Kitchen Chemistry 101: Multigram Production of High Quality Biographene in a Blender with Edible Proteins

A high yielding aqueous phase exfoliation of graphite to high quality graphene using edible proteins and kitchen chemistry is reported here. Bovine serum albumin (BSA), β‐lactoglobulin, ovalbumin, lysozyme, and hemoglobin are used to exfoliate graphite and the exfoliation efficiency depended on the sign and magnitude of the protein charge. BSA showed maximum exfoliation rate, facilitated graphite exfoliation in water, at room temperature, by turbulence/shear force generated in a kitchen blender at exfoliation efficiencies exceeding 4 mg mL^?1 h^?1. Raman spectroscopy and transmission electron microscopy indicated 3–5 layer, defect‐free graphene of 0.5 μm size. Graphene dispersions loaded on a cellulose paper (650 μg cm^?2) showed the film conductivity of 32 000 S m^?1, which is much higher than graphene/polymer composites. Our method yielded ≈7 mg mL^?1, BSA‐coated graphene with controllable surface charge, which is stable under wide ranges of pH (3.0–11) and temperature (5.0–50 °C), and in fetal bovine serum, for more than two months.These findings may lead to the large scale production of graphene for biological applications.     

Proportional hazards modeling of time-dependent covariates usinglinear regression: a case study [mine power cable reliability]

In the proportional hazards model, the effect of a covariate is assumed to be time-invariant. In this paper a graphical method based on a linear regression model (LRM) is used to test whether this assumption is realistic. The variation in the effect of a covariate is plotted against time. The slope of this plot indicates the nature of the influence of a covariate over time. A covariate is time-dependent if a drastic change in the slope of the plot is found and the time-point, at which this drastic change occurs provides guideline in redefining a time-dependent covariate into two or more time-independent covariates. This method is applied to failure data of cables used for supplying power to electric mine loaders. The results obtained by applying only the proportional hazards model were misleading as the graphical method based on the LRM showed that one covariate was highly time-dependent. This graphical method should be used to supplement the proportional hazards model, not as a separate method. This avoids misinterpretation of the influence of a time-dependent covariate in the proportional hazards model. The proportional hazards model should be used to identify the most important covariates, while the LRM should be used as an explanatory tool to check the consistency of the influence of the covariates. The LRM involves matrix computations which can be quite time consuming for large data-sets. Also, tests for the statistically significant effect of a covariate are not yet well established in the model     

Time-domain measurements with the Hewlett-Packard network analyzerHP 8510 using the matrix pencil method

The generalized pencil of function (GPOF) method, also known as the matrix pencil method, is used to improve the resolution of HP 8510B network analyzer data in the time domain. This method provides for much higher resolution than the Fourier techniques. A comparison of the two methods is given for the example of the Beatty standard. The examples show that a parametric technique such as the GPOF can provide accurate and reliable results with a high degree of resolution even when the fast Fourier transform (FFT)-based technique fails     

Lyso platelet activating factor (LysoPAF) and its enantiomer. Total synthesis and carbon-13 NMR spectroscopy

Described is a reaction sequence for the total synthesis of lyso platelet activating factor (lysoPAF; 1-O-alkyl-sn-glycero-3-phosphocholine) and its enantiomer. The procedure is versatile and yields optically pure isomers of defined chain length. The synthesis is equally suited for the preparation of lysoPAF analogues and its enantiomers with unsaturation in the long aliphatic chain. First,rac-1(3)-O-alkylglycerol is prepared by alkylation ofrac-isopropylideneglycerol with alkyl methanesulfonate followed by acid-catalyzed removal of the ketal group. The primary hydroxy group of alkylglycerol is then protected by tritylation, the secondary hydroxy group is acylated, and the protective trityl group is removed under mild acidic conditions with boric acid on silicic acid, essentially without acyl migration. Condensation of the diradylglycerol with bromoethyl dichlorophosphate in diethyl ether, hydrolysis of the resulting chloride, and nucleophilic displacement of the bromine with trimethylamine givesrac-1-O-alkyl-2-acylglycero-3-phosphocholine in good overall yield. The racemic alkylacylglycerophosphocholine is finally treated with snake venom phospholipase A₂ (Ophiophagus hannah) which affords 1-O-alkyl-sn-glycero-3-phosphocholine (lysoPAF) of natural configuration in optically pure form. The “unnatural” 3-O-alkyl-2-O-acyl-sn-glycerol-1-phosphocholine enantiomer, which is not susceptible to phospholipase A₂ cleavage, gives 3-O-alkyl-sn-glycero-1-phosphocholine upon deacylation with methanolic sodium hydroxide. Homogeneity and structure of the intermediates and final products were ascertained by carbon-13 nuclear magnetic resonance spectroscopy on monomeric solutions.     

3D FDTD Implementation for Scattering of Electric Anisotropic Dispersive Medium Using Recursive Convolution Method

The finite-difference time-domain method based on recursive convoltion method (RC-FDTD) for the electric anisotropic dispersive medium is discussed in detail. To exemplify the availability of the three-dimensional RC-FDTD algorithm, the backscattering Radar-Cross-Section(RCS) of a non-magnetized plasma sphere is computed, and the numerical results are the same as the one of the Shift Operater-FDTD method, and show that the RC-FDTD method is correct and efficient. In addition, the co-polarized and cross-polarized backscattering time-domain of a magnetized plasma sphere are obtained by the RC-FDTD algorithm. The results show that when the external magnetic field is implemented, the cross-polarized component appear, evidently.     

Noncooperative Differential Game Based Efficiency-aware Traffic Assignment for Multipath Routing in CRAHN

Comparing to the traditional multihop ad hoc networks, dynamic spectrum environment is the special characteristic of CRAHN (cognitive radio ad hoc networks). Therefore, the cognitive users will show their selfishness on spectrum bandwidth cost in multihop communication. In CRAHN, multipath routing is a reasonable choice when considering efficiency and stability. In order to take further advantage of efficiency of multipath routing, this paper study the efficiency-awareness traffic assignment problem of multipath routing in CRAHN. There are several existing game based traffic assignment schemes for selfish wireless network, however, all of them can not be directly applicable to CRAHN. In addition, none of the existing works studied whether the scheme is efficient. In this paper, a noncooperative differential game is proposed, and the equilibrium of the game is computed and proved to be an efficient traffic assignment for multipath routing in CRAHN. Besides this, we also optimize the total cost of game from the game designer’s point of view, and give a simple example to illustrate the optimization procedure.     

Scalable Gaussian Normal Basis Multipliers over GF(2<Superscript><Emphasis Type=Italic>m</Emphasis></Superscript>) Using Hankel Matrix-Vector Representation

This work presents a novel scalable multiplication algorithm for a type-t Gaussian normal basis (GNB) of GF(2^m). Utilizing the basic characteristics of MSD-first and LSD-first schemes with d-bit digit size, the GNB multiplication can be decomposed into n(n + 1) Hankel matrix-vector multiplications. where n = (mt + 1)/d. The proposed scalable architectures for computing GNB multiplication comprise of one d × d Hankel multiplier, four registers and one final reduction polynomial circuit. Using the relationship of the basis conversion from the GNB to the normal basis, we also present the modified scalable multiplier which requires only nk Hankel multiplications, where k = mt/2d if m is even or k = (mt − t + 2)/2d if m is odd. The developed scalable multipliers have the feature of scalability. It is shown that, as the selected digit size d ≥ 8, the proposed scalable architectures have significantly lower time-area complexity than existing digit-serial multipliers. Moreover, the proposed architectures have the features of regularity, modularity, and local interconnection ability. Accordingly, they are well suited for VLSI implementation.     

Creep behavior of the ternary 95.5Sn-3.9Ag-0.6Cu solder—Part I: As-cast condition

The compression creep behavior was studied for the ternary solder alloy 95.5Sn-3.9Ag-0.6Cu in the as-cast condition. Samples were tested under stresses of 2–45 MPa and temperatures of −25–160°C. There was a significant variability in the creep curve shape, strain magnitude, and steady-state strain-rate properties. A multivariable linear-regression analysis of the steady-state strain-rate data, using the sinh-law stress representation, indicated two mechanisms distinguished by low- and high-temperature regimes of −25–75°C and 75–160°C, respectively. The sinh-law stress exponent (n) and apparent-activation energy (ΔH) in the −25–75°C regime were 4.4 ± 0.7 kJ/mol and 25 ± 7 kJ/mol (63% confidence intervals), respectively. Those same parameters in the 75–160°C regime were 5.2±0.8 kJ/mol and 95±14 kJ/mol, respectively, for the high-temperature regime. The values of ΔH suggested a short-circuit diffusion mechanism at low temperatures and a lattice or bulk-diffusion mechanism at high temperatures. The stress dependency of the steady-state strain rate did not indicate a strong power-law breakdown behavior or a threshold stress phenomenon. Cracks and grain-boundary sliding were not observed in any of the samples. As the creep temperature increased, a coarsened particle boundary and particle depletion zone formed in the region of fine Ag₃Sn particles that existed between the Sn-rich phase areas. The coarsened particle boundary, as well as accelerated coarsening of Ag₃Sn particles, were direct consequences of the creep deformation process.     

Integrated Dual-Display-Based 3G Mobile Phone / Wireless Terminal

In this paper, we describe HW and SW features of the developed prototype of a hybrid 3G mobile phone and wireless terminal, which provides integral video projection onto two VGA/2 displays that, when put side-by-side, form the integrated display with the ratio of the overall width to its overall height, equal to 4:3, so providing the integral video VGA format and enabling visual presentation of standard full-size web pages, PC mainstream SW screens (such as e.g. the ones of e-mail clients), multi-media content etc. When not in use, the displays can be fold back one onto each other, so preserving the industry-standard dimensions of the device. The two displays that share the image provide it with overall resolution of 640 x 480 pixels per inch. The device is driven by Texas Instruments OMAP 2420 multimedia processor with ARM1136 core and Linux operating system. In addition, the device is equipped with specially developped prototypes of unique spring/microgenerator-based battery charger as well as with ultra-thin mountable foil-based QWERTY keyboard.     

Performance of Efficient Signal Detection for LED-ID Systems

In this paper, effects of reader-to-reader interference are investigated for LED identification (LED-ID) system in a multi-reader environment. The LED-ID readers typically use different channels to avoid collision between readers. However, in-channel collision usually happens in terms of interrogation range. A reader-to-reader interference scenario is proposed, and nominal interrogation range of a desired reader is derived from this model. In order to evaluate the LED-ID reader-to-reader interference quantitatively, an efficient detection scheme is proposed and simulated by employing spreading sequence. The spreading sequence is inserted between each user’s frame formats. In the receiver, the desired signal is detected by using correlation among inserted spreading sequences. From simulation results, it is confirmed that the proposed scheme is very effective to enhance reliability of LED-ID communication systems.