entire amount of MgO used in preparing doped zirconia gels remains in a single MgO-ZrO₂ crystalline phase formed initially by thermal treatment.[/p]     

Dynamic changes in salivation,salivary composition,and rumen fermentation associated with duration of high-grain feeding in cows

Salivary secretions are essential for the regulation of digestive processes, as well as rumen and cow health. This research evaluated the effects of the duration of high-grain feeding, and of the time relative to a meal, on salivation, saliva properties, feed bolus characteristics, chewing activity, ruminal and reticular volatile fatty acids, as well as salivary and ruminal pH. Nine nonlactating cannulated Holstein cows were sampled at 1 and 23 d after transition to a 65% grain diet (short term and long term, respectively). Both before and after a controlled meal (2.5 kg of dry matter, offered over 4 h), unstimulated saliva was taken orally for composition analysis. Stimulated salivation and feed boli characteristics were evaluated by collection of ingesta from cardia during 30 min. Chewing and ruminal pH were measured during the controlled meal and for a total of 6 h thereafter. Results from unstimulated saliva showed no effect of the duration of high-grain feeding on bicarbonate, phosphate, total proteins, mucins, lysozyme, and buffer capacity, but increased osmolality at the long term. Lysozyme activity did not differ with high-grain feeding duration, but tended to be lower after the meal. In contrast to short-term-fed cows, the long-term-fed cows increased both meal consumption and feed bolus size, but decreased chewing and feed ensalivation (5.2 vs. 4.6 ± 0.50 g of saliva/g of dry matter), and had lower pH of the stimulated saliva (7.00 vs. 6.67 ± 0.076). These cows also had decreased chewing index (66.5 vs. 45.4 min/kg of neutral detergent fiber), and despite the increase in stimulated saliva buffer capacity (0.027 vs. 0.039 ± 0.006), mean ruminal pH decreased (6.31 vs. 6.11 ± 0.065) during ad libitum feeding. Both in the rumen and reticulum, the concentration of total volatile fatty acids was lower and propionate proportion was higher at the long term. Linear regression analyses revealed a positive influence of the flow rates of salivary bicarbonate and phosphate on ruminal pH during the short term. For every 1-mol increment in the flow of bicarbonate or phosphate, ruminal pH increased by 0.062 or 0.439 units, respectively. Overall, salivary buffers are key determinants of ruminal pH regulation, especially during short-term grain feeding. However, in the long term, ruminal pH drop during ad libitum feeding was stronger, and this effect seems to be exacerbated by increased feed bolus size, accompanied by reductions in feed ensalivation, stimulated saliva pH, and chewing index.     

Work-family conflict and psychosocial work environment stressors as predictors of job stress in a cross-cultural study.

The purpose of this cross-cultural study was to investigate the relationship between work-family conflict (WFC), family-work conflict (FWC), job demands, job control, social support, flexibility in working hours, and job stress. The sample consisted of 27 doctors and 328 nurses from Norway, as well as 111 doctors and 136 nurses from India. The results indicate that predictors of job stress in India are different from Norway and different from doctors to nurses. For Norwegian doctors, none of the study variables were predictors of job stress. For Norwegian nurses WFC, high job demands, and low flexibility in working hours were predictors of job stress. For Indian doctors low job control and for Indian nurses high FWC and low social support were predictors of job stress. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

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