Melt-extracted oxide ceramic fibres — the fundamentals

A melt-extraction technique, using a sharpened molybdenum wheel, has been used to produce fine oxide ceramic fibres. Wetting of the molybdenum wheel by molten ceramic is a key parameter in the melt-extraction process. Two types of fibre are generally obtained, depending on the extraction speed. At very low wheel speed, fine and uniform fibres of high quality are produced. However, when the wheel speed exceeds a critical velocity, Rayleigh waves are formed on the free surface of the fibres. Moreover, the average fibre thickness first increases with the wheel velocity, then passes through a maximum, decreasing at high velocity. This thickness variation is discussed in terms of both surface tension and viscosity of the liquid ceramics.     

Experimental and numerical investigation of fracture in double-edge notched steel plates

Double-edge notched (DENT) steel plates were pulled until complete fracture and several experimental observations were made (using profilometry and scanning electron microscopy). The essential work of fracture (EWF) model was found to be well verified. Numerical simulations—up to the maximum load only—of some experiments were performed using the finite element method (FEM), and incorporating geometric and material non-linearities (large deformation elasto-plasticity). Some experimental measurements were compared with the corresponding numerical computations and excellent agreement was found.     

Using internal fibre geometry to improve the performance of pin-loaded holes in composite materials

The anisotropic nature of fibre reinforced composites leads to large stress concentrations around pin-loaded holes through standard weave cloths. Proper understanding of how this anisotropic nature affects the load distribution around holes can be utilised to reduce these concentrations if sufficient thought is given to the internal fibre geometry near to the hole. Such local reinforcements need not be highly complex and can be readily produced without excessive effort, producing significant improvements in performance.     

Studies on the in vitro Release of Ibuprofen from Polyethylene Glycol-Polyvinyl Acetate Mixtures Liquid Filled into Hard Gelatin Capsules

The release of ibuprofen from mixtures of polyethylene glycol (PEG) with polyvinyl acetate (PVAc) has been studied in vitro and complemented by x-ray diffraction measurements, differential scanning calorimetry (DSC), and melting point determinations via hot-stage microscopy (HSM). Results indicate that ibuprofen release can be affected markedly by alteration of the PVAc concentration. The molecular weight of the PEG and the pH of the dissolution medium are also shown to affect the release profile. Visual observation during the drug release process revealed a complex behavior which included emission of liquidlike droplets, formation of a crust around the releasing mass, and/or production of flakes of solid material. This behavior appeared to have a disadvantageous effect on the reproducibility of drug release. Construction of a phase diagram from results of thermal analysis using DSC and HSM indicated the formation of an eutectic mixture with a composition of 35% ibuprofen and 65% PEG 1500 and a melting point of 36°C. The complex behavior of the drug-releasing mass is discussed in terms of this phase diagram. Only the release data for systems containing 4% w/w or more of PVAc could be linearized by plotting against the square root of time whereas data for all of the systems studied could be linearized by first-order plots.     

The effect of na and Sr modification on surface tension and volumetric shrinkage of A356 alloy and their influence on porosity formation

Modification of the eutectic Si in Al-Si foundry alloys by adding strontium or sodium is, unfortunately, accompanied by an increase of porosity in the casting. In an attempt to understand the nature of this problem, this study used a sessile-drop method to investigate the effect of Sr and Na on surface tension and volumetric shrinkage, two probable causes of porosity occur-rence. The addition of 0.01 wt pct Sr and 0.005 wt pct Na to A356 alloy decreases the surface tension of the liquid by about 19 and 10 pct, respectively, and may increase the volume shrink-age by about 12 pct. These changes to surface tension and volumetric shrinkage promote the early formation of the pores during solidification and give the availability of a longer period of growth prior to complete solidification, resulting in a larger pore size. The effect of surface tension on the pores is more significant than volumetric shrinkage. Although the predicted pore diameter increases with lower surface tension or higher volumetric shrinkage, these two effects alone do not seem able to completely account for the observed increase in porosity that is associated with modification.     

Gas-phase modification of rare-earth intermetallic compounds

Recent work concerning the interstitial modification of permanent magnet alloys based on rare-earth iron intermetallic compounds is reviewed. The crystal structure of the new materials is discussed, then the thermodynamic and statistical aspects of the low-temperature interstitial modification process are considered. Finally, reaction kinetics and thermal stability of the new compounds are discussed and future prospects assessed.