Reaction scheme and kinetic modelling for the MTO process over a SAPO-18 catalyst

A kinetic model for simulation of the MTO process over SAPO-18 catalyst in a wide range of operating conditions has been proposed. The kinetic model predicts the experimental evolution of reaction products with time on stream, which follows three consecutive periods: initiation (where olefin production increases), a period of maximum olefin production and a period in which this production decreases. The kinetic scheme takes into account these three steps that evolve with time on stream: formation of active intermediate compounds, an step where olefins are formed by reaction of oxygenates (methanol/DME) with these intermediates and deactivation of intermediates by degradation to coke. The presence of water in the reaction medium attenuates the reaction rate of these steps. Discrimination of kinetic equations and calculation of the parameters of best fit have been carried out by solving the mass conservation equations of the individual components of the kinetic scheme together with the kinetic equation for deactivation and taking into account the effect of water on the kinetics of each step.     

Dynamics of plastic polygonal plates with rounded corners

A method of calculating the dynamic deflection of rigidly plastic plates resting on a viscoelastic bed with complex piecewise-smooth support contours composed of sections of straight lines and circles under impact and explosion loading is presented. The general solution, which includes previously known partial solutions for circular and polygonal plates, is obtained. The results of calculation of the deflection of a square hinge-supported plate with rounded corners are presented for the case of the presence and absence of a plastic base.Translated from Problemy Prochnosti, No. 9, pp. 62–66, September, 1991.     

The effect of plastic deformation on Al2CuLi (T 1) precipitation

The enhancement ofT ₁ precipitation in Al-Li-Cu alloys by plastic deformation prior to aging (that is, cold work) and the subsequent increase in alloy strength is investigated. The increased understanding of the role of matrix dislocations in the nucleation and growth ofT ₁ plates, discussed in the previous paper,^[1] permits a detailed study of the phenomenon. In this paper, the effect of different levels of plastic strain on theT ₁ particle distributions as a function of aging time at 190 °C is quantified, and the subsequent influence on tensile properties is thereby described. The effect of plastic deformation is shown to decrease theT ₁ plate length and thickness, increase the number density by almost two orders of magnitude, increase the yield strength by 100 MPa, while simultaneously reaching peak strength in 20 pct of the time required without plastic deformation. Formerly Graduate Student, Department of Materials Science, University of Virginia,     

Construction and performance of a multiparameter focal plane detector for use on a QMG/2 magnetic spectrometer

The design, construction and performance of a modular, two pressure focal plane detector, 550 mm long, 1000 mm deep and with an active height of 60 mm are described. The detector has been operated with ions ranging from 50 MeV ¹H to 200 MeV ³⁶S. Typical results achieved are 0.5 mm and 0.3° for the spatial and angular resolutions, and 0.7% and 3% for the total energy and energy loss measurements. A height signal is also provided.     

Electrochemical Faceting of polycrystalline platinum in HF solutions

The electrochemical faceting of polycrystalline (pc) platinum yielding a (100)-preferred oriented electrode surface was accomplished in HF solutions by applying to the pc platinum electrode a square wave potential perturbation at 1 kHz in the 0.2 to 1.3 V range (vs rhe). SEM patterns of the resulting surfaces were also obtained. For HF concentrations up to 2 M no appreciable influence of the electrolyte concentration on the electrochemical faceting was noticed. Otherwise, the voltammetric response of the (100)-type preferred oriented platinum surface in the H-adatom potential range when compared to previously reported data resulted remarkably sensitive to the electrolyte composition. The discussion of results was based on the non-equilibrium adsorption conditions for anions under the periodic perturbation.     

Location errors in tachistoscopic recognition: Guesses, probe errors, or spatial confusions?

Examined whether location errors in tachistoscopic visual probe tasks reflect (1) uncertainty about the actual position of items, (2) inappropriate guesses, encouraged by a requirement to respond, or (3) confusion about the position being tested. 46 undergraduates completed probe tasks in which they provided confidence ratings on each trial and tasks that substituted a color cue for a visual pointer or used a double bar probe. Results suggest that location errors on visual probe tasks reflect confusion about the spatial position of target items. Findings are consistent with data questioning the concept of iconic memory and imply that the bar-probe task cannot be used to study precategorical visual memory. (French abstract) (PsycINFO Database Record (c) 2010 APA, all rights reserved)