Hermetic Packaging Using Eutectic SnPb Solder and Cr/Ni/Cu Metallurgy Layer

We have developed an easy, low-cost, and low-temperature optoelectronic hermetic packaging technology utilizing the eutectic SnPb solder and the Cr/Ni/Cu bonding pad. Bonding characteristics of the design were investigated in three different setups: silicon-silicon, silicon-glass, and glass-glass samples. Hermeticity was achieved at 200 degC without flux for all samples during the final bonding process. The bonding pads did not dewet during or after the reflow process. By utilizing the eutectic SnPb solder, the self-alignment process can be achieved. Because the bonding process was conducted through visual alignment, original misalignment was estimated to be more than 100 mum. The surface tension of melting solder during the reflow process allowed the samples to self-align and obtain a misalignment of less than 20 mum after solidification, which was 4% of the entire solder width. The bonding strength of the three setups ranged from 3 to 10 MPa. Among the three setups, glass-glass samples appear to have the strongest bonding strength. This low-temperature and cost-effective soldering process has demonstrated its feasibility and potential utilization in optoelectronic packaging     

Successful Aging

This issue's Works in Progress department presents six abstracts for projects that are developing interesting solutions to the elderly's quality of life challenges. The first two abstracts discuss projects that will help provide the elderly with freedom and independence by instrumenting their environments with supportive technology. The next two abstracts discuss projects building specialized user interfaces for addressing some of the challenges associated with aging, such as vision impairment. The final two abstracts present projects that will aid independence for the elderly by providing remote monitoring and assistance.     

Self-Consistent Effects on the Starting Current of Gyrotron Oscillators

Self-consistent effects on the starting current of gyrotron oscillators are examined. Field profiles in the open cavity are shown to be sensitive to the interaction dynamics. This can either significantly raise or lower the oscillation threshold, particularly for the low-Q modes. The transition from resonant-mode oscillations at the low magnetic field to backward-wave oscillations at the high magnetic field is demonstrated.     

Noise modeling for RF CMOS circuit simulation

The RF noise in 0.18-/spl mu/m CMOS technology has been measured and modeled. In contrast to some other groups, we find only a moderate enhancement of the drain current noise for short-channel MOSFETs. The gate current noise on the other hand is more significantly enhanced, which is explained by the effects of the gate resistance. The experimental results are modeled with a nonquasi-static RF model, based on channel segmentation, which is capable of predicting both drain and gate current noise accurately. Experimental evidence is shown for two additional noise mechanisms: 1) avalanche noise associated with the avalanche current from drain to bulk and 2) shot noise in the direct-tunneling gate leakage current. Additionally, we show low-frequency noise measurements, which strongly point toward an explanation of the 1/f noise based on carrier trapping, not only in n-channel MOSFETs, but also in p-channel MOSFETs.     

Surface characterization of sprayed CuGa x In1−x Se2 layers

Small-area polycrystalline CuGa _x In_1–x Se₂-based solar cells produced in the laboratory have been reported with efficiencies up to 18.8%. This success at achieving high-efficiency devices has stimulated a parallel research effort to produce large-area modules based on the use of CuGa _x In_1–x Se₂ with reduced cost of production. One method that has potential to achieve these objectives is chemical spray pyrolysis. Preliminary studies have resulted in devices with efficiencies of 4–5%. Further improvements toward implementing higher-efficiency devices are expected to result from a better understanding of the physical and chemical properties of the chalcopyrite layers produced. In this work we have investigated, for the first time, the properties of these layers using X-ray photoelectron spectroscopy (XPS) to identify the secondary phases and residual impurities present. The layers studied were for In/Ga mole ratios of x=0, 0.2, 0.4, 0.6, 0.8, and 1.0 in CuGa _x In_1–x Se₂. The layers were also profiled by sputter etching away the surface of the layers and repeating the XPS measurements. The effects of annealing the layers in air, vacuum, and selenium vapor were also investigated.     

Switching a multistable solid-state laser from one stable steady state to another-dynamic stability analysis

The switching of a multistable laser from one stable steady state to the next has been studied using a longitudinally pumped laser with a nonlinear mirror. To achieve switching, use has been made of a second mode that is oscillating at the pump frequency. This pump mode is kept just below its threshold for oscillation. We find through an analysis of the dynamic gain functions of both the laser and pump modes that the steady state of the laser mode is very sensitive to changes in the steady state of the pump mode that are brought about by fluctuations in the pump intensity. It is found that for switching to be possible, the difference in frequency between the pump and laser mode should not be much larger than the linewidth of the laser atomic medium. We conclude that a conventionally pumped multistable and multimode solid-state laser can have one of its modes switched from one of its stable steady states to another such state, of a lower or higher intensity, by longitudinally injecting a pulse of suitable magnitude, frequency, and duration as a perturbation. This can happen provided that one of the other N-1 modes, which are kept below oscillation threshold, has been pushed by such a perturbation to just above threshold for oscillation in order that it couples with the oscillating laser mode. We have estimated the switching time to be less than the laser cavity photon decay time but of the order of the round-trip time in the Fabry-Perot cavity. The analysis also shows that the laser threshold intensity and its stability are not dependent on the difference between the frequencies of the pump and laser modes. However, the threshold is found to be sensitive to changes in the overlap parameter which is defined as a ratio of the beam waists.     

Preparation of micrometer‐sized,monodisperse, magnetic polymer particles

Micrometer‐sized, monodisperse, magnetic composite particles were prepared by heating micrometer‐sized, monodisperse, hollow polystyrene/polydivinylbenzene composite polymer particles at 200°C for 4 h (particles had been dipped in pentacarbonyliron) and then washed in 12 N HCl and water. The hollow polymer particles were produced by seeded polymerization by the dynamic swelling method that was proposed by authors. The magnetic composite particles contained Fe₃O₄, the content of which was 49% based on total weight, and were attracted easily in water by a 1650 G magnet. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 428–433, 2003     

Evidence of flexoelectricity in polymer-dispersed liquid crystals

The linear electro-optic response of polymer-dispersed liquid crystal films has been studied. Micrometer-sized droplets of a cyanobiphenyl mixture (E7) were formed in a Norland Optical Adhesive 65 photopolymer by photopolymerization-induced phase separation. Samples with various average nematic droplet sizes were systematically investigated. The temperature dependence of the first-harmonic electro-optic spectra was obtained. Peculiar peaks and double peaks in the phase spectra were found at temperatures close to the clearing point. Samples with narrow distributions of droplet sizes were characterized by a double peak of the amplitude spectra in the low-frequency range. A flexoelectric origin of the first-harmonic spectra in confined nematic systems is discussed.     

Effect of proton radiation on the kinetics of phosphorescence decay in the ceramic material ZnS-Cu

The results of studying the dose dependences of the decay kinetics of phosphorescence excited by X-ray radiation in luminescent ZnS-Cu ceramic material before and after irradiation with 50-MeV protons are considered. An anomalous variation in the exponent of the hyperbolic phosphorescence curves was observed experimentally as the accumulated light sum increased. It is found from an analysis of the data obtained that two processes are involved in the decay: one of these is monomolecular and corresponds to the first-order kinetics; the other is bimolecular and corresponds to the second-order kinetics. Transitions of charge carriers delocalized from traps occur at the nonradiative-recombination centers induced by proton radiation. Recombination of these charge carriers at the emission centers in the course of decay is described by the second-order kinetics.