Ormosil coatings of high hardness

Organically modified silicates (ormosils) of two systems were coated on polyethyleneterephthalate (PET) substrates. One was the tetraethoxysilane (TEOS)-vinyltriethoxysilane (VTES) system and the other was the TEOS-tetraisopropyltitanate (TIPT)-VTES system. The reactions among the alkoxides were examined by liquid state ²⁹Si nuclear magnetic resonance (NMR) spectroscopy. The chemical bonds between TEOS and VTES, between TEOS and TIPT, and between VTES and TIPT are shown in the spectra and the reaction schemes are proposed. Vickers hardnesses of the ormosil coatings were obtained by using the models developed by Jönsson and Hogmark, and the theoretical models developed by the authors were valuable to predict the hardness values. The ormosil coatings obtained in the present study were much harder than the hardest transparent plastics, and thus are very useful for hard or protective coatings on organic polymers.     

Characteristics of hydrogen-fueled gas turbine cycle with intercooler,hydrogen turbine and hydrogen heater

The performances of a hydrogen-fueled gas turbine cycle equipped with an intercooler, regenerator, hydrogen turbine and recuperative hydrogen heater are analyzed. The intercooler is very effective to prevent the condensation and freezing of water vapor in cooling the suction air. The operation of hydrogen turbine in low-temperature range can also be prevented by adopting hydrogen heater. Thermodynamic analysis has revealed that the thermal efficiency and the specific output are considerably improved compared to those of the simple gas turbine cycle.     

Restoration challenges for urban rivers.

Urban sources account for significant quantities of important diffuse pollutants, and urban watercourses are typically badly polluted. As well as toxic metals, hydrocarbons including PAHs, and suspended matter, priority urban pollutants include faecal pathogens and nutrients. Can urban watercourses be restored by sufficient reductions in pollution loads? Case studies in the UK and Sweden provide insights and some grounds for optimism. A major trans-Atlantic review of the performance of best management practices (BMPs) is informing BMP planning. New approaches such as the maximisation of self-purification capacity in the receiving waters may also need to be developed, alongside BMPs at source. Other initiatives in Europe, USA and China, including collaborative projects, are trying to address the intractable issues such as persistent pollutants from transport and urban infrastructure. The challenge is daunting, but there are clear ways forward and future research needs are evident.     

A surface distortion analysis applied to the hoop/column deployablemesh reflector antenna

A practical approach is demonstrated for the deterministic analysis of surface distortions in reflector antennas, based on a first-order approximation to the aperture field phase. Measured pattern results from the 15-m-diameter hoop/column deployable mesh reflector antenna are used to demonstrate the accuracy which can be obtained with this surface distortion analysis. The only practical limitation of the first-order approximation is determined by the slope derivations of the distorted surface from the best-fit paraboloid     

Axisymmetric fracture mechanics analysis by the boundary integral equation method

The boundary integral equation (BIE) method of numerical stress analysis is shown to be a powerful technique for solving axisymmetric fracture mechanics problems of the types encountered in practice in pipes, tubes and pressure vessels. Comparisons with established analytical and finite element solutions for problems involving circumferential and penny-shaped cracks in round bars, spheres and hollow cylinders show that accurate values of stress intensity factors at the tips of cracks can be obtained by this method. The main advantage of the technique over the finite element method is the much reduced amount of labour required to prepare the mesh data, since in the BIE approach only the boundary of an axisymmetric component needs to be discretised into simple and relatively coarse line elements.