pH sensitive phosphate crosslinked films of starch-carboxymethyl cellulose

This work aims to develop hydrogel films of starch and carboxymethyl cellulose (CMC) crosslinked with sodium trimetaphosphate (STMP) and to characterize some of their properties. Starch and STMP (S/T), starch and CMC (S/C), and mixed (S/T/C) films were prepared by casting. The degree of substitution, morphology, swelling degree, FTIR, mechanical properties, and sorption isotherms were studied. Reticulated samples (S/T and S/T/C) showed the same degree of substitution (0.050 ± 0.001). All films presented homogeneous morphology, but the mixed film showed greater roughness. Crosslinking increased the swelling capacity of the mixed hydrogel at pH 7, although it remained decreased concerning the S/T hydrogel. However, this property was sensitive to pH variations. The mixed film (S/T/C) showed greater mechanical resistance. The casting process was efficient to produce hydrogel films of starch/CMC crosslinked with STMP and the general results demonstrated the advantages of the mixed hydrogel.     

Preparation and characterization of thermoresponsive poly(N-isopropylacrylamide-co-N-isopropylmethacrylamide) hydrogel materials for smart windows

In this study, a series of thermoresponsive cross-linked copolymer poly [N-isopropylacrylamide(NIPAm)-co-N-isopropylmethacrylamide(NIPMAm)] (P-M series samples: P-M-0, 10, 20, 30, 40, where numbers are co-monomer contents) hydrogels were prepared by free radical polymerization using the main monomer N-isopropylacrylamide (NIPAm), co-monomer N-isopropylmethacrylamide (NIPMAm), cross-linking agent N, N-methylenebisacrylamide, initiator (ammonium persulfate)/catalyst, and solvent water. In addition, a series of samples [P-G series samples: P-G-0, 10, 20, 30, 40, where numbers are co-solvent glycerol content) were prepared using P-M-40 as components and water/co-solvent glycerol as a mixed solvent. The effects of co-monomer NIPMAm and co-solvent glycerol contents on the lower critical solution temperature (LCST)/freezing temperature and light transmittance as function of temperature of the prepared copolymer gels were investigated. The resulting thermoresponsive polymer gels had LCSTs in the range of 17.9 to 38.7°C and freezing points in the range of 6.3 to −38.5°C. These gels are suitable materials for smart windows that are responsive to various environmental conditions.     

Physiology and behavior of Pseudomonas fluorescens single and dual strain biofilms under diverse hydrodynamics stresses

Three selected Pseudomonas fluorescens strains (the type strain and two strains originally isolated from a dairy processing plant - D3-348 and D3-350) were used to form turbulent and laminar flow-generated biofilms under laboratorial conditions using flow cell reactors with stainless steel substrata. The D3-348 and D3-350 strains were also used to form dual biofilms. Biofilm phenotypic characteristics, such as respiratory activity, total and culturable cells, biomass, total and matrix proteins and polysaccharides were compared. Biofilm mechanical stability, as a major feature involved in biofilm persistence, was also assessed using a rotating device system. The results indicate that hydrodynamic conditions have a remarkable impact on biofilm phenotype. Turbulent biofilms were more active, had more mass per adhesion surface area, a higher number of total and culturable cells, a higher amount of total proteins per gram of biofilm, similar matrix proteins and identical (D3-348 and D3-350 single and dual biofilms) or smaller (type strain) total and matrix polysaccharides content than their laminar counterparts. Biofilms formed by the type strain revealed a considerable higher amount of total and culturable cells and a higher amount of total proteins (turbulent biofilms) and total and matrix polysaccharides per gram of biofilm than single and dual biofilms formed by the other strains. Mechanical stability assays disclosed that biofilms formed by both type and D3-348 strains had the highest resistance to removal when exposed to mechanical stress. Dual strain biofilms population analysis revealed an apparent co-existence, evidencing neutral interactions. The overall results provided useful information regarding a broad spectrum of P. fluorescens biofilm phenotypic parameters, which can contribute to control and model biofilm processes in food industry.     

A possible mechanism of destruction of coastal trees by tsunamis: A hydrodynamic study on effects of coastal steep hills

In this paper, experimental and numerical studies are presented to understand why some trees close to the shoreline survived the 25 October 2010 Mentawai tsunami, while trees further inland before a steep coastal hill were all destroyed. A set of experiments were performed in a wave flume to measure the flow depths and forces acting on tree models, and the experimental results were used to verify our numerical model. Cross-shore distribution of the flow depth and the flow-induced bending moment acting on tree trunks were studied using our numerical model. Our results show that the presence of the steep hill increased both the flow depth and the bending moment acting on trees close to the steep hill, and might be an important mechanism responsible for the destruction of coastal trees.     

Characterization of CFRP Laminates’ layups using through-Transmitting ultrasound waves

Ultrasound waves interact strongly with the orientation and sequence of the plies in a layup when propagating in the thickness direction of composite laminates. Also the layup orientation greatly influences its properties in a composite laminate. If the layup orientation of a ply is misaligned, it could result in the part being rejected and discarded. Now, most researchers cut a small coupon from the waste edge and use a microscope to optically verify the ply sequences on important parts. This may add a substantial cost to the production since the test is both labor intensive and performed after the part is cured. A nondestructive technique would be very beneficial, which could be used to test the part after curing and requires less time than the optical test. Therefore we have developed, reduced, and implemented a novel ply-by-ply vector decomposition model for composite laminates fabricated from unidirectional plies. This model decomposes the transmission of a linearly polarized ultrasound wave into orthogonal components through each ply of a laminate. High probability is found, by comparisons between the model and tests, in characterizing cured layups of the laminates by using the proposed method.     

Measurement of the shape in the radioactive area by ultrasonic wave sensor

The HANARO (High-flux Advanced Neutron Application Reactor) has been operated since 1995. The Cold Neutron (CN) hole was implanted in the reflector tank from the design stage. Before a vacuum chamber and a moderator cell for the cold neutron source are installed into the CN hole, it is necessary to measure exactly the size of the inside diameter and thickness of the CN hole to prevent the interference problem. Due to inaccessibility and high radiation field in the CN hole, a mechanical measurement method is not permitted. The immersed ultrasonic technique is considered as the best way to measure the thickness and the diameter of the CN hole. The 4-Axis manipulator was designed and fabricated for locating the ultrasonic sensors. The transducer of an ultrasonic sensor having 10 MHz frequency leads to high resolution as much as 0.03mm. The inside diameter and thickness of 550 points of the CN hole were measured using 2 channel ultrasonic sensors. The results show that the thickness and inside diameter of the CN hole is in the range of 3.3 - 6.7mm and 0 156-165mm, respectively. This data will be a good reference for the design of the cold neutron source facility.     

Phenolic compounds in a Spanish red wine aged in barrels made of Spanish,French and American oak wood

A red Rioja wine was aged in barrels made of Spanish oak wood for 21 months. The evolutions of colour percentage intensity, families of phenolic compounds and low molecular weight phenolic compounds were studied in these wines and compared with those of the same wine aged in barrels made of French and American oak. The analysis of chromatic parameters and total anthocyanins indicates that the wines aged in Spanish and French oak wood barrels have similar chromatic characteristics, but are significantly different to those of wines aged in barrels made of American oak wood, indicating a different degree of modification of the colour. The ageing process also had an important influence on the low molecular weight polyphenols composition of wine. The evolution of these components allowed the production of wines with different characteristics, in relation to the type of wood used in barrel making process. On the other hand, Spanish oak wood can be considered suitable for barrel production for quality wines, since a wine aged in barrels made of Spanish oak wood showed similar and intermediate characteristics to those of the same wine aged in French and American oak woods.     

Influence of modified atmosphere packaging and storage temperature on the sensory and microbiological quality of fresh peeled white asparagus

The sensory and microbiological quality of fresh peeled white asparagus packaged in two different types of P-Plus films and stored at two different temperatures (5 °C and 10 °C) for up to 14 days, was studied. The shelf life limiting alterations at each temperature were evaluated. The best modified atmosphere was determined.At 10 °C, the shelf life was 6 days, the loss of freshness was the main cause of quality loss, as indicated by colour darkening and presence of blotches. Moreover the sensorial acceptance of cooked asparagus was affected, being on the limit.Fresh appearance was maintained better at 5 °C than at 10 °C, being microbial spoilage the main limiting factor. The atmosphere generated with film A (around 7% CO₂ and 15% O₂) inhibited spoilage and maintained the acidity of asparagus better than the atmosphere generated by film B (around 2% CO₂ and 20% O₂). The shelf life of asparagus packaged in film A and stored at 5 °C was 14 days.Mesophiles and enterobacteriaceae counts in asparagus stored at 5 °C were acceptable during 14 days being around 7 log cfu/g. Mesophiles counts were slightly higher in asparagus stored at 10 °C than at 5 °C, while the increase in enterobacteriaceae was clearly higher in asparagus stored at 10 °C.     

Axisymmetric thermocapillary convection in open cylindrical annuli with deforming interfaces

Two-dimensional thermocapillary convection in an open cylindrical annulus heated from the inside wall is computed. The deformable free surface is obtained as a solution of the coupled transport equations, assuming pinned contact points, at Prandtl number of 30 and prescribed geometry. Only steady convection is possible at any Reynolds number (Re) in the axisymmetric computations with either nondeformable or deformable surfaces. Dynamic free-surface deformations do not induce transitions to oscillatory convection even at large Re and capillary numbers (Ca). Free surfaces are convex near the cold wall stagnation point and concave near the hot wall. Two peaks appear at the free surface at low Re while four peaks are possible at larger Re. Free surface shapes and convection in the interior are insensitive to variations in Ca while the magnitudes of surface ripples increase with Ca. At Ca = 0 convection is calculated assuming nondeformable concave surfaces as function of the liquid volume (V) and the contact angle (θ) at the inner boundary. At constant V, peaks of surface velocity increase while central surface temperatures decrease with increasing θ. Curvature significantly influences convection which is more vigorous with increasing V/θ at constant θ/V.