Rubber effect on metallic dampers used on the supports of steel cross members

There are many strengthening methods made with steel cross members for strengthening the structures with inadequate earthquake behavior. This type of strengthening methods is also effective in buckling of the cross members in the behavior of the structural frames. This buckling may cause partial or complete collapse of the structure. Thus, it is quite important to prevent and limit the formation of buckling in steel crosses. At the TEC 2018, the insulation unit is defined as the elements that can exhibit flexible behavior on the horizontal direction and rigid behavior on the vertical direction under the effect of earthquake loads. The basic principle of using insulation units is that these members can dissipate energy in the carrier system. The originality of this study is to experimentally investigate the damper behavior created by using cylindrical rubber wedges, which can be easily found in the automotive industry, in combination with steel plates and bolts. In this experimental study, the contribution of seismic insulators to the structural element to be strengthened was investigated. The insulators used in this study are considered by analogy with lead-core rubber insulators. As such seismic lead-core rubber insulators move under the influence of lateral loads, the lead core inside makes plastic deformation, thus increasing the damping rate. In this insulator study, it is aimed to use U plates or bolts instead of lead core. While vertical loads are covered by rubber support, horizontal loads will be damped due to plastic deformation of U plates or bolts. The five types of seismic dampers were used as 10 B-type rubber wedge mounted damper (SR), 2 U-type steel plates damper (SP), 10 M6 steel bolted damper (SB), 2 U-type steel plates and 10 B-type rubber wedge mounted damper (SPR), 10 M6 steel bolted, and 10 C-type rubber wedge mounted damper (SBR). These specimens were tested under lateral loading and constant vertical loading. The results obtained at the end of the tests shall be compared considering the strength, stiffness, and dissipated energy capacities of the specimens.     

A Novel Cross-layer Routing Protocol for Increasing Packet Transfer Reliability in Mobile Sensor Networks

In mobile sensor networks (MSNs), sensor data is generally transferred via mobile sensor nodes by multi-hop fashion. Because of the mobility of the nodes in the network, the efficient routing protocols are needed to ensure end-to-end route reliability while incurring minimal power consumption and packet delay. In this study, we developed a new routing protocol to meet these requirements for MSNs based on a cross-layer interaction among five reference layers (application, transport, network, MAC and physical). The proposed protocol primarily exploits the idea of interaction among these five layers all-in-one protocol. Its primary goals are (i) to discover the most reliable route in network, (ii) to sustain the route reliability and (iii) to be energy efficient and delay aware. It has been designed, modeled and simulated by using OPNET Modeler simulation software. The simulation results of the proposed protocol have been compared to three well known routing protocols (i.e., AODV, Leach-Mobile, CBR-Mobile). According to the obtained results, the proposed protocol outperforms its counterparts in terms of route reliability and end-to-end delay performances.     

Performance analysis of new-design solar air collectors for drying applications

This paper presents a performance analysis of four types of air heating flat plate solar collectors: a finned collector with an angle of 75°, a finned collector with an angle of 70°, a collector with tubes, and a base collector. In this study, the first and second laws of efficiencies were determined for the collectors and comparisons were made among them. The results showed that the efficiency depends on the solar radiation and the construction of the solar air collectors. The temperature rise varied almost linearly with the incident radiation. The first law of efficiency changed between 26% and 80% for collector-I, between 26% and 42% for collector-II, between 70% and 60% for collector-III, and between 26% and 64% for collector-IV. The values of second law efficiency varied from 0.27 to 0.64 for all collectors? The highest collector efficiency and air temperature rise were achieved by the finned collector with angle of 75°, whereas the lowest values were obtained for the base collector. The effectiveness order of the collectors was determined as the finned collector with angle of 75°, the finned collector with angle of 70°, the collector with tubes, and the base collector.     

The complete analysis of the polyorganosiloxanes formed by the trimethylsilylation of the minerals olivine and suzorite

Methods are reported for the separation and complete quantitative estimation of the polyorganosiloxanes prepared by the trimethylsilylation of mineral silicates. Quantitative methods for the determination of low molecular weight oligomers up to Q₆M₁₂ (Q≡SiO_4/2; M≡(CH₃)₃SiO_1/2) are well known but there are no previously reported methods for the determination of high molecular weight species. This paper describes the application of gel permeation chromatography and quantitative high performance liquid chromatography to the study of these higher molecular weight species. Polyorganosiloxanes prepared from suzorite (a phlogopite) and from olivine (an orthosilicate) are used as examples. A further example is a study of the formation of higher molecular weight species on heating these polymers.     

A practical solid sampling method for the determination of lead in chewing gum by electrothermal atomic absorption spectrometry

In this study, the lead concentrations of chewing gum samples having different compositions were determined by solid sampling electrothermal atomic absorption spectrometry. In order to optimise the experimental conditions, the effects of pyrolysis temperature, atomization temperature, sample amount and sample thermal pre-treatment, on the analyte sensitivity were investigated. The samples were ashed at 400 °C for 2 h prior to directly determined by SS-ETAAS applying 600 °C of pyrolysis and 1600 °C of atomization temperatures without to add a modifier, acid and/or surfactant. The relationship between sample mass and integrated absorbance was linear up to 1.2 mg of sample; for higher sample mass the relationship was no longer linear, irrespective of the lead content. In addition, the thermally treated chewing gum samples were digested using concentrated HNO₃. The lead concentrations found by the two methods in 27 different kinds of samples were not significantly different at 95% confidence level. The proposed solid sampling technique was fast, simple, the risks of contamination and analyte loss were low. Detection limit (3σ) for lead was 0.017 ng/g.     

A direct borohydride-peroxide fuel cell-LiPO hybrid motorcycle prototype: Investigation of short-term behavior of DBPFC stack – I

In the present study, a safer and more performance 270?W Direct Borohydride/Peroxide Fuel Cell (DBPFC) Stack has been constructed for an electrical hybrid motorbike application. Performance tests were carried out with single cell and 5–10–25?cell stacks. Performance loss has been not observed while stacking DBPFC because of the Independent Cell Liquid Distribution Network (ICLDN) system and special bipolar plate design. The power densities have been approximately 120?mWcm^?2 for a single DBPFC and 25-cell DBPFC stack without any stacking loss. Additionally, the stack temperature has been controlled by keeping the oxidant concentration low, and it has been maintained at approximately 52?°C without using a cooling system. The short-term performances of the 25-cell DBPFC stack have been tested over 25?min and 50?min, which showed that the performance and stack security of the DBPFC are highly related to the oxidant properties, such as the concentration, temperature and feed type.     

Photo-electrochemistry of metallic titanium/mixed phase titanium oxide

In this study, the effect of potassium hydroxide concentration in anodization bath, anodization time, and calcination temperature on the photo-electrochemical behavior of metallic titanium/mixed phase titanium oxide is investigated. Further, the phase structure of a titanium oxide photocatalyst prepared on a titanium electrode through a high-voltage anodization method is examined. The study exploits photo-electrochemical, Fourier transform infrared spectroscopy attenuated total reflectance (FTIR–ATR), X-ray diffraction, and Raman spectroscopic methods to obtain better insights into the mechanism of mixed-phase titanium oxide formation. In this regard, the photo-electrochemical properties of the photocatalysts prepared in single excitation energy, violet light (410 nm), were investigated. The anodization time and the potassium hydroxide concentration in the anodization bath have significant effects on the photo-electrochemical properties of the photocatalysts. The experiments show that the effect of potassium hydroxide concentration is a function of the anodization potential applied, demonstrating different patterns as the anodization potential changes. Furthermore, FTIR-ATR, X-ray diffraction, and Raman spectroscopic studies reveal that the extended anodization times decrease the population of OH-containing groups, leading to lower photo-electrochemical performance. On the other hand, the formation of anatase phases becomes more favorable only in the extended anodization times before application of the calcination process. Additionally, the calcination temperature has a significant impact on the anatase to rutile ratio. Finally, increasing potassium hydroxide concentration leads to the formation of an amorphous titanium oxide layer. It can be concluded that the obtained information might have a significant impact on the preparation of titanium oxide and other metal oxide photocatalysts through the high voltage anodization process.     

Characterization of Double-Junction GaAsP Two-Color LED Structure

The structural, optical, electrical and electrical–optical properties of a double-junction GaAsP light-emitting diode (LED) structure grown on a GaP (100) substrate by using a molecular beam epitaxy technique were investigated. The p–n junction layers of GaAs_1?xP_x and GaAs_1?yP_y, which form the double-junction LED structure, were grown with two different P/As ratios. High-resolution x-ray diffraction (HRXRD), photoluminescence (PL), and current–voltage (I–V) measurements were used to investigate the structural, optical and electrical properties of the sample. Alloy composition values (x, y) and some crystal structure parameters were determined using HRXRD measurements. The phosphorus compositions of the first and second junctions were found to be 63.120% and 82.040%, respectively. Using PL emission peak positions at room temperature, the band gap energies (E_g) of the first and second junctions were found to be 1.867 eV and 2.098 eV, respectively. In addition, the alloy compositions were calculated by Vegard’s law using PL measurements. The turn-on voltage (V_on) and series resistance (R_s) of the device were obtained from the I–V measurements to be 4.548 V and 119 Ω, respectively. It was observed that the LED device emitted in the red (664.020 nm) and yellow (591.325 nm) color regions.     

Niobium boride coating on AISI M2 steel by boro-niobizing treatment

In this study, niobium boride coating was applied on pre-boronized AISI M2 steel by the thermo-reactive deposition technique in a powder mixture consisting of ferro-niobium, ammonium chloride and alumina at 950 °C for 1-4 h. The coated samples were characterized by X-ray diffraction, scanning electron microscope and micro-hardness tests. Niobium boride layer formed on the pre-boronized AISI M2 steel was smooth, compact and homogeneous. X-ray studies showed that the phases formed on the steel surfaces are NbB, Nb₃B₂, FeB and Fe₂B. The depth of the niobium boride layer ranged from 0.97 μm to 3.25 μm, depending on treatment time. The higher the treatment time the thicker the niobium boride layer observed. The hardness of the niobium boride layer was 2738 ± 353 HV_0.01.